Di-μ2-chlorido-bis[chlorido(η5-2,3,4,5-tetramethyl-1-propylcyclopentadienyl)iridium(III)]
The asymmetric unit of the title complex, [Ir2Cl4(C12H19)2], a versatile starting material for the preparation of uniquely substituted pentaalkylcyclopentadienyl–iridium complexes, consists of an iridium(III) atom, a substituted cyclopentadienyl ligand and two chlorine ligands. The full di...
| Main Authors: | , , |
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2013-03-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536813005072 |
| _version_ | 1818957919183437824 |
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| author | Nicholas De Weerd David Morris Joseph S. Merola |
| author_facet | Nicholas De Weerd David Morris Joseph S. Merola |
| author_sort | Nicholas De Weerd |
| collection | DOAJ |
| description | The asymmetric unit of the title complex, [Ir2Cl4(C12H19)2], a versatile starting material for the preparation of uniquely substituted pentaalkylcyclopentadienyl–iridium complexes, consists of an iridium(III) atom, a substituted cyclopentadienyl ligand and two chlorine ligands. The full dimer is generated by an inversion center. In the dimer, the two IrIII atoms and two bridging Cl atoms form a perfectly planar ring. The two IrIII atoms and the two terminal Cl atoms also form a rigorous plane that is orthogonal [89.48 (3)°] to the Ir2Cl2 ring. The plane of the cyclopentadienyl ligand forms a dihedral angle of 54.06 (7)° with respect to the Ir2Cl2 ring. |
| first_indexed | 2024-12-20T11:17:30Z |
| format | Article |
| id | doaj.art-f5590f5b68db4c78aeffaf6cd356d2e5 |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-20T11:17:30Z |
| publishDate | 2013-03-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-f5590f5b68db4c78aeffaf6cd356d2e52022-12-21T19:42:34ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682013-03-01693m176m17610.1107/S1600536813005072Di-μ2-chlorido-bis[chlorido(η5-2,3,4,5-tetramethyl-1-propylcyclopentadienyl)iridium(III)]Nicholas De WeerdDavid MorrisJoseph S. MerolaThe asymmetric unit of the title complex, [Ir2Cl4(C12H19)2], a versatile starting material for the preparation of uniquely substituted pentaalkylcyclopentadienyl–iridium complexes, consists of an iridium(III) atom, a substituted cyclopentadienyl ligand and two chlorine ligands. The full dimer is generated by an inversion center. In the dimer, the two IrIII atoms and two bridging Cl atoms form a perfectly planar ring. The two IrIII atoms and the two terminal Cl atoms also form a rigorous plane that is orthogonal [89.48 (3)°] to the Ir2Cl2 ring. The plane of the cyclopentadienyl ligand forms a dihedral angle of 54.06 (7)° with respect to the Ir2Cl2 ring.http://scripts.iucr.org/cgi-bin/paper?S1600536813005072 |
| spellingShingle | Nicholas De Weerd David Morris Joseph S. Merola Di-μ2-chlorido-bis[chlorido(η5-2,3,4,5-tetramethyl-1-propylcyclopentadienyl)iridium(III)] Acta Crystallographica Section E |
| title | Di-μ2-chlorido-bis[chlorido(η5-2,3,4,5-tetramethyl-1-propylcyclopentadienyl)iridium(III)] |
| title_full | Di-μ2-chlorido-bis[chlorido(η5-2,3,4,5-tetramethyl-1-propylcyclopentadienyl)iridium(III)] |
| title_fullStr | Di-μ2-chlorido-bis[chlorido(η5-2,3,4,5-tetramethyl-1-propylcyclopentadienyl)iridium(III)] |
| title_full_unstemmed | Di-μ2-chlorido-bis[chlorido(η5-2,3,4,5-tetramethyl-1-propylcyclopentadienyl)iridium(III)] |
| title_short | Di-μ2-chlorido-bis[chlorido(η5-2,3,4,5-tetramethyl-1-propylcyclopentadienyl)iridium(III)] |
| title_sort | di 956 2 chlorido bis chlorido 951 5 2 3 4 5 tetramethyl 1 propylcyclopentadienyl iridium iii |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536813005072 |
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