Controlled Two-Step Formation of Faceted Perovskite Rare-Earth Scandate Nanoparticles

A general approach to the formation of well-faceted nanoparticles is discussed and successfully applied to the production of several rare-earth scandates. Two steps were used, with higher temperatures first to nucleate the perovskite phase, followed by lower temperatures to smooth the particle surfa...

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Main Authors: Ryan J. Paull, Tiffany Ly, Zachary R. Mansley, Kenneth R. Poeppelmeier, Laurence D. Marks
Format: Article
Language:English
Published: MDPI AG 2019-04-01
Series:Crystals
Subjects:
Online Access:https://www.mdpi.com/2073-4352/9/4/218
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author Ryan J. Paull
Tiffany Ly
Zachary R. Mansley
Kenneth R. Poeppelmeier
Laurence D. Marks
author_facet Ryan J. Paull
Tiffany Ly
Zachary R. Mansley
Kenneth R. Poeppelmeier
Laurence D. Marks
author_sort Ryan J. Paull
collection DOAJ
description A general approach to the formation of well-faceted nanoparticles is discussed and successfully applied to the production of several rare-earth scandates. Two steps were used, with higher temperatures first to nucleate the perovskite phase, followed by lower temperatures to smooth the particle surfaces. Exploiting these two different regimes led to smaller nanoparticles with more faceting. This general approach may be tailored to other material systems as a step towards producing shape-controlled nanoparticles for a desired application.
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spelling doaj.art-f5891b8d2a0c4651a2cfa9b112270d8d2022-12-22T02:53:55ZengMDPI AGCrystals2073-43522019-04-019421810.3390/cryst9040218cryst9040218Controlled Two-Step Formation of Faceted Perovskite Rare-Earth Scandate NanoparticlesRyan J. Paull0Tiffany Ly1Zachary R. Mansley2Kenneth R. Poeppelmeier3Laurence D. Marks4Department of Materials Science and Engineering, Northwestern University, Evanston, IL 60208, USADepartment of Materials Science and Engineering, Northwestern University, Evanston, IL 60208, USADepartment of Materials Science and Engineering, Northwestern University, Evanston, IL 60208, USADepartment of Chemistry, Northwestern University, Evanston, IL 60208, USADepartment of Materials Science and Engineering, Northwestern University, Evanston, IL 60208, USAA general approach to the formation of well-faceted nanoparticles is discussed and successfully applied to the production of several rare-earth scandates. Two steps were used, with higher temperatures first to nucleate the perovskite phase, followed by lower temperatures to smooth the particle surfaces. Exploiting these two different regimes led to smaller nanoparticles with more faceting. This general approach may be tailored to other material systems as a step towards producing shape-controlled nanoparticles for a desired application.https://www.mdpi.com/2073-4352/9/4/218rare-earth scandateperovskitenucleation and growth
spellingShingle Ryan J. Paull
Tiffany Ly
Zachary R. Mansley
Kenneth R. Poeppelmeier
Laurence D. Marks
Controlled Two-Step Formation of Faceted Perovskite Rare-Earth Scandate Nanoparticles
Crystals
rare-earth scandate
perovskite
nucleation and growth
title Controlled Two-Step Formation of Faceted Perovskite Rare-Earth Scandate Nanoparticles
title_full Controlled Two-Step Formation of Faceted Perovskite Rare-Earth Scandate Nanoparticles
title_fullStr Controlled Two-Step Formation of Faceted Perovskite Rare-Earth Scandate Nanoparticles
title_full_unstemmed Controlled Two-Step Formation of Faceted Perovskite Rare-Earth Scandate Nanoparticles
title_short Controlled Two-Step Formation of Faceted Perovskite Rare-Earth Scandate Nanoparticles
title_sort controlled two step formation of faceted perovskite rare earth scandate nanoparticles
topic rare-earth scandate
perovskite
nucleation and growth
url https://www.mdpi.com/2073-4352/9/4/218
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AT kennethrpoeppelmeier controlledtwostepformationoffacetedperovskiterareearthscandatenanoparticles
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