Deposition environment and provenance of the Palaeogene Shahejie Formation in Nanpu Sag: Evidences from trace and rare earth element geochemistry

In order to reveal the formation mechanism of the organic-rich shales of the Shahejie Formation in Nanpu Sag, the depositional environment and provenance were investigated in detail through analyzing trace and rare earth elements(REE) geochemical characteristics. The results show that the trace elem...

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Main Authors: Yuqian Jing, Chuang Lei, Kedong Liu, Zhenhua Li
Format: Article
Language:zho
Published: Editorial Department of Bulletin of Geological Science and Technology 2023-01-01
Series:地质科技通报
Subjects:
Online Access:https://dzkjqb.cug.edu.cn/en/article/doi/10.19509/j.cnki.dzkq.2022.0131
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author Yuqian Jing
Chuang Lei
Kedong Liu
Zhenhua Li
author_facet Yuqian Jing
Chuang Lei
Kedong Liu
Zhenhua Li
author_sort Yuqian Jing
collection DOAJ
description In order to reveal the formation mechanism of the organic-rich shales of the Shahejie Formation in Nanpu Sag, the depositional environment and provenance were investigated in detail through analyzing trace and rare earth elements(REE) geochemical characteristics. The results show that the trace elements Li, Cs and Bi are enriched, Cr and Sn are relatively depleted, and other trace elements are close to those in the upper continental crust(UCC).The total amount of REE vary widely, which is close to or higher than the average value in the UCC, and the supply of terrestrial source debris is adequate. The REE allocation pattern shows light rare earth element(LREE) enrichment with a high degree of divergence, and a relative deficit of heavy rare earth element(HREE) with a low degree of divergence. Eu negative anomaly is obvious, Ce is basically normal. The variations of Sr abundance and Sr/Ba ratio reflect that, in Nanpu Sag, the lake water was separated to a certain extent, and the fresh water, brackish water and saline water coexisted during sedimentary period of the third member of Shahejie Formation(Es3), and during these dimentary period of the first member of Shahejie Formation(Es1), the connectivity of lake water was enhanced, which was dominated by brackish water.The values of the V/(V+Ni), Th/U, δCe, and Ceanom comprehensively delineate the water body presented suboxic environment with moderate stratification. Respectively, the source Ba content indicated the water body was dominated by high paleoproductivity. The REE assemblage characteristics suggests that the provenance of Shahejie Formation were primarily derived from Yanshanian granites developed in Yanshanian fold belt and a small amount of sedimentary rocks. The development of organic-rich shales in the Shahejie Formation in Nanpu Sag is closely related to paleoenvironment and paleogeography, which can be summarized as the followings: ①suitable paleosalinity as well as sufficient nutrients at water body contributed to the booming of various planktonic algae, improving the production efficiency of the aquatic organic matter; ②suboxic water column slowed down the degradation of oxygen-sensitive material during the burial process, enhancing the preservation efficiency of sedimentary organic matter.
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spelling doaj.art-f5d446ab3a77472c9bd69e14fa915c092024-03-05T02:56:00ZzhoEditorial Department of Bulletin of Geological Science and Technology地质科技通报2096-85232023-01-0142135035910.19509/j.cnki.dzkq.2022.0131dzkjtb-42-1-350Deposition environment and provenance of the Palaeogene Shahejie Formation in Nanpu Sag: Evidences from trace and rare earth element geochemistryYuqian Jing0Chuang Lei1Kedong Liu2Zhenhua Li3State Key Laboratory of Petroleum Resources and Prospecting, China University of Petroleum(Beijing), Beijing 102249, ChinaState Key Laboratory of Petroleum Resources and Prospecting, China University of Petroleum(Beijing), Beijing 102249, ChinaShandong Provincial Nuclear Industry 248 Geological Brigade, Qingdao Shandong 266041, ChinaDongying Market Supervision and Administrtion Bureau, Dongying Shandong 257091, ChinaIn order to reveal the formation mechanism of the organic-rich shales of the Shahejie Formation in Nanpu Sag, the depositional environment and provenance were investigated in detail through analyzing trace and rare earth elements(REE) geochemical characteristics. The results show that the trace elements Li, Cs and Bi are enriched, Cr and Sn are relatively depleted, and other trace elements are close to those in the upper continental crust(UCC).The total amount of REE vary widely, which is close to or higher than the average value in the UCC, and the supply of terrestrial source debris is adequate. The REE allocation pattern shows light rare earth element(LREE) enrichment with a high degree of divergence, and a relative deficit of heavy rare earth element(HREE) with a low degree of divergence. Eu negative anomaly is obvious, Ce is basically normal. The variations of Sr abundance and Sr/Ba ratio reflect that, in Nanpu Sag, the lake water was separated to a certain extent, and the fresh water, brackish water and saline water coexisted during sedimentary period of the third member of Shahejie Formation(Es3), and during these dimentary period of the first member of Shahejie Formation(Es1), the connectivity of lake water was enhanced, which was dominated by brackish water.The values of the V/(V+Ni), Th/U, δCe, and Ceanom comprehensively delineate the water body presented suboxic environment with moderate stratification. Respectively, the source Ba content indicated the water body was dominated by high paleoproductivity. The REE assemblage characteristics suggests that the provenance of Shahejie Formation were primarily derived from Yanshanian granites developed in Yanshanian fold belt and a small amount of sedimentary rocks. The development of organic-rich shales in the Shahejie Formation in Nanpu Sag is closely related to paleoenvironment and paleogeography, which can be summarized as the followings: ①suitable paleosalinity as well as sufficient nutrients at water body contributed to the booming of various planktonic algae, improving the production efficiency of the aquatic organic matter; ②suboxic water column slowed down the degradation of oxygen-sensitive material during the burial process, enhancing the preservation efficiency of sedimentary organic matter.https://dzkjqb.cug.edu.cn/en/article/doi/10.19509/j.cnki.dzkq.2022.0131nanpu sagshahejie formationtrace elementrare earth elementdeposition environmentprovenance
spellingShingle Yuqian Jing
Chuang Lei
Kedong Liu
Zhenhua Li
Deposition environment and provenance of the Palaeogene Shahejie Formation in Nanpu Sag: Evidences from trace and rare earth element geochemistry
地质科技通报
nanpu sag
shahejie formation
trace element
rare earth element
deposition environment
provenance
title Deposition environment and provenance of the Palaeogene Shahejie Formation in Nanpu Sag: Evidences from trace and rare earth element geochemistry
title_full Deposition environment and provenance of the Palaeogene Shahejie Formation in Nanpu Sag: Evidences from trace and rare earth element geochemistry
title_fullStr Deposition environment and provenance of the Palaeogene Shahejie Formation in Nanpu Sag: Evidences from trace and rare earth element geochemistry
title_full_unstemmed Deposition environment and provenance of the Palaeogene Shahejie Formation in Nanpu Sag: Evidences from trace and rare earth element geochemistry
title_short Deposition environment and provenance of the Palaeogene Shahejie Formation in Nanpu Sag: Evidences from trace and rare earth element geochemistry
title_sort deposition environment and provenance of the palaeogene shahejie formation in nanpu sag evidences from trace and rare earth element geochemistry
topic nanpu sag
shahejie formation
trace element
rare earth element
deposition environment
provenance
url https://dzkjqb.cug.edu.cn/en/article/doi/10.19509/j.cnki.dzkq.2022.0131
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AT kedongliu depositionenvironmentandprovenanceofthepalaeogeneshahejieformationinnanpusagevidencesfromtraceandrareearthelementgeochemistry
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