Diastereodivergent formal [4 + 1] cycloaddition of azoalkenes as one-carbon synthons

Diastereodivergent formal [4 + 1] cycloaddition of azoalkenes as one-carbon synthons

The first diastereodivergent formal [4 + 1] cycloaddition reactions of azoalkenes with p-quinone methides (p-QMs) have been accomplished. The reported reaction occurred via a domino oxa-1,4-addition/1,6-addition process, allowing the use of common azoalkenes as C1 synthons. A broad range of 2,3-di...

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Bibliographic Details
Main Authors:	Chun-Yan Guan, Tian-Jiao Han, Shi-Kun Jia, Yuan-Zhao Hua, Guang-Jian Mei
Format:	Article
Language:	English
Published:	KeAi Communications Co. Ltd. 2023-08-01
Series:	Green Synthesis and Catalysis
Subjects:	Azoalkene One-carbon synthon Diastereodivergent [4 + 1] Cycloaddition para-Quinone methides
Online Access:	http://www.sciencedirect.com/science/article/pii/S2666554922000424

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