Quarry Residue: Treatment of Industrial Effluent Containing Dye

This work is devoted to the investigation of the discoloration of the synthetic and industrial effluent, using a quarry residue (MbP), which is a material naturally composed of mixed oxides, compared to zinc oxide (ZnO), acting as photocatalysts and adsorbents. The optimization of the pH and catalys...

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Main Authors: Lariana Negrão Beraldo de Almeida, Tatiana Gulminie Josué, Othavio Henrique Lupepsa Nogueira, Daniele Toniolo Dias, Angelo Marcelo Tusset, Onélia Aparecida Andreo dos Santos, Giane Gonçalves Lenzi
Format: Article
Language:English
Published: MDPI AG 2021-07-01
Series:Catalysts
Subjects:
Online Access:https://www.mdpi.com/2073-4344/11/7/852
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author Lariana Negrão Beraldo de Almeida
Tatiana Gulminie Josué
Othavio Henrique Lupepsa Nogueira
Daniele Toniolo Dias
Angelo Marcelo Tusset
Onélia Aparecida Andreo dos Santos
Giane Gonçalves Lenzi
author_facet Lariana Negrão Beraldo de Almeida
Tatiana Gulminie Josué
Othavio Henrique Lupepsa Nogueira
Daniele Toniolo Dias
Angelo Marcelo Tusset
Onélia Aparecida Andreo dos Santos
Giane Gonçalves Lenzi
author_sort Lariana Negrão Beraldo de Almeida
collection DOAJ
description This work is devoted to the investigation of the discoloration of the synthetic and industrial effluent, using a quarry residue (MbP), which is a material naturally composed of mixed oxides, compared to zinc oxide (ZnO), acting as photocatalysts and adsorbents. The optimization of the pH and catalyst concentration parameters was carried out, and the industrial effluent was then treated by photocatalytic reactions, adsorption, and photolysis. Industrial effluent was supplied by a packaging company and was collected for a period of seven consecutive days, showing the oscillation of the parameters in the process. The material characterizations were obtained by scanning electron microscopy (SEM-EDS), X-Ray diffraction (XRD), and photoacoustic spectroscopy (PAS). The results indicated that the composition of the quarry waste is mainly silica and has E<sub>gap</sub> 2.16 eV. The quarry residue as photocatalyst was active for the artificial effluent (synthetic dye solution), with a maximum of 98% discoloration, and as an adsorbent for industrial effluent, with a maximum of 57% of discoloration. Although the quarry residue has shown results lower than ZnO, it is considered a promising material in adsorption processes and photocatalytic reactions for discoloration of aqueous solutions.
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spelling doaj.art-f53773a0138345c7897a71c333fe1acc2023-11-22T03:27:32ZengMDPI AGCatalysts2073-43442021-07-0111785210.3390/catal11070852Quarry Residue: Treatment of Industrial Effluent Containing DyeLariana Negrão Beraldo de Almeida0Tatiana Gulminie Josué1Othavio Henrique Lupepsa Nogueira2Daniele Toniolo Dias3Angelo Marcelo Tusset4Onélia Aparecida Andreo dos Santos5Giane Gonçalves Lenzi6Departamento de Engenharia Química, Universidade Estadual de Maringá, 5790, Maringá 87020-900, BrazilDepartamento de Engenharia Química, Universidade Tecnológica Federal do Paraná, Rua Doutor Washington Subtil Chueire, 330, Ponta Grossa 84016-210, BrazilDepartamento de Engenharia Química, Universidade Tecnológica Federal do Paraná, Rua Doutor Washington Subtil Chueire, 330, Ponta Grossa 84016-210, BrazilDepartamento Acadêmico de Física, Universidade Tecnológica Federal do Paraná, Rua Doutor Washington Subtil Chueire, 330, Ponta Grossa 84016-210, BrazilDepartamento de Engenharia, Universidade Tecnológica Federal do Paraná, Rua Doutor Washington Subtil Chueire, 330, Ponta Grossa 84016-210, BrazilDepartamento de Engenharia Química, Universidade Estadual de Maringá, 5790, Maringá 87020-900, BrazilDepartamento de Engenharia Química, Universidade Tecnológica Federal do Paraná, Rua Doutor Washington Subtil Chueire, 330, Ponta Grossa 84016-210, BrazilThis work is devoted to the investigation of the discoloration of the synthetic and industrial effluent, using a quarry residue (MbP), which is a material naturally composed of mixed oxides, compared to zinc oxide (ZnO), acting as photocatalysts and adsorbents. The optimization of the pH and catalyst concentration parameters was carried out, and the industrial effluent was then treated by photocatalytic reactions, adsorption, and photolysis. Industrial effluent was supplied by a packaging company and was collected for a period of seven consecutive days, showing the oscillation of the parameters in the process. The material characterizations were obtained by scanning electron microscopy (SEM-EDS), X-Ray diffraction (XRD), and photoacoustic spectroscopy (PAS). The results indicated that the composition of the quarry waste is mainly silica and has E<sub>gap</sub> 2.16 eV. The quarry residue as photocatalyst was active for the artificial effluent (synthetic dye solution), with a maximum of 98% discoloration, and as an adsorbent for industrial effluent, with a maximum of 57% of discoloration. Although the quarry residue has shown results lower than ZnO, it is considered a promising material in adsorption processes and photocatalytic reactions for discoloration of aqueous solutions.https://www.mdpi.com/2073-4344/11/7/852adsorptionphotolysisphotocatalysisquarry residuediscolorationpackaging industry
spellingShingle Lariana Negrão Beraldo de Almeida
Tatiana Gulminie Josué
Othavio Henrique Lupepsa Nogueira
Daniele Toniolo Dias
Angelo Marcelo Tusset
Onélia Aparecida Andreo dos Santos
Giane Gonçalves Lenzi
Quarry Residue: Treatment of Industrial Effluent Containing Dye
Catalysts
adsorption
photolysis
photocatalysis
quarry residue
discoloration
packaging industry
title Quarry Residue: Treatment of Industrial Effluent Containing Dye
title_full Quarry Residue: Treatment of Industrial Effluent Containing Dye
title_fullStr Quarry Residue: Treatment of Industrial Effluent Containing Dye
title_full_unstemmed Quarry Residue: Treatment of Industrial Effluent Containing Dye
title_short Quarry Residue: Treatment of Industrial Effluent Containing Dye
title_sort quarry residue treatment of industrial effluent containing dye
topic adsorption
photolysis
photocatalysis
quarry residue
discoloration
packaging industry
url https://www.mdpi.com/2073-4344/11/7/852
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AT tatianagulminiejosue quarryresiduetreatmentofindustrialeffluentcontainingdye
AT othaviohenriquelupepsanogueira quarryresiduetreatmentofindustrialeffluentcontainingdye
AT danieletoniolodias quarryresiduetreatmentofindustrialeffluentcontainingdye
AT angelomarcelotusset quarryresiduetreatmentofindustrialeffluentcontainingdye
AT oneliaaparecidaandreodossantos quarryresiduetreatmentofindustrialeffluentcontainingdye
AT gianegoncalveslenzi quarryresiduetreatmentofindustrialeffluentcontainingdye