One conceivable mechanism of UV-light induced SO<sub>2</sub> Oxidation to H<sub>2</sub>SO<sub>4</sub>
The electron-excited chemistry of sulfur dioxide oxidation induced by UV irradiation of air with trace O<sub>3</sub> and SO<sub>2</sub> is considered. The importance of this mechanism is evaluated based on recent laboratory experiments on SO<sub>2</sub> oxidation...
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Format: | Article |
Language: | English |
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Copernicus Publications
2010-03-01
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Series: | Atmospheric Chemistry and Physics |
Online Access: | http://www.atmos-chem-phys.net/10/3141/2010/acp-10-3141-2010.pdf |
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author | A. Sorokin |
author_facet | A. Sorokin |
author_sort | A. Sorokin |
collection | DOAJ |
description | The electron-excited chemistry of sulfur dioxide oxidation induced by UV irradiation of air with trace O<sub>3</sub> and SO<sub>2</sub> is considered. The importance of this mechanism is evaluated based on recent laboratory experiments on SO<sub>2</sub> oxidation in a laminar tube with air induced by UV irradiation. Results show that under respective conditions the route of SO<sub>2</sub> oxidation involving electron excited oxygen molecules may present an additional source of gaseous H<sub>2</sub>SO<sub>4</sub> production to known OH-radical mechanism. |
first_indexed | 2024-04-13T11:07:13Z |
format | Article |
id | doaj.art-f4b7db05769945d581b177a3deccf2a8 |
institution | Directory Open Access Journal |
issn | 1680-7316 1680-7324 |
language | English |
last_indexed | 2024-04-13T11:07:13Z |
publishDate | 2010-03-01 |
publisher | Copernicus Publications |
record_format | Article |
series | Atmospheric Chemistry and Physics |
spelling | doaj.art-f4b7db05769945d581b177a3deccf2a82022-12-22T02:49:15ZengCopernicus PublicationsAtmospheric Chemistry and Physics1680-73161680-73242010-03-0110631413145One conceivable mechanism of UV-light induced SO<sub>2</sub> Oxidation to H<sub>2</sub>SO<sub>4</sub>A. SorokinThe electron-excited chemistry of sulfur dioxide oxidation induced by UV irradiation of air with trace O<sub>3</sub> and SO<sub>2</sub> is considered. The importance of this mechanism is evaluated based on recent laboratory experiments on SO<sub>2</sub> oxidation in a laminar tube with air induced by UV irradiation. Results show that under respective conditions the route of SO<sub>2</sub> oxidation involving electron excited oxygen molecules may present an additional source of gaseous H<sub>2</sub>SO<sub>4</sub> production to known OH-radical mechanism.http://www.atmos-chem-phys.net/10/3141/2010/acp-10-3141-2010.pdf |
spellingShingle | A. Sorokin One conceivable mechanism of UV-light induced SO<sub>2</sub> Oxidation to H<sub>2</sub>SO<sub>4</sub> Atmospheric Chemistry and Physics |
title | One conceivable mechanism of UV-light induced SO<sub>2</sub> Oxidation to H<sub>2</sub>SO<sub>4</sub> |
title_full | One conceivable mechanism of UV-light induced SO<sub>2</sub> Oxidation to H<sub>2</sub>SO<sub>4</sub> |
title_fullStr | One conceivable mechanism of UV-light induced SO<sub>2</sub> Oxidation to H<sub>2</sub>SO<sub>4</sub> |
title_full_unstemmed | One conceivable mechanism of UV-light induced SO<sub>2</sub> Oxidation to H<sub>2</sub>SO<sub>4</sub> |
title_short | One conceivable mechanism of UV-light induced SO<sub>2</sub> Oxidation to H<sub>2</sub>SO<sub>4</sub> |
title_sort | one conceivable mechanism of uv light induced so sub 2 sub oxidation to h sub 2 sub so sub 4 sub |
url | http://www.atmos-chem-phys.net/10/3141/2010/acp-10-3141-2010.pdf |
work_keys_str_mv | AT asorokin oneconceivablemechanismofuvlightinducedsosub2suboxidationtohsub2subsosub4sub |