Study on the Performances of PLLA/CaSiO3 Composites

In the current work, calcium silicate (CaSiO3) was blended with the poly (L-lactic acid) (PLLA) to prepare the PLLA/CaSiO3 composites, and the crystallization process, melting process and thermal decomposition behavior of PLLA/CaSiO3 composites were studied. The promoting effect of CaSiO3 on the cry...

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Main Authors: Zhang Qiuhe, Zhao Lisha, Deng Ting, Cai Yanhua
Format: Article
Language:English
Published: EDP Sciences 2021-01-01
Series:E3S Web of Conferences
Online Access:https://www.e3s-conferences.org/articles/e3sconf/pdf/2021/12/e3sconf_icersd2020_02037.pdf
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author Zhang Qiuhe
Zhao Lisha
Deng Ting
Cai Yanhua
author_facet Zhang Qiuhe
Zhao Lisha
Deng Ting
Cai Yanhua
author_sort Zhang Qiuhe
collection DOAJ
description In the current work, calcium silicate (CaSiO3) was blended with the poly (L-lactic acid) (PLLA) to prepare the PLLA/CaSiO3 composites, and the crystallization process, melting process and thermal decomposition behavior of PLLA/CaSiO3 composites were studied. The promoting effect of CaSiO3 on the crystallization of PLLA was proved by the melt-crystallization, and the CaSiO3 content was a crucial factor to the crystallization behavior of PLLA. The crystallization temperature significantly affected the melting behavior of PLLA, and the double melting peaks degenerated into the single melting peak with the increasing of crystallization temperature from 90 °C to 130 °C. Additionally, for a given PLLA/CaSiO3 sample, the different melting processes in heating after the melt-crystallization results from the different heating rates, and the appearance of the cold-crystallization peak indicated the medium nucleation capacity of CaSiO3. The presence of CaSiO3 decreased the onset thermal decomposition temperature of PLLA, and this effect depended on the competitive relationship of the poor compatibility of PLLA with CaSiO3 and the content of CaSiO3 with high thermal stability.
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spelling doaj.art-f5b907463a854b4a90ea9cdaf3af14e22022-12-21T19:46:43ZengEDP SciencesE3S Web of Conferences2267-12422021-01-012360203710.1051/e3sconf/202123602037e3sconf_icersd2020_02037Study on the Performances of PLLA/CaSiO3 CompositesZhang Qiuhe0Zhao LishaDeng Ting1Cai YanhuaChongqing Key Laboratory of Environmental Materials & Remediation Technologies, Chongqing University of Arts and SciencesChongqing Key Laboratory of Environmental Materials & Remediation Technologies, Chongqing University of Arts and SciencesIn the current work, calcium silicate (CaSiO3) was blended with the poly (L-lactic acid) (PLLA) to prepare the PLLA/CaSiO3 composites, and the crystallization process, melting process and thermal decomposition behavior of PLLA/CaSiO3 composites were studied. The promoting effect of CaSiO3 on the crystallization of PLLA was proved by the melt-crystallization, and the CaSiO3 content was a crucial factor to the crystallization behavior of PLLA. The crystallization temperature significantly affected the melting behavior of PLLA, and the double melting peaks degenerated into the single melting peak with the increasing of crystallization temperature from 90 °C to 130 °C. Additionally, for a given PLLA/CaSiO3 sample, the different melting processes in heating after the melt-crystallization results from the different heating rates, and the appearance of the cold-crystallization peak indicated the medium nucleation capacity of CaSiO3. The presence of CaSiO3 decreased the onset thermal decomposition temperature of PLLA, and this effect depended on the competitive relationship of the poor compatibility of PLLA with CaSiO3 and the content of CaSiO3 with high thermal stability.https://www.e3s-conferences.org/articles/e3sconf/pdf/2021/12/e3sconf_icersd2020_02037.pdf
spellingShingle Zhang Qiuhe
Zhao Lisha
Deng Ting
Cai Yanhua
Study on the Performances of PLLA/CaSiO3 Composites
E3S Web of Conferences
title Study on the Performances of PLLA/CaSiO3 Composites
title_full Study on the Performances of PLLA/CaSiO3 Composites
title_fullStr Study on the Performances of PLLA/CaSiO3 Composites
title_full_unstemmed Study on the Performances of PLLA/CaSiO3 Composites
title_short Study on the Performances of PLLA/CaSiO3 Composites
title_sort study on the performances of plla casio3 composites
url https://www.e3s-conferences.org/articles/e3sconf/pdf/2021/12/e3sconf_icersd2020_02037.pdf
work_keys_str_mv AT zhangqiuhe studyontheperformancesofpllacasio3composites
AT zhaolisha studyontheperformancesofpllacasio3composites
AT dengting studyontheperformancesofpllacasio3composites
AT caiyanhua studyontheperformancesofpllacasio3composites