Mechanism driven design of trimer Ni1Sb2 site delivering superior hydrogenation selectivity to ethylene
Designing atomically uniform ensemble sites for matching targeted reaction pathway is important yet challenging in heterogeneous catalysis. Here, the authors fabricate a trimer Ni1Sb2 site featuring superior selectivity for acetylene semi-hydrogenation via a mechanism-driven design strategy.
| Main Authors: | , , , , , , , , , , , |
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| Format: | Article |
| Language: | English |
| Published: |
Nature Portfolio
2022-09-01
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| Series: | Nature Communications |
| Online Access: | https://doi.org/10.1038/s41467-022-33250-8 |
| _version_ | 1811265043783745536 |
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| author | Xiaohu Ge Mingying Dou Yueqiang Cao Xi Liu Qiang Yuwen Jing Zhang Gang Qian Xueqing Gong Xinggui Zhou Liwei Chen Weikang Yuan Xuezhi Duan |
| author_facet | Xiaohu Ge Mingying Dou Yueqiang Cao Xi Liu Qiang Yuwen Jing Zhang Gang Qian Xueqing Gong Xinggui Zhou Liwei Chen Weikang Yuan Xuezhi Duan |
| author_sort | Xiaohu Ge |
| collection | DOAJ |
| description | Designing atomically uniform ensemble sites for matching targeted reaction pathway is important yet challenging in heterogeneous catalysis. Here, the authors fabricate a trimer Ni1Sb2 site featuring superior selectivity for acetylene semi-hydrogenation via a mechanism-driven design strategy. |
| first_indexed | 2024-04-12T20:15:26Z |
| format | Article |
| id | doaj.art-f4c20a760a3d4d74830167ba72b3668d |
| institution | Directory Open Access Journal |
| issn | 2041-1723 |
| language | English |
| last_indexed | 2024-04-12T20:15:26Z |
| publishDate | 2022-09-01 |
| publisher | Nature Portfolio |
| record_format | Article |
| series | Nature Communications |
| spelling | doaj.art-f4c20a760a3d4d74830167ba72b3668d2022-12-22T03:18:09ZengNature PortfolioNature Communications2041-17232022-09-0113111310.1038/s41467-022-33250-8Mechanism driven design of trimer Ni1Sb2 site delivering superior hydrogenation selectivity to ethyleneXiaohu Ge0Mingying Dou1Yueqiang Cao2Xi Liu3Qiang Yuwen4Jing Zhang5Gang Qian6Xueqing Gong7Xinggui Zhou8Liwei Chen9Weikang Yuan10Xuezhi Duan11State Key Laboratory of Chemical Engineering, East China University of Science and TechnologyState Key Laboratory of Chemical Engineering, East China University of Science and TechnologyState Key Laboratory of Chemical Engineering, East China University of Science and TechnologySchool of Chemistry and Chemical Engineering, In-situ Center for Physical Sciences, Frontiers Science Center for Transformative Molecules, Shanghai Jiao Tong UniversityState Key Laboratory of Chemical Engineering, East China University of Science and TechnologyState Key Laboratory of Chemical Engineering, East China University of Science and TechnologyState Key Laboratory of Chemical Engineering, East China University of Science and TechnologyKey Laboratory for Advanced Materials, Centre for Computational Chemistry and Research Institute of Industrial Catalysis, East China University of Science and TechnologyState Key Laboratory of Chemical Engineering, East China University of Science and TechnologySchool of Chemistry and Chemical Engineering, In-situ Center for Physical Sciences, Frontiers Science Center for Transformative Molecules, Shanghai Jiao Tong UniversityState Key Laboratory of Chemical Engineering, East China University of Science and TechnologyState Key Laboratory of Chemical Engineering, East China University of Science and TechnologyDesigning atomically uniform ensemble sites for matching targeted reaction pathway is important yet challenging in heterogeneous catalysis. Here, the authors fabricate a trimer Ni1Sb2 site featuring superior selectivity for acetylene semi-hydrogenation via a mechanism-driven design strategy.https://doi.org/10.1038/s41467-022-33250-8 |
| spellingShingle | Xiaohu Ge Mingying Dou Yueqiang Cao Xi Liu Qiang Yuwen Jing Zhang Gang Qian Xueqing Gong Xinggui Zhou Liwei Chen Weikang Yuan Xuezhi Duan Mechanism driven design of trimer Ni1Sb2 site delivering superior hydrogenation selectivity to ethylene Nature Communications |
| title | Mechanism driven design of trimer Ni1Sb2 site delivering superior hydrogenation selectivity to ethylene |
| title_full | Mechanism driven design of trimer Ni1Sb2 site delivering superior hydrogenation selectivity to ethylene |
| title_fullStr | Mechanism driven design of trimer Ni1Sb2 site delivering superior hydrogenation selectivity to ethylene |
| title_full_unstemmed | Mechanism driven design of trimer Ni1Sb2 site delivering superior hydrogenation selectivity to ethylene |
| title_short | Mechanism driven design of trimer Ni1Sb2 site delivering superior hydrogenation selectivity to ethylene |
| title_sort | mechanism driven design of trimer ni1sb2 site delivering superior hydrogenation selectivity to ethylene |
| url | https://doi.org/10.1038/s41467-022-33250-8 |
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