N,N-Dimethyl-2-[(1E)-({[(methylsulfanyl)methanethioyl]amino}imino)methyl]aniline
In the title compound, C11H15N3S2, the dithiocarbazate moiety is rotated by 18.73 (8)° with respect to the benzene ring. The dithiocarbazate group adopts an E configuration with respect to the C=N bond of the benzylidene group. Furthermore, in the solid state the compound exists in the thione tautom...
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2018-03-01
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| Series: | IUCrData |
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| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S2414314618004613 |
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| author | Winaki P. Sohtun Arunachalam Kannan Saravanan Dhandayutham Marappan Velusamy |
| author_facet | Winaki P. Sohtun Arunachalam Kannan Saravanan Dhandayutham Marappan Velusamy |
| author_sort | Winaki P. Sohtun |
| collection | DOAJ |
| description | In the title compound, C11H15N3S2, the dithiocarbazate moiety is rotated by 18.73 (8)° with respect to the benzene ring. The dithiocarbazate group adopts an E configuration with respect to the C=N bond of the benzylidene group. Furthermore, in the solid state the compound exists in the thione tautomeric form. In the crystal, molecules are linked by pairs of weak N—H...S hydrogen bonds, forming inversion dimers which are arranged in layers parallel to (010). |
| first_indexed | 2024-12-13T17:07:16Z |
| format | Article |
| id | doaj.art-f56c8d65f3ac4529bb3159089b04f800 |
| institution | Directory Open Access Journal |
| issn | 2414-3146 |
| language | English |
| last_indexed | 2024-12-13T17:07:16Z |
| publishDate | 2018-03-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | IUCrData |
| spelling | doaj.art-f56c8d65f3ac4529bb3159089b04f8002022-12-21T23:37:40ZengInternational Union of CrystallographyIUCrData2414-31462018-03-0133x18046110.1107/S2414314618004613bt4068N,N-Dimethyl-2-[(1E)-({[(methylsulfanyl)methanethioyl]amino}imino)methyl]anilineWinaki P. Sohtun0Arunachalam Kannan1Saravanan Dhandayutham2Marappan Velusamy3Department of Chemistry, North Eastern Hill University, Shillong 793 022, Meghalaya, IndiaDepartment of Chemistry, National College, Tiruchirappalli 620 001, Tamilnadu, IndiaDepartment of Chemistry, National College, Tiruchirappalli 620 001, Tamilnadu, IndiaDepartment of Chemistry, North Eastern Hill University, Shillong 793 022, Meghalaya, IndiaIn the title compound, C11H15N3S2, the dithiocarbazate moiety is rotated by 18.73 (8)° with respect to the benzene ring. The dithiocarbazate group adopts an E configuration with respect to the C=N bond of the benzylidene group. Furthermore, in the solid state the compound exists in the thione tautomeric form. In the crystal, molecules are linked by pairs of weak N—H...S hydrogen bonds, forming inversion dimers which are arranged in layers parallel to (010).http://scripts.iucr.org/cgi-bin/paper?S2414314618004613Schiff basedithiocarbazateligandcrystal structure |
| spellingShingle | Winaki P. Sohtun Arunachalam Kannan Saravanan Dhandayutham Marappan Velusamy N,N-Dimethyl-2-[(1E)-({[(methylsulfanyl)methanethioyl]amino}imino)methyl]aniline IUCrData Schiff base dithiocarbazate ligand crystal structure |
| title | N,N-Dimethyl-2-[(1E)-({[(methylsulfanyl)methanethioyl]amino}imino)methyl]aniline |
| title_full | N,N-Dimethyl-2-[(1E)-({[(methylsulfanyl)methanethioyl]amino}imino)methyl]aniline |
| title_fullStr | N,N-Dimethyl-2-[(1E)-({[(methylsulfanyl)methanethioyl]amino}imino)methyl]aniline |
| title_full_unstemmed | N,N-Dimethyl-2-[(1E)-({[(methylsulfanyl)methanethioyl]amino}imino)methyl]aniline |
| title_short | N,N-Dimethyl-2-[(1E)-({[(methylsulfanyl)methanethioyl]amino}imino)methyl]aniline |
| title_sort | n n dimethyl 2 1e methylsulfanyl methanethioyl amino imino methyl aniline |
| topic | Schiff base dithiocarbazate ligand crystal structure |
| url | http://scripts.iucr.org/cgi-bin/paper?S2414314618004613 |
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