Surface modified Acacia Senegal Gum based spherical hydrogel; fabrication, characterization, and kinetically optimized waste water treatment with remarkable adsorption efficiency
Acacia Senegal Gum hydrogel (HASG) with swollen dimension less than 50 μm were fabricated, and chemically modified with versatile diethylenetriamine (d-amine) to tailor the surface properties for environmental remediation.Negatively charged metal ions, for example, chromate (Cr(III)), dichromate (Cr...
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| Format: | Article |
| Language: | English |
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Elsevier
2023-06-01
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| Series: | Heliyon |
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| Online Access: | http://www.sciencedirect.com/science/article/pii/S2405844023044055 |
| _version_ | 1797802822817808384 |
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| author | Rasha M.K. Mohamed |
| author_facet | Rasha M.K. Mohamed |
| author_sort | Rasha M.K. Mohamed |
| collection | DOAJ |
| description | Acacia Senegal Gum hydrogel (HASG) with swollen dimension less than 50 μm were fabricated, and chemically modified with versatile diethylenetriamine (d-amine) to tailor the surface properties for environmental remediation.Negatively charged metal ions, for example, chromate (Cr(III)), dichromate (Cr(VI)), and arsenate (As(V)) were removed from aqueous media by using modified hydrogels (m-HASG). The FT-IR spectra revealed some new peaks due to d-amine treatment. The zeta potential measurements confirm a positively charged surface of HASG upon d-amine modification at ambient conditions. The absorption studies revealed that 0.05 g feed of m-(HASG) possesses 69.8, 99.3, and 40.00% cleaning potential against As(V), Cr(VI), and Cr(III), respectively with 2 h contact time in deionized water. Almost comparable adsorption efficiency was achieved by the prepared hydrogels towards the targeted analytes dissolved in real water samples. Adsorption isotherms, for example, Langmuir, Freundlich and modified Freundlich isotherms were applied to the collected data. Briefly, Modified Freundlich isotherm manifested comparatively agreeable line for the all adsorbents pollutants with highest R2 figure.In addition, maximum adsorption capacity (Qm) with 217, 256, and 271 mg g−1 numerical values were obtained against As(V), Cr(VI), and Cr(III), respectively. In real water samples, 217, 256, and 271 mg g−1 adsorption capacity was represented by m-(HASG).In brief, m-(HASG) is a brilliant material for environmental application as cleaner candidate towards toxic metal ions. |
| first_indexed | 2024-03-13T05:11:31Z |
| format | Article |
| id | doaj.art-f52ad7777edd4cf6a7ba98ed4026c3dd |
| institution | Directory Open Access Journal |
| issn | 2405-8440 |
| language | English |
| last_indexed | 2024-03-13T05:11:31Z |
| publishDate | 2023-06-01 |
| publisher | Elsevier |
| record_format | Article |
| series | Heliyon |
| spelling | doaj.art-f52ad7777edd4cf6a7ba98ed4026c3dd2023-06-16T05:10:23ZengElsevierHeliyon2405-84402023-06-0196e17197Surface modified Acacia Senegal Gum based spherical hydrogel; fabrication, characterization, and kinetically optimized waste water treatment with remarkable adsorption efficiencyRasha M.K. Mohamed0Department of Chemistry, College of Science, Jouf University, P.O. Box: 2014, Sakaka, Saudi Arabia; Department of Chemistry, Faculty of Science, Assiut University, P.O. Box: 71515, Assiut, EgyptAcacia Senegal Gum hydrogel (HASG) with swollen dimension less than 50 μm were fabricated, and chemically modified with versatile diethylenetriamine (d-amine) to tailor the surface properties for environmental remediation.Negatively charged metal ions, for example, chromate (Cr(III)), dichromate (Cr(VI)), and arsenate (As(V)) were removed from aqueous media by using modified hydrogels (m-HASG). The FT-IR spectra revealed some new peaks due to d-amine treatment. The zeta potential measurements confirm a positively charged surface of HASG upon d-amine modification at ambient conditions. The absorption studies revealed that 0.05 g feed of m-(HASG) possesses 69.8, 99.3, and 40.00% cleaning potential against As(V), Cr(VI), and Cr(III), respectively with 2 h contact time in deionized water. Almost comparable adsorption efficiency was achieved by the prepared hydrogels towards the targeted analytes dissolved in real water samples. Adsorption isotherms, for example, Langmuir, Freundlich and modified Freundlich isotherms were applied to the collected data. Briefly, Modified Freundlich isotherm manifested comparatively agreeable line for the all adsorbents pollutants with highest R2 figure.In addition, maximum adsorption capacity (Qm) with 217, 256, and 271 mg g−1 numerical values were obtained against As(V), Cr(VI), and Cr(III), respectively. In real water samples, 217, 256, and 271 mg g−1 adsorption capacity was represented by m-(HASG).In brief, m-(HASG) is a brilliant material for environmental application as cleaner candidate towards toxic metal ions.http://www.sciencedirect.com/science/article/pii/S2405844023044055Acacia Senegal GumHASGm-(HASG)Cr(III)/Cr(VI)/As(V)Pollutant removal |
| spellingShingle | Rasha M.K. Mohamed Surface modified Acacia Senegal Gum based spherical hydrogel; fabrication, characterization, and kinetically optimized waste water treatment with remarkable adsorption efficiency Heliyon Acacia Senegal Gum HASG m-(HASG) Cr(III)/Cr(VI)/As(V) Pollutant removal |
| title | Surface modified Acacia Senegal Gum based spherical hydrogel; fabrication, characterization, and kinetically optimized waste water treatment with remarkable adsorption efficiency |
| title_full | Surface modified Acacia Senegal Gum based spherical hydrogel; fabrication, characterization, and kinetically optimized waste water treatment with remarkable adsorption efficiency |
| title_fullStr | Surface modified Acacia Senegal Gum based spherical hydrogel; fabrication, characterization, and kinetically optimized waste water treatment with remarkable adsorption efficiency |
| title_full_unstemmed | Surface modified Acacia Senegal Gum based spherical hydrogel; fabrication, characterization, and kinetically optimized waste water treatment with remarkable adsorption efficiency |
| title_short | Surface modified Acacia Senegal Gum based spherical hydrogel; fabrication, characterization, and kinetically optimized waste water treatment with remarkable adsorption efficiency |
| title_sort | surface modified acacia senegal gum based spherical hydrogel fabrication characterization and kinetically optimized waste water treatment with remarkable adsorption efficiency |
| topic | Acacia Senegal Gum HASG m-(HASG) Cr(III)/Cr(VI)/As(V) Pollutant removal |
| url | http://www.sciencedirect.com/science/article/pii/S2405844023044055 |
| work_keys_str_mv | AT rashamkmohamed surfacemodifiedacaciasenegalgumbasedsphericalhydrogelfabricationcharacterizationandkineticallyoptimizedwastewatertreatmentwithremarkableadsorptionefficiency |