Investigation of the performances for CFRP composites exposed to different aging environment at nano-scale

The nanomechanical technique was applied to investigate quantitatively the evolution of epoxy matrix and fiber/matrix interface in CFRPs under different hygrothermal conditions (water, seawater and acidic solution at 20, 50 and 80 °C). The moisture penetration depth was originally defined based on t...

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Main Authors: Yi-Fan Niu, Duo-Duo Wang, Jia-Wei Yao
Format: Article
Language:English
Published: Elsevier 2022-12-01
Series:Polymer Testing
Subjects:
Online Access:http://www.sciencedirect.com/science/article/pii/S0142941822002926
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author Yi-Fan Niu
Duo-Duo Wang
Jia-Wei Yao
author_facet Yi-Fan Niu
Duo-Duo Wang
Jia-Wei Yao
author_sort Yi-Fan Niu
collection DOAJ
description The nanomechanical technique was applied to investigate quantitatively the evolution of epoxy matrix and fiber/matrix interface in CFRPs under different hygrothermal conditions (water, seawater and acidic solution at 20, 50 and 80 °C). The moisture penetration depth was originally defined based on the change trend of nanoindentation hardness and elastic modulus from the exposed surface to the center area of sample. The scanned modulus map of composite surface using Peak Force Quantitative Nano-mechanic (PF-QNM)) method was used to deduce the interface thickness. It was found that the moisture uptake of CFRPs in water was higher than that in seawater, but lower than that in acidic solution at the same temperature. High temperature promoted the penetration of water molecules. The moisture penetration depth was about 600 μm for the composites reaching the saturation moisture uptake in the deionized water and seawater at 80 °C, but 800 μm for the composites in the acidic solution. The interface thickness was enlarged with the moisture uptake increasing in water and seawater, which was attributed to the plasticizing effect of water molecules, whereas the acidic solution produced an inverse trend, which might be due to the secondary crosslinking reaction of free radicals.
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spelling doaj.art-f4914aead761415f9f898ff13b5852da2022-12-22T04:29:44ZengElsevierPolymer Testing0142-94182022-12-01116107771Investigation of the performances for CFRP composites exposed to different aging environment at nano-scaleYi-Fan Niu0Duo-Duo Wang1Jia-Wei Yao2Corresponding author.; Sino-European Institute of Aviation Engineering, Civil Aviation University of China, Tianjin, 300300, ChinaSino-European Institute of Aviation Engineering, Civil Aviation University of China, Tianjin, 300300, ChinaSino-European Institute of Aviation Engineering, Civil Aviation University of China, Tianjin, 300300, ChinaThe nanomechanical technique was applied to investigate quantitatively the evolution of epoxy matrix and fiber/matrix interface in CFRPs under different hygrothermal conditions (water, seawater and acidic solution at 20, 50 and 80 °C). The moisture penetration depth was originally defined based on the change trend of nanoindentation hardness and elastic modulus from the exposed surface to the center area of sample. The scanned modulus map of composite surface using Peak Force Quantitative Nano-mechanic (PF-QNM)) method was used to deduce the interface thickness. It was found that the moisture uptake of CFRPs in water was higher than that in seawater, but lower than that in acidic solution at the same temperature. High temperature promoted the penetration of water molecules. The moisture penetration depth was about 600 μm for the composites reaching the saturation moisture uptake in the deionized water and seawater at 80 °C, but 800 μm for the composites in the acidic solution. The interface thickness was enlarged with the moisture uptake increasing in water and seawater, which was attributed to the plasticizing effect of water molecules, whereas the acidic solution produced an inverse trend, which might be due to the secondary crosslinking reaction of free radicals.http://www.sciencedirect.com/science/article/pii/S0142941822002926Carbon fiber reinforced epoxy compositesHygrothermal agingNanomechanical techniquesMoisture uptakeInterface thickness
spellingShingle Yi-Fan Niu
Duo-Duo Wang
Jia-Wei Yao
Investigation of the performances for CFRP composites exposed to different aging environment at nano-scale
Polymer Testing
Carbon fiber reinforced epoxy composites
Hygrothermal aging
Nanomechanical techniques
Moisture uptake
Interface thickness
title Investigation of the performances for CFRP composites exposed to different aging environment at nano-scale
title_full Investigation of the performances for CFRP composites exposed to different aging environment at nano-scale
title_fullStr Investigation of the performances for CFRP composites exposed to different aging environment at nano-scale
title_full_unstemmed Investigation of the performances for CFRP composites exposed to different aging environment at nano-scale
title_short Investigation of the performances for CFRP composites exposed to different aging environment at nano-scale
title_sort investigation of the performances for cfrp composites exposed to different aging environment at nano scale
topic Carbon fiber reinforced epoxy composites
Hygrothermal aging
Nanomechanical techniques
Moisture uptake
Interface thickness
url http://www.sciencedirect.com/science/article/pii/S0142941822002926
work_keys_str_mv AT yifanniu investigationoftheperformancesforcfrpcompositesexposedtodifferentagingenvironmentatnanoscale
AT duoduowang investigationoftheperformancesforcfrpcompositesexposedtodifferentagingenvironmentatnanoscale
AT jiaweiyao investigationoftheperformancesforcfrpcompositesexposedtodifferentagingenvironmentatnanoscale