Crystal structure of [1,3-bis(2,4,6-trimethylphenyl)imidazolidin-2-ylidene]dichlorido(2-{[(2-methoxyethyl)(methyl)amino]methyl}benzylidene)ruthenium

Crystal structure of [1,3-bis(2,4,6-trimethylphenyl)imidazolidin-2-ylidene]dichlorido(2-{[(2-methoxyethyl)(methyl)amino]methyl}benzylidene)ruthenium

The title compound, [RuCl2(C33H43N3O)], is an example of a new generation of N,N-dialkyl ruthenium catalysts with an N—Ru coordination bond as part of a six-membered chelate ring. The Ru atom has an Addison τ parameter of 0.244, which indicates a geometry intermediate between square-based pyramidal...

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Bibliographic Details
Main Authors: Gunay Z. Mammadova, Zeliha Atioğlu, Mehmet Akkurt, Mikhail S. Grigoriev, Nikita S. Volchkov, Asmet N. Azizova, Ajaya Bhattarai, Alexandra S. Antonova
Format: Article
Language:English
Published: International Union of Crystallography 2024-01-01
Series:Acta Crystallographica Section E: Crystallographic Communications
Subjects:
crystal structure
ruthenium catalyst
hoveyda–grubbs catalyst
olefin metathesis
Online Access:http://scripts.iucr.org/cgi-bin/paper?S2056989023010381

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