Study on the Performances of PLLA/CaSiO3 Composites
In the current work, calcium silicate (CaSiO3) was blended with the poly (L-lactic acid) (PLLA) to prepare the PLLA/CaSiO3 composites, and the crystallization process, melting process and thermal decomposition behavior of PLLA/CaSiO3 composites were studied. The promoting effect of CaSiO3 on the cry...
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Format: | Article |
Language: | English |
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EDP Sciences
2021-01-01
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Series: | E3S Web of Conferences |
Online Access: | https://www.e3s-conferences.org/articles/e3sconf/pdf/2021/12/e3sconf_icersd2020_02037.pdf |
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author | Zhang Qiuhe Zhao Lisha Deng Ting Cai Yanhua |
author_facet | Zhang Qiuhe Zhao Lisha Deng Ting Cai Yanhua |
author_sort | Zhang Qiuhe |
collection | DOAJ |
description | In the current work, calcium silicate (CaSiO3) was blended with the poly (L-lactic acid) (PLLA)
to prepare the PLLA/CaSiO3 composites, and the crystallization process, melting process and thermal
decomposition behavior of PLLA/CaSiO3 composites were studied. The promoting effect of CaSiO3 on the
crystallization of PLLA was proved by the melt-crystallization, and the CaSiO3 content was a crucial factor
to the crystallization behavior of PLLA. The crystallization temperature significantly affected the melting
behavior of PLLA, and the double melting peaks degenerated into the single melting peak with the increasing
of crystallization temperature from 90 °C to 130 °C. Additionally, for a given PLLA/CaSiO3 sample, the
different melting processes in heating after the melt-crystallization results from the different heating rates,
and the appearance of the cold-crystallization peak indicated the medium nucleation capacity of CaSiO3. The
presence of CaSiO3 decreased the onset thermal decomposition temperature of PLLA, and this effect
depended on the competitive relationship of the poor compatibility of PLLA with CaSiO3 and the content of
CaSiO3 with high thermal stability. |
first_indexed | 2024-12-20T08:31:29Z |
format | Article |
id | doaj.art-f5b907463a854b4a90ea9cdaf3af14e2 |
institution | Directory Open Access Journal |
issn | 2267-1242 |
language | English |
last_indexed | 2024-12-20T08:31:29Z |
publishDate | 2021-01-01 |
publisher | EDP Sciences |
record_format | Article |
series | E3S Web of Conferences |
spelling | doaj.art-f5b907463a854b4a90ea9cdaf3af14e22022-12-21T19:46:43ZengEDP SciencesE3S Web of Conferences2267-12422021-01-012360203710.1051/e3sconf/202123602037e3sconf_icersd2020_02037Study on the Performances of PLLA/CaSiO3 CompositesZhang Qiuhe0Zhao LishaDeng Ting1Cai YanhuaChongqing Key Laboratory of Environmental Materials & Remediation Technologies, Chongqing University of Arts and SciencesChongqing Key Laboratory of Environmental Materials & Remediation Technologies, Chongqing University of Arts and SciencesIn the current work, calcium silicate (CaSiO3) was blended with the poly (L-lactic acid) (PLLA) to prepare the PLLA/CaSiO3 composites, and the crystallization process, melting process and thermal decomposition behavior of PLLA/CaSiO3 composites were studied. The promoting effect of CaSiO3 on the crystallization of PLLA was proved by the melt-crystallization, and the CaSiO3 content was a crucial factor to the crystallization behavior of PLLA. The crystallization temperature significantly affected the melting behavior of PLLA, and the double melting peaks degenerated into the single melting peak with the increasing of crystallization temperature from 90 °C to 130 °C. Additionally, for a given PLLA/CaSiO3 sample, the different melting processes in heating after the melt-crystallization results from the different heating rates, and the appearance of the cold-crystallization peak indicated the medium nucleation capacity of CaSiO3. The presence of CaSiO3 decreased the onset thermal decomposition temperature of PLLA, and this effect depended on the competitive relationship of the poor compatibility of PLLA with CaSiO3 and the content of CaSiO3 with high thermal stability.https://www.e3s-conferences.org/articles/e3sconf/pdf/2021/12/e3sconf_icersd2020_02037.pdf |
spellingShingle | Zhang Qiuhe Zhao Lisha Deng Ting Cai Yanhua Study on the Performances of PLLA/CaSiO3 Composites E3S Web of Conferences |
title | Study on the Performances of PLLA/CaSiO3 Composites |
title_full | Study on the Performances of PLLA/CaSiO3 Composites |
title_fullStr | Study on the Performances of PLLA/CaSiO3 Composites |
title_full_unstemmed | Study on the Performances of PLLA/CaSiO3 Composites |
title_short | Study on the Performances of PLLA/CaSiO3 Composites |
title_sort | study on the performances of plla casio3 composites |
url | https://www.e3s-conferences.org/articles/e3sconf/pdf/2021/12/e3sconf_icersd2020_02037.pdf |
work_keys_str_mv | AT zhangqiuhe studyontheperformancesofpllacasio3composites AT zhaolisha studyontheperformancesofpllacasio3composites AT dengting studyontheperformancesofpllacasio3composites AT caiyanhua studyontheperformancesofpllacasio3composites |