Design of oxygen-doped TiZrHfNbTa refractory high entropy alloys with enhanced strength and ductility

Refractory high entropy alloys (RHEAs) are considered promising materials for high-temperature applications due to their thermal stability and high-temperature mechanical properties. However, most RHEAs have high density (>10 g/cm3) and exhibit limited ductility at low temperatures and softening...

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Bibliographic Details
Main Authors: L.K. Iroc, O.U. Tukac, B.B. Tanrisevdi, O. El-Atwani, M.A. Tunes, Y.E. Kalay, E. Aydogan
Format: Article
Language:English
Published: Elsevier 2022-11-01
Series:Materials & Design
Subjects:
Online Access:http://www.sciencedirect.com/science/article/pii/S0264127522008619
Description
Summary:Refractory high entropy alloys (RHEAs) are considered promising materials for high-temperature applications due to their thermal stability and high-temperature mechanical properties. However, most RHEAs have high density (>10 g/cm3) and exhibit limited ductility at low temperatures and softening at high temperatures. In this study, we show that oxygen-doping can be used as a new alloy design strategy for tailoring the mechanical behavior of the TiZrHfNbTa alloy: a novel low-density (7.98 g/cm3) ductile RHEA. Even though the material is a single-phase BCC with some oxides at room temperature, secondary BCC and HCP nano-lamellar structures start to form above 600 °C in addition to the nano-twins which are shown to be stable up to 1000 °C. This alloy shows superior strength and compressive ductility due to the nanoengineered microstructure. The present study sheds light on tailoring the strength-ductility balance in RHEAs by controlling the microstructure of novel RHEAs at the nanoscale via oxygen-doping.
ISSN:0264-1275