Controlled Two-Step Formation of Faceted Perovskite Rare-Earth Scandate Nanoparticles
A general approach to the formation of well-faceted nanoparticles is discussed and successfully applied to the production of several rare-earth scandates. Two steps were used, with higher temperatures first to nucleate the perovskite phase, followed by lower temperatures to smooth the particle surfa...
Main Authors: | , , , , |
---|---|
Format: | Article |
Language: | English |
Published: |
MDPI AG
2019-04-01
|
Series: | Crystals |
Subjects: | |
Online Access: | https://www.mdpi.com/2073-4352/9/4/218 |
_version_ | 1811306222394015744 |
---|---|
author | Ryan J. Paull Tiffany Ly Zachary R. Mansley Kenneth R. Poeppelmeier Laurence D. Marks |
author_facet | Ryan J. Paull Tiffany Ly Zachary R. Mansley Kenneth R. Poeppelmeier Laurence D. Marks |
author_sort | Ryan J. Paull |
collection | DOAJ |
description | A general approach to the formation of well-faceted nanoparticles is discussed and successfully applied to the production of several rare-earth scandates. Two steps were used, with higher temperatures first to nucleate the perovskite phase, followed by lower temperatures to smooth the particle surfaces. Exploiting these two different regimes led to smaller nanoparticles with more faceting. This general approach may be tailored to other material systems as a step towards producing shape-controlled nanoparticles for a desired application. |
first_indexed | 2024-04-13T08:40:35Z |
format | Article |
id | doaj.art-f5891b8d2a0c4651a2cfa9b112270d8d |
institution | Directory Open Access Journal |
issn | 2073-4352 |
language | English |
last_indexed | 2024-04-13T08:40:35Z |
publishDate | 2019-04-01 |
publisher | MDPI AG |
record_format | Article |
series | Crystals |
spelling | doaj.art-f5891b8d2a0c4651a2cfa9b112270d8d2022-12-22T02:53:55ZengMDPI AGCrystals2073-43522019-04-019421810.3390/cryst9040218cryst9040218Controlled Two-Step Formation of Faceted Perovskite Rare-Earth Scandate NanoparticlesRyan J. Paull0Tiffany Ly1Zachary R. Mansley2Kenneth R. Poeppelmeier3Laurence D. Marks4Department of Materials Science and Engineering, Northwestern University, Evanston, IL 60208, USADepartment of Materials Science and Engineering, Northwestern University, Evanston, IL 60208, USADepartment of Materials Science and Engineering, Northwestern University, Evanston, IL 60208, USADepartment of Chemistry, Northwestern University, Evanston, IL 60208, USADepartment of Materials Science and Engineering, Northwestern University, Evanston, IL 60208, USAA general approach to the formation of well-faceted nanoparticles is discussed and successfully applied to the production of several rare-earth scandates. Two steps were used, with higher temperatures first to nucleate the perovskite phase, followed by lower temperatures to smooth the particle surfaces. Exploiting these two different regimes led to smaller nanoparticles with more faceting. This general approach may be tailored to other material systems as a step towards producing shape-controlled nanoparticles for a desired application.https://www.mdpi.com/2073-4352/9/4/218rare-earth scandateperovskitenucleation and growth |
spellingShingle | Ryan J. Paull Tiffany Ly Zachary R. Mansley Kenneth R. Poeppelmeier Laurence D. Marks Controlled Two-Step Formation of Faceted Perovskite Rare-Earth Scandate Nanoparticles Crystals rare-earth scandate perovskite nucleation and growth |
title | Controlled Two-Step Formation of Faceted Perovskite Rare-Earth Scandate Nanoparticles |
title_full | Controlled Two-Step Formation of Faceted Perovskite Rare-Earth Scandate Nanoparticles |
title_fullStr | Controlled Two-Step Formation of Faceted Perovskite Rare-Earth Scandate Nanoparticles |
title_full_unstemmed | Controlled Two-Step Formation of Faceted Perovskite Rare-Earth Scandate Nanoparticles |
title_short | Controlled Two-Step Formation of Faceted Perovskite Rare-Earth Scandate Nanoparticles |
title_sort | controlled two step formation of faceted perovskite rare earth scandate nanoparticles |
topic | rare-earth scandate perovskite nucleation and growth |
url | https://www.mdpi.com/2073-4352/9/4/218 |
work_keys_str_mv | AT ryanjpaull controlledtwostepformationoffacetedperovskiterareearthscandatenanoparticles AT tiffanyly controlledtwostepformationoffacetedperovskiterareearthscandatenanoparticles AT zacharyrmansley controlledtwostepformationoffacetedperovskiterareearthscandatenanoparticles AT kennethrpoeppelmeier controlledtwostepformationoffacetedperovskiterareearthscandatenanoparticles AT laurencedmarks controlledtwostepformationoffacetedperovskiterareearthscandatenanoparticles |