A unique Co@CoO catalyst for hydrogenolysis of biomass-derived 5-hydroxymethylfurfural to 2,5-dimethylfuran
The development of precious-metal-free catalysts to promote the sustainable production of fuels and chemicals from biomass challenging. Here the authors report a unique core-shell structured Co@CoO catalyst which exhibits excellent performance in the hydrogenolysis of biomass-derived compounds.
Main Authors: | , , , , , , , , , , , , , |
---|---|
Format: | Article |
Language: | English |
Published: |
Nature Portfolio
2022-06-01
|
Series: | Nature Communications |
Online Access: | https://doi.org/10.1038/s41467-022-31362-9 |
_version_ | 1811328813784629248 |
---|---|
author | Shuang Xiang Lin Dong Zhi-Qiang Wang Xue Han Luke L. Daemen Jiong Li Yongqiang Cheng Yong Guo Xiaohui Liu Yongfeng Hu Anibal J. Ramirez-Cuesta Sihai Yang Xue-Qing Gong Yanqin Wang |
author_facet | Shuang Xiang Lin Dong Zhi-Qiang Wang Xue Han Luke L. Daemen Jiong Li Yongqiang Cheng Yong Guo Xiaohui Liu Yongfeng Hu Anibal J. Ramirez-Cuesta Sihai Yang Xue-Qing Gong Yanqin Wang |
author_sort | Shuang Xiang |
collection | DOAJ |
description | The development of precious-metal-free catalysts to promote the sustainable production of fuels and chemicals from biomass challenging. Here the authors report a unique core-shell structured Co@CoO catalyst which exhibits excellent performance in the hydrogenolysis of biomass-derived compounds. |
first_indexed | 2024-04-13T15:31:39Z |
format | Article |
id | doaj.art-f59d4e4c61864f139201b373d4cb1391 |
institution | Directory Open Access Journal |
issn | 2041-1723 |
language | English |
last_indexed | 2024-04-13T15:31:39Z |
publishDate | 2022-06-01 |
publisher | Nature Portfolio |
record_format | Article |
series | Nature Communications |
spelling | doaj.art-f59d4e4c61864f139201b373d4cb13912022-12-22T02:41:22ZengNature PortfolioNature Communications2041-17232022-06-011311910.1038/s41467-022-31362-9A unique Co@CoO catalyst for hydrogenolysis of biomass-derived 5-hydroxymethylfurfural to 2,5-dimethylfuranShuang Xiang0Lin Dong1Zhi-Qiang Wang2Xue Han3Luke L. Daemen4Jiong Li5Yongqiang Cheng6Yong Guo7Xiaohui Liu8Yongfeng Hu9Anibal J. Ramirez-Cuesta10Sihai Yang11Xue-Qing Gong12Yanqin Wang13Key Laboratory for Advanced Materials and Joint International Research Laboratory of Precision Chemistry and Molecular Engineering, Feringa Nobel Prize Scientist Joint Research Center, Research Institute of Industrial Catalysis, School of Chemistry and Molecular Engineering, East China University of Science and TechnologyKey Laboratory for Advanced Materials and Joint International Research Laboratory of Precision Chemistry and Molecular Engineering, Feringa Nobel Prize Scientist Joint Research Center, Research Institute of Industrial Catalysis, School of Chemistry and Molecular Engineering, East China University of Science and TechnologyKey Laboratory for Advanced Materials and Joint International Research Laboratory of Precision Chemistry and Molecular Engineering, Feringa Nobel Prize Scientist Joint Research Center, Research Institute of Industrial Catalysis, School of Chemistry and Molecular Engineering, East China University of Science and TechnologyDepartment of Chemistry, University of ManchesterNeutron Scattering Division, Neutron Sciences Directorate, Oak Ridge National LaboratoryShanghai Synchrotron Radiation Facility, Shanghai Advanced Research Institute, Chinese Academy of SciencesNeutron Scattering Division, Neutron Sciences Directorate, Oak Ridge National LaboratoryKey Laboratory for Advanced Materials and Joint International Research Laboratory of Precision Chemistry and Molecular Engineering, Feringa Nobel Prize Scientist Joint Research Center, Research Institute of Industrial Catalysis, School of Chemistry and Molecular Engineering, East China University of Science and TechnologyKey Laboratory for Advanced Materials and Joint International Research Laboratory of Precision Chemistry and Molecular Engineering, Feringa Nobel Prize Scientist Joint Research Center, Research Institute of Industrial Catalysis, School of Chemistry and Molecular Engineering, East China University of Science and TechnologySinopec Shanghai Research Institute of Petrochemical TechnologyNeutron Scattering Division, Neutron Sciences Directorate, Oak Ridge National LaboratoryDepartment of Chemistry, University of ManchesterKey Laboratory for Advanced Materials and Joint International Research Laboratory of Precision Chemistry and Molecular Engineering, Feringa Nobel Prize Scientist Joint Research Center, Research Institute of Industrial Catalysis, School of Chemistry and Molecular Engineering, East China University of Science and TechnologyKey Laboratory for Advanced Materials and Joint International Research Laboratory of Precision Chemistry and Molecular Engineering, Feringa Nobel Prize Scientist Joint Research Center, Research Institute of Industrial Catalysis, School of Chemistry and Molecular Engineering, East China University of Science and TechnologyThe development of precious-metal-free catalysts to promote the sustainable production of fuels and chemicals from biomass challenging. Here the authors report a unique core-shell structured Co@CoO catalyst which exhibits excellent performance in the hydrogenolysis of biomass-derived compounds.https://doi.org/10.1038/s41467-022-31362-9 |
spellingShingle | Shuang Xiang Lin Dong Zhi-Qiang Wang Xue Han Luke L. Daemen Jiong Li Yongqiang Cheng Yong Guo Xiaohui Liu Yongfeng Hu Anibal J. Ramirez-Cuesta Sihai Yang Xue-Qing Gong Yanqin Wang A unique Co@CoO catalyst for hydrogenolysis of biomass-derived 5-hydroxymethylfurfural to 2,5-dimethylfuran Nature Communications |
title | A unique Co@CoO catalyst for hydrogenolysis of biomass-derived 5-hydroxymethylfurfural to 2,5-dimethylfuran |
title_full | A unique Co@CoO catalyst for hydrogenolysis of biomass-derived 5-hydroxymethylfurfural to 2,5-dimethylfuran |
title_fullStr | A unique Co@CoO catalyst for hydrogenolysis of biomass-derived 5-hydroxymethylfurfural to 2,5-dimethylfuran |
title_full_unstemmed | A unique Co@CoO catalyst for hydrogenolysis of biomass-derived 5-hydroxymethylfurfural to 2,5-dimethylfuran |
title_short | A unique Co@CoO catalyst for hydrogenolysis of biomass-derived 5-hydroxymethylfurfural to 2,5-dimethylfuran |
title_sort | unique co coo catalyst for hydrogenolysis of biomass derived 5 hydroxymethylfurfural to 2 5 dimethylfuran |
url | https://doi.org/10.1038/s41467-022-31362-9 |
work_keys_str_mv | AT shuangxiang auniquecocoocatalystforhydrogenolysisofbiomassderived5hydroxymethylfurfuralto25dimethylfuran AT lindong auniquecocoocatalystforhydrogenolysisofbiomassderived5hydroxymethylfurfuralto25dimethylfuran AT zhiqiangwang auniquecocoocatalystforhydrogenolysisofbiomassderived5hydroxymethylfurfuralto25dimethylfuran AT xuehan auniquecocoocatalystforhydrogenolysisofbiomassderived5hydroxymethylfurfuralto25dimethylfuran AT lukeldaemen auniquecocoocatalystforhydrogenolysisofbiomassderived5hydroxymethylfurfuralto25dimethylfuran AT jiongli auniquecocoocatalystforhydrogenolysisofbiomassderived5hydroxymethylfurfuralto25dimethylfuran AT yongqiangcheng auniquecocoocatalystforhydrogenolysisofbiomassderived5hydroxymethylfurfuralto25dimethylfuran AT yongguo auniquecocoocatalystforhydrogenolysisofbiomassderived5hydroxymethylfurfuralto25dimethylfuran AT xiaohuiliu auniquecocoocatalystforhydrogenolysisofbiomassderived5hydroxymethylfurfuralto25dimethylfuran AT yongfenghu auniquecocoocatalystforhydrogenolysisofbiomassderived5hydroxymethylfurfuralto25dimethylfuran AT anibaljramirezcuesta auniquecocoocatalystforhydrogenolysisofbiomassderived5hydroxymethylfurfuralto25dimethylfuran AT sihaiyang auniquecocoocatalystforhydrogenolysisofbiomassderived5hydroxymethylfurfuralto25dimethylfuran AT xueqinggong auniquecocoocatalystforhydrogenolysisofbiomassderived5hydroxymethylfurfuralto25dimethylfuran AT yanqinwang auniquecocoocatalystforhydrogenolysisofbiomassderived5hydroxymethylfurfuralto25dimethylfuran AT shuangxiang uniquecocoocatalystforhydrogenolysisofbiomassderived5hydroxymethylfurfuralto25dimethylfuran AT lindong uniquecocoocatalystforhydrogenolysisofbiomassderived5hydroxymethylfurfuralto25dimethylfuran AT zhiqiangwang uniquecocoocatalystforhydrogenolysisofbiomassderived5hydroxymethylfurfuralto25dimethylfuran AT xuehan uniquecocoocatalystforhydrogenolysisofbiomassderived5hydroxymethylfurfuralto25dimethylfuran AT lukeldaemen uniquecocoocatalystforhydrogenolysisofbiomassderived5hydroxymethylfurfuralto25dimethylfuran AT jiongli uniquecocoocatalystforhydrogenolysisofbiomassderived5hydroxymethylfurfuralto25dimethylfuran AT yongqiangcheng uniquecocoocatalystforhydrogenolysisofbiomassderived5hydroxymethylfurfuralto25dimethylfuran AT yongguo uniquecocoocatalystforhydrogenolysisofbiomassderived5hydroxymethylfurfuralto25dimethylfuran AT xiaohuiliu uniquecocoocatalystforhydrogenolysisofbiomassderived5hydroxymethylfurfuralto25dimethylfuran AT yongfenghu uniquecocoocatalystforhydrogenolysisofbiomassderived5hydroxymethylfurfuralto25dimethylfuran AT anibaljramirezcuesta uniquecocoocatalystforhydrogenolysisofbiomassderived5hydroxymethylfurfuralto25dimethylfuran AT sihaiyang uniquecocoocatalystforhydrogenolysisofbiomassderived5hydroxymethylfurfuralto25dimethylfuran AT xueqinggong uniquecocoocatalystforhydrogenolysisofbiomassderived5hydroxymethylfurfuralto25dimethylfuran AT yanqinwang uniquecocoocatalystforhydrogenolysisofbiomassderived5hydroxymethylfurfuralto25dimethylfuran |