Numerical analysis of phase decomposition in A-B binary alloys using Cahn-Hilliard equations

The analysis of phase decomposition was carried out using the nonlinear and linear Cahn-Hilliard equations in a hypothetical A-B alloy system with a miscibility gap. These equations were solved by the explicit finite difference method assuming a regular solution model. The supersaturated solid solut...

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Bibliographic Details
Main Authors: Susana Lezama-Alvarez, Erika O. Avila-Davila, Victor M. Lopez-Hirata, Jorge L. Gonzalez-Velazquez
Format: Article
Language:English
Published: Associação Brasileira de Metalurgia e Materiais (ABM); Associação Brasileira de Cerâmica (ABC); Associação Brasileira de Polímeros (ABPol) 2013-01-01
Series:Materials Research
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Online Access:http://www.scielo.br/scielo.php?script=sci_arttext&pid=S1516-14392013005000080
Description
Summary:The analysis of phase decomposition was carried out using the nonlinear and linear Cahn-Hilliard equations in a hypothetical A-B alloy system with a miscibility gap. These equations were solved by the explicit finite difference method assuming a regular solution model. The supersaturated solid solution and decomposed phases were considered to have an fcc structure. Different aging temperatures and thermodynamic interaction parameters ΩA-B were used to simulate different alloy systems. The numerical simulation results showed that the growth kinetics of phase decomposition in the alloy with 30at.% A was slower than that of 50 at.% A. Additionally, the start time and modulation wavelength of phase decomposition are strongly affected by the thermodynamic interaction parameter ΩA-B value. The numerical simulation results showed that the growth kinetics of phase decomposition with the linear equation is slower than that with the nonlinear one.
ISSN:1516-1439