(µ<sub>2</sub>-η<sup>4</sup>-<i>N</i>-(2-Butynyl)phthalimide)(hexacarbonyl)dicobalt

(µ<sub>2</sub>-η<sup>4</sup>-<i>N</i>-(2-Butynyl)phthalimide)(hexacarbonyl)dicobalt

The reaction of [Co<sub>2</sub>(CO)<sub>8</sub>] with an equimolar amount of the internal alkyne <i>N</i>-(2-butynyl)phthalimide (1-Phthalimido-2-butyne) <b>1</b> in heptane solution yields the title compound [Co<sub>2</sub>(CO)<sub>6...

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Bibliographic Details
Main Authors: Isabelle Jourdain, Michael Knorr, Tom Charenton, Carsten Strohmann, Jan-Lukas Kirchhoff, Mohamed Othman
Format: Article
Language:English
Published: MDPI AG 2023-01-01
Series:Molbank
Subjects:
cobalt
carbonyl
triphenylphosphite
crystal structure
molecular cluster
Online Access:https://www.mdpi.com/1422-8599/2023/1/M1545
Description
Summary:The reaction of [Co<sub>2</sub>(CO)<sub>8</sub>] with an equimolar amount of the internal alkyne <i>N</i>-(2-butynyl)phthalimide (1-Phthalimido-2-butyne) <b>1</b> in heptane solution yields the title compound [Co<sub>2</sub>(CO)<sub>6</sub>(µ-phthalimidoCH<sub>2</sub>C≡CMe)] <b>2</b>. Compound <b>2</b> has been characterized using IR, <sup>1</sup>H and <sup>13</sup>C NMR spectroscopy; the tetrahedrane-type cluster framework has been ascertained using a single-crystal X-ray diffraction study performed at 100 K.
ISSN:1422-8599

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