Tetrakis(μ2-3,4-dimethoxyphenylacetato)-κ3O,O′:O′;κ3O:O:O′;κ2O:O′;κ2O:O′-bis[(3,4-dimethoxyphenylacetato-κ2O,O′)(1,10-phenanthroline-κ2N,N)thulium(III)]
In the title centrosymmetric dinuclear complex, [Tm2(C10H11O4)6(C12H8N2)2], the unique TmIII ion is coordinated by five 3,4-dimethoxyphenylacetate (DMPA) ligands and and a bis-chelating 1,10-phenanthroline (phen) ligand via seven O atoms and two N atoms, forming a distorted tricapped trigonal-prisma...
| Main Authors: | , , |
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2010-01-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536809051435 |
| _version_ | 1818894134039019520 |
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| author | Jia-Lu Liu Hua-Qiong Li Guo-Liang Zhao |
| author_facet | Jia-Lu Liu Hua-Qiong Li Guo-Liang Zhao |
| author_sort | Jia-Lu Liu |
| collection | DOAJ |
| description | In the title centrosymmetric dinuclear complex, [Tm2(C10H11O4)6(C12H8N2)2], the unique TmIII ion is coordinated by five 3,4-dimethoxyphenylacetate (DMPA) ligands and and a bis-chelating 1,10-phenanthroline (phen) ligand via seven O atoms and two N atoms, forming a distorted tricapped trigonal-prismatic environment. The DMPA ligands coordinate in the bis-chelate, bridging and bridging tridentate modes. |
| first_indexed | 2024-12-19T18:23:39Z |
| format | Article |
| id | doaj.art-f5045b8f6af3412dad69097b3e9a2b98 |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-19T18:23:39Z |
| publishDate | 2010-01-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-f5045b8f6af3412dad69097b3e9a2b982022-12-21T20:10:54ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682010-01-01661m9m910.1107/S1600536809051435Tetrakis(μ2-3,4-dimethoxyphenylacetato)-κ3O,O′:O′;κ3O:O:O′;κ2O:O′;κ2O:O′-bis[(3,4-dimethoxyphenylacetato-κ2O,O′)(1,10-phenanthroline-κ2N,N)thulium(III)]Jia-Lu LiuHua-Qiong LiGuo-Liang ZhaoIn the title centrosymmetric dinuclear complex, [Tm2(C10H11O4)6(C12H8N2)2], the unique TmIII ion is coordinated by five 3,4-dimethoxyphenylacetate (DMPA) ligands and and a bis-chelating 1,10-phenanthroline (phen) ligand via seven O atoms and two N atoms, forming a distorted tricapped trigonal-prismatic environment. The DMPA ligands coordinate in the bis-chelate, bridging and bridging tridentate modes.http://scripts.iucr.org/cgi-bin/paper?S1600536809051435 |
| spellingShingle | Jia-Lu Liu Hua-Qiong Li Guo-Liang Zhao Tetrakis(μ2-3,4-dimethoxyphenylacetato)-κ3O,O′:O′;κ3O:O:O′;κ2O:O′;κ2O:O′-bis[(3,4-dimethoxyphenylacetato-κ2O,O′)(1,10-phenanthroline-κ2N,N)thulium(III)] Acta Crystallographica Section E |
| title | Tetrakis(μ2-3,4-dimethoxyphenylacetato)-κ3O,O′:O′;κ3O:O:O′;κ2O:O′;κ2O:O′-bis[(3,4-dimethoxyphenylacetato-κ2O,O′)(1,10-phenanthroline-κ2N,N)thulium(III)] |
| title_full | Tetrakis(μ2-3,4-dimethoxyphenylacetato)-κ3O,O′:O′;κ3O:O:O′;κ2O:O′;κ2O:O′-bis[(3,4-dimethoxyphenylacetato-κ2O,O′)(1,10-phenanthroline-κ2N,N)thulium(III)] |
| title_fullStr | Tetrakis(μ2-3,4-dimethoxyphenylacetato)-κ3O,O′:O′;κ3O:O:O′;κ2O:O′;κ2O:O′-bis[(3,4-dimethoxyphenylacetato-κ2O,O′)(1,10-phenanthroline-κ2N,N)thulium(III)] |
| title_full_unstemmed | Tetrakis(μ2-3,4-dimethoxyphenylacetato)-κ3O,O′:O′;κ3O:O:O′;κ2O:O′;κ2O:O′-bis[(3,4-dimethoxyphenylacetato-κ2O,O′)(1,10-phenanthroline-κ2N,N)thulium(III)] |
| title_short | Tetrakis(μ2-3,4-dimethoxyphenylacetato)-κ3O,O′:O′;κ3O:O:O′;κ2O:O′;κ2O:O′-bis[(3,4-dimethoxyphenylacetato-κ2O,O′)(1,10-phenanthroline-κ2N,N)thulium(III)] |
| title_sort | tetrakis amp 956 2 3 4 dimethoxyphenylacetato amp 954 3o o amp 8242 o amp 8242 amp 954 3o o o amp 8242 amp 954 2o o amp 8242 amp 954 2o o amp 8242 bis 3 4 dimethoxyphenylacetato amp 954 2o o amp 8242 1 10 phenanthroline amp 954 2n n thulium iii |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536809051435 |
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