Assessment of Clayey Freshwater Sediments as Suitable Precursors for Alkaline Activation

One of the biggest challenges in the construction industry in recent times is the mitigation of the environmental impact of this sector, the reduction in dependence on primary raw materials, and the reduction in CO<sub>2</sub> production while maintaining functional properties. Alkaline...

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Main Authors: Jan Fořt, Ayodele Afolayan, Martin Mildner, Petr Hotěk, Martin Keppert, Robert Černý
Format: Article
Language:English
Published: MDPI AG 2024-01-01
Series:Polymers
Subjects:
Online Access:https://www.mdpi.com/2073-4360/16/2/175
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author Jan Fořt
Ayodele Afolayan
Martin Mildner
Petr Hotěk
Martin Keppert
Robert Černý
author_facet Jan Fořt
Ayodele Afolayan
Martin Mildner
Petr Hotěk
Martin Keppert
Robert Černý
author_sort Jan Fořt
collection DOAJ
description One of the biggest challenges in the construction industry in recent times is the mitigation of the environmental impact of this sector, the reduction in dependence on primary raw materials, and the reduction in CO<sub>2</sub> production while maintaining functional properties. Alkaline activation of a number of waste products represents a promising way to achieve the above-mentioned goals, but the availability of a number of waste products changes over time, especially in Europe. While freshwater sediments were in the past widely utilized as an agricultural fertilizer, recent precautions have significantly decreased such application, and thus new destinations must be delivered. To explore the potential of freshwater sediments, select samples from various locations were subjected to detailed characterization to verify the applicability of the material for alkali activation. As recognized, the selected sediments contain a substantial volume of desired mineralogical compounds that can serve, after 900 °C curing, as suitable precursors. Such samples have consequently activated the mixture of alkaline activators to obtain dense structures and were subjected to detailed investigation aimed at understanding the mechanical parameters. The obtained mechanical results ranging between 14.9 MPa and 36.8 MPa reveal the engineering potential of sediments for valorization through alkali activation and outline new research challenges in this area.
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spelling doaj.art-f5b90fba4e644a56a63614c86bf298f02024-01-26T18:12:43ZengMDPI AGPolymers2073-43602024-01-0116217510.3390/polym16020175Assessment of Clayey Freshwater Sediments as Suitable Precursors for Alkaline ActivationJan Fořt0Ayodele Afolayan1Martin Mildner2Petr Hotěk3Martin Keppert4Robert Černý5Department of Materials Engineering and Chemistry, Faculty of Civil Engineering, Czech Technical University in Prague, Takurova 7, 166 29 Prague, Czech RepublicDepartment of Materials Engineering and Chemistry, Faculty of Civil Engineering, Czech Technical University in Prague, Takurova 7, 166 29 Prague, Czech RepublicDepartment of Materials Engineering and Chemistry, Faculty of Civil Engineering, Czech Technical University in Prague, Takurova 7, 166 29 Prague, Czech RepublicDepartment of Materials Engineering and Chemistry, Faculty of Civil Engineering, Czech Technical University in Prague, Takurova 7, 166 29 Prague, Czech RepublicDepartment of Materials Engineering and Chemistry, Faculty of Civil Engineering, Czech Technical University in Prague, Takurova 7, 166 29 Prague, Czech RepublicDepartment of Materials Engineering and Chemistry, Faculty of Civil Engineering, Czech Technical University in Prague, Takurova 7, 166 29 Prague, Czech RepublicOne of the biggest challenges in the construction industry in recent times is the mitigation of the environmental impact of this sector, the reduction in dependence on primary raw materials, and the reduction in CO<sub>2</sub> production while maintaining functional properties. Alkaline activation of a number of waste products represents a promising way to achieve the above-mentioned goals, but the availability of a number of waste products changes over time, especially in Europe. While freshwater sediments were in the past widely utilized as an agricultural fertilizer, recent precautions have significantly decreased such application, and thus new destinations must be delivered. To explore the potential of freshwater sediments, select samples from various locations were subjected to detailed characterization to verify the applicability of the material for alkali activation. As recognized, the selected sediments contain a substantial volume of desired mineralogical compounds that can serve, after 900 °C curing, as suitable precursors. Such samples have consequently activated the mixture of alkaline activators to obtain dense structures and were subjected to detailed investigation aimed at understanding the mechanical parameters. The obtained mechanical results ranging between 14.9 MPa and 36.8 MPa reveal the engineering potential of sediments for valorization through alkali activation and outline new research challenges in this area.https://www.mdpi.com/2073-4360/16/2/175alkali-activated materialfreshwater sedimentporosityparticle sizemechanical strength
spellingShingle Jan Fořt
Ayodele Afolayan
Martin Mildner
Petr Hotěk
Martin Keppert
Robert Černý
Assessment of Clayey Freshwater Sediments as Suitable Precursors for Alkaline Activation
Polymers
alkali-activated material
freshwater sediment
porosity
particle size
mechanical strength
title Assessment of Clayey Freshwater Sediments as Suitable Precursors for Alkaline Activation
title_full Assessment of Clayey Freshwater Sediments as Suitable Precursors for Alkaline Activation
title_fullStr Assessment of Clayey Freshwater Sediments as Suitable Precursors for Alkaline Activation
title_full_unstemmed Assessment of Clayey Freshwater Sediments as Suitable Precursors for Alkaline Activation
title_short Assessment of Clayey Freshwater Sediments as Suitable Precursors for Alkaline Activation
title_sort assessment of clayey freshwater sediments as suitable precursors for alkaline activation
topic alkali-activated material
freshwater sediment
porosity
particle size
mechanical strength
url https://www.mdpi.com/2073-4360/16/2/175
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AT petrhotek assessmentofclayeyfreshwatersedimentsassuitableprecursorsforalkalineactivation
AT martinkeppert assessmentofclayeyfreshwatersedimentsassuitableprecursorsforalkalineactivation
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