3,4,5,6,7,8,9-Heptachlorophenaleno[1,9-bc]pyrazole

Treatment of perchloro-7H-cyclopropano[a]acenaphthylene 1 with hydrazine hydrate in DMF at ca. 80 °C gives the new 3,4,5,6,7,8,9-heptachlorophenaleno[1,9-bc]pyrazole 2 in 69% yield. This compound is the first example of a phenalene fused pyrazole.

Bibliographic Details
Main Authors: Polina K. Demetriadou, Panayiotis A. Koutentis
Format: Article
Language:English
Published: MDPI AG 2009-10-01
Series:Molbank
Subjects:
Online Access:http://www.mdpi.com/1422-8599/2009/4/M625/
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author Polina K. Demetriadou
Panayiotis A. Koutentis
author_facet Polina K. Demetriadou
Panayiotis A. Koutentis
author_sort Polina K. Demetriadou
collection DOAJ
description Treatment of perchloro-7H-cyclopropano[a]acenaphthylene 1 with hydrazine hydrate in DMF at ca. 80 °C gives the new 3,4,5,6,7,8,9-heptachlorophenaleno[1,9-bc]pyrazole 2 in 69% yield. This compound is the first example of a phenalene fused pyrazole.
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spelling doaj.art-f4715e07461f4e90af2b2ea8550436732022-12-22T00:27:26ZengMDPI AGMolbank1422-85992009-10-0120094M62510.3390/M6253,4,5,6,7,8,9-Heptachlorophenaleno[1,9-bc]pyrazolePolina K. DemetriadouPanayiotis A. KoutentisTreatment of perchloro-7H-cyclopropano[a]acenaphthylene 1 with hydrazine hydrate in DMF at ca. 80 °C gives the new 3,4,5,6,7,8,9-heptachlorophenaleno[1,9-bc]pyrazole 2 in 69% yield. This compound is the first example of a phenalene fused pyrazole.http://www.mdpi.com/1422-8599/2009/4/M625/phenalenepyrazolecyclopropane
spellingShingle Polina K. Demetriadou
Panayiotis A. Koutentis
3,4,5,6,7,8,9-Heptachlorophenaleno[1,9-bc]pyrazole
Molbank
phenalene
pyrazole
cyclopropane
title 3,4,5,6,7,8,9-Heptachlorophenaleno[1,9-bc]pyrazole
title_full 3,4,5,6,7,8,9-Heptachlorophenaleno[1,9-bc]pyrazole
title_fullStr 3,4,5,6,7,8,9-Heptachlorophenaleno[1,9-bc]pyrazole
title_full_unstemmed 3,4,5,6,7,8,9-Heptachlorophenaleno[1,9-bc]pyrazole
title_short 3,4,5,6,7,8,9-Heptachlorophenaleno[1,9-bc]pyrazole
title_sort 3 4 5 6 7 8 9 heptachlorophenaleno 1 9 bc pyrazole
topic phenalene
pyrazole
cyclopropane
url http://www.mdpi.com/1422-8599/2009/4/M625/
work_keys_str_mv AT polinakdemetriadou 3456789heptachlorophenaleno19bcpyrazole
AT panayiotisakoutentis 3456789heptachlorophenaleno19bcpyrazole