Influence of the Zeolite ZSM-5 on Catalytic Pyrolysis of Biomass via TG-FTIR
Bio-oil from the pyrolysis of biomass is an important renewable source for liquid fuel. However, the application of bio-oil has been severely restricted due to its high viscosity, acidity, and low heating value. Thus, it has been necessary to upgrade bio-oil for automobile fuel via catalytic deoxyge...
| Main Authors: | , , , |
|---|---|
| Format: | Article |
| Language: | English |
| Published: |
North Carolina State University
2015-06-01
|
| Series: | BioResources |
| Subjects: | |
| Online Access: | http://ojs.cnr.ncsu.edu/index.php/BioRes/article/view/BioRes_10_3_4485_Wang_Influence_Zeolite_Pyrolysis_Biomass |
| _version_ | 1818407599657189376 |
|---|---|
| author | Ze Wang Siwei Liu Weigang Lin Wenli Song |
| author_facet | Ze Wang Siwei Liu Weigang Lin Wenli Song |
| author_sort | Ze Wang |
| collection | DOAJ |
| description | Bio-oil from the pyrolysis of biomass is an important renewable source for liquid fuel. However, the application of bio-oil has been severely restricted due to its high viscosity, acidity, and low heating value. Thus, it has been necessary to upgrade bio-oil for automobile fuel via catalytic deoxygenation reactions. Herein, the effects of the zeolite ZSM-5 on the pyrolysis of four biomass materials (corn cob, corn straw, pine powder, and cellulose) were investigated via TG-FTIR (thermogravimetric analyzer coupled with a Fourier transform infrared spectrometer) to better understand the working mechanism of ZSM-5. The contents of the products of H2O, CO, CO2, and the C-O, C=O, and OH groups evolved with increasing pyrolytic temperature were monitored by FTIR. It was found that the relative contents of the C-O and C=O groups were decreased under the catalysis of ZSM-5, while the formations of CO, H2O, and the OH containing compounds were promoted. To explain the regulations, reaction routes were speculated and the catalytic conversion mechanisms were deduced. |
| first_indexed | 2024-12-14T09:30:24Z |
| format | Article |
| id | doaj.art-f523e8a06aec4eb59eca9f65ad16242a |
| institution | Directory Open Access Journal |
| issn | 1930-2126 1930-2126 |
| language | English |
| last_indexed | 2024-12-14T09:30:24Z |
| publishDate | 2015-06-01 |
| publisher | North Carolina State University |
| record_format | Article |
| series | BioResources |
| spelling | doaj.art-f523e8a06aec4eb59eca9f65ad16242a2022-12-21T23:08:05ZengNorth Carolina State UniversityBioResources1930-21261930-21262015-06-011034485449710.15376/biores.10.3.4485-4497Influence of the Zeolite ZSM-5 on Catalytic Pyrolysis of Biomass via TG-FTIRZe Wang0Siwei Liu1Weigang Lin2Wenli Song3 Institute of Process Engineering, CAS; China Institute of Process Engineering, CAS; China Institute of Process Engineering, CAS; China Institute of Process Engineering, CAS; ChinaBio-oil from the pyrolysis of biomass is an important renewable source for liquid fuel. However, the application of bio-oil has been severely restricted due to its high viscosity, acidity, and low heating value. Thus, it has been necessary to upgrade bio-oil for automobile fuel via catalytic deoxygenation reactions. Herein, the effects of the zeolite ZSM-5 on the pyrolysis of four biomass materials (corn cob, corn straw, pine powder, and cellulose) were investigated via TG-FTIR (thermogravimetric analyzer coupled with a Fourier transform infrared spectrometer) to better understand the working mechanism of ZSM-5. The contents of the products of H2O, CO, CO2, and the C-O, C=O, and OH groups evolved with increasing pyrolytic temperature were monitored by FTIR. It was found that the relative contents of the C-O and C=O groups were decreased under the catalysis of ZSM-5, while the formations of CO, H2O, and the OH containing compounds were promoted. To explain the regulations, reaction routes were speculated and the catalytic conversion mechanisms were deduced.http://ojs.cnr.ncsu.edu/index.php/BioRes/article/view/BioRes_10_3_4485_Wang_Influence_Zeolite_Pyrolysis_BiomassBiomasUpgradingCatalysisMechanismZSM-5 |
| spellingShingle | Ze Wang Siwei Liu Weigang Lin Wenli Song Influence of the Zeolite ZSM-5 on Catalytic Pyrolysis of Biomass via TG-FTIR BioResources Biomas Upgrading Catalysis Mechanism ZSM-5 |
| title | Influence of the Zeolite ZSM-5 on Catalytic Pyrolysis of Biomass via TG-FTIR |
| title_full | Influence of the Zeolite ZSM-5 on Catalytic Pyrolysis of Biomass via TG-FTIR |
| title_fullStr | Influence of the Zeolite ZSM-5 on Catalytic Pyrolysis of Biomass via TG-FTIR |
| title_full_unstemmed | Influence of the Zeolite ZSM-5 on Catalytic Pyrolysis of Biomass via TG-FTIR |
| title_short | Influence of the Zeolite ZSM-5 on Catalytic Pyrolysis of Biomass via TG-FTIR |
| title_sort | influence of the zeolite zsm 5 on catalytic pyrolysis of biomass via tg ftir |
| topic | Biomas Upgrading Catalysis Mechanism ZSM-5 |
| url | http://ojs.cnr.ncsu.edu/index.php/BioRes/article/view/BioRes_10_3_4485_Wang_Influence_Zeolite_Pyrolysis_Biomass |
| work_keys_str_mv | AT zewang influenceofthezeolitezsm5oncatalyticpyrolysisofbiomassviatgftir AT siweiliu influenceofthezeolitezsm5oncatalyticpyrolysisofbiomassviatgftir AT weiganglin influenceofthezeolitezsm5oncatalyticpyrolysisofbiomassviatgftir AT wenlisong influenceofthezeolitezsm5oncatalyticpyrolysisofbiomassviatgftir |