One conceivable mechanism of UV-light induced SO<sub>2</sub> Oxidation to H<sub>2</sub>SO<sub>4</sub>

The electron-excited chemistry of sulfur dioxide oxidation induced by UV irradiation of air with trace O<sub>3</sub> and SO<sub>2</sub> is considered. The importance of this mechanism is evaluated based on recent laboratory experiments on SO<sub>2</sub> oxidation...

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Main Author: A. Sorokin
Format: Article
Language:English
Published: Copernicus Publications 2010-03-01
Series:Atmospheric Chemistry and Physics
Online Access:http://www.atmos-chem-phys.net/10/3141/2010/acp-10-3141-2010.pdf
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author A. Sorokin
author_facet A. Sorokin
author_sort A. Sorokin
collection DOAJ
description The electron-excited chemistry of sulfur dioxide oxidation induced by UV irradiation of air with trace O<sub>3</sub> and SO<sub>2</sub> is considered. The importance of this mechanism is evaluated based on recent laboratory experiments on SO<sub>2</sub> oxidation in a laminar tube with air induced by UV irradiation. Results show that under respective conditions the route of SO<sub>2</sub> oxidation involving electron excited oxygen molecules may present an additional source of gaseous H<sub>2</sub>SO<sub>4</sub> production to known OH-radical mechanism.
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spelling doaj.art-f4b7db05769945d581b177a3deccf2a82022-12-22T02:49:15ZengCopernicus PublicationsAtmospheric Chemistry and Physics1680-73161680-73242010-03-0110631413145One conceivable mechanism of UV-light induced SO<sub>2</sub> Oxidation to H<sub>2</sub>SO<sub>4</sub>A. SorokinThe electron-excited chemistry of sulfur dioxide oxidation induced by UV irradiation of air with trace O<sub>3</sub> and SO<sub>2</sub> is considered. The importance of this mechanism is evaluated based on recent laboratory experiments on SO<sub>2</sub> oxidation in a laminar tube with air induced by UV irradiation. Results show that under respective conditions the route of SO<sub>2</sub> oxidation involving electron excited oxygen molecules may present an additional source of gaseous H<sub>2</sub>SO<sub>4</sub> production to known OH-radical mechanism.http://www.atmos-chem-phys.net/10/3141/2010/acp-10-3141-2010.pdf
spellingShingle A. Sorokin
One conceivable mechanism of UV-light induced SO<sub>2</sub> Oxidation to H<sub>2</sub>SO<sub>4</sub>
Atmospheric Chemistry and Physics
title One conceivable mechanism of UV-light induced SO<sub>2</sub> Oxidation to H<sub>2</sub>SO<sub>4</sub>
title_full One conceivable mechanism of UV-light induced SO<sub>2</sub> Oxidation to H<sub>2</sub>SO<sub>4</sub>
title_fullStr One conceivable mechanism of UV-light induced SO<sub>2</sub> Oxidation to H<sub>2</sub>SO<sub>4</sub>
title_full_unstemmed One conceivable mechanism of UV-light induced SO<sub>2</sub> Oxidation to H<sub>2</sub>SO<sub>4</sub>
title_short One conceivable mechanism of UV-light induced SO<sub>2</sub> Oxidation to H<sub>2</sub>SO<sub>4</sub>
title_sort one conceivable mechanism of uv light induced so sub 2 sub oxidation to h sub 2 sub so sub 4 sub
url http://www.atmos-chem-phys.net/10/3141/2010/acp-10-3141-2010.pdf
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