A review of nonfullerene solar cells: Insight into the correlation among molecular structure, morphology, and device performance

Abstract Nonfullerene acceptors (NFAs) lead the continuous development of organic solar cells (OSCs) with competitive efficiency over 19%. Design and synthesis of novel photovoltaic materials are effective methods to improve the OSCs performance, which can regulate the optoelectric properties, such...

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Main Authors: Jingming Xin, Wangchang Li, Yutong Zhang, Qiuju Liang, Chunpeng Song, Yuzhen Zhao, Zemin He, Jiangang Liu, Wei Ma
Format: Article
Language:English
Published: Wiley 2023-03-01
Series:Battery Energy
Subjects:
Online Access:https://doi.org/10.1002/bte2.20220040
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author Jingming Xin
Wangchang Li
Yutong Zhang
Qiuju Liang
Chunpeng Song
Yuzhen Zhao
Zemin He
Jiangang Liu
Wei Ma
author_facet Jingming Xin
Wangchang Li
Yutong Zhang
Qiuju Liang
Chunpeng Song
Yuzhen Zhao
Zemin He
Jiangang Liu
Wei Ma
author_sort Jingming Xin
collection DOAJ
description Abstract Nonfullerene acceptors (NFAs) lead the continuous development of organic solar cells (OSCs) with competitive efficiency over 19%. Design and synthesis of novel photovoltaic materials are effective methods to improve the OSCs performance, which can regulate the optoelectric properties, such as energy level, absorption spectra, charge transport, and so on. So far, hundreds of NFAs have been reported. Meanwhile, it has been demonstrated that intrinsic morphology of active layer is partially determined by the chemical structures of NFAs. Hence, only in‐depth understanding of the relationship between different structures of NFAs and morphology can guide the molecular design of NFAs for highly efficient OSCs. Herein, we review some state‐of‐the‐art NFAs according to their functional moieties, that is, arene core, end group and side chain, and discuss the relationship between molecular structure, morphology and device parameter. Additionally, the challenges and prospects for further development of OSCs based on NFAs are briefly considered. This review brings a unique insight into structure–function correlation in this field, which may help to rapidly develop efficient OSCs.
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spelling doaj.art-f606351a2050465c98ced129e210bc6e2023-03-20T10:47:57ZengWileyBattery Energy2768-16962023-03-0122n/an/a10.1002/bte2.20220040A review of nonfullerene solar cells: Insight into the correlation among molecular structure, morphology, and device performanceJingming Xin0Wangchang Li1Yutong Zhang2Qiuju Liang3Chunpeng Song4Yuzhen Zhao5Zemin He6Jiangang Liu7Wei Ma8School of Electronics and Information Northwestern Polytechnical University Xi'an ChinaSchool of Electronics and Information Northwestern Polytechnical University Xi'an ChinaSchool of Electronics and Information Northwestern Polytechnical University Xi'an ChinaSchool of Electronics and Information Northwestern Polytechnical University Xi'an ChinaSchool of Electronics and Information Northwestern Polytechnical University Xi'an ChinaXi'an Key Laboratory of Advanced Photo‐electronics Materials and Energy Conversion Device, School of Electronic Information Xijing University Xi'an ChinaSchool of Electronics and Information Northwestern Polytechnical University Xi'an ChinaSchool of Electronics and Information Northwestern Polytechnical University Xi'an ChinaState Key Laboratory for Mechanical Behavior of Materials Xi'an Jiaotong University Xi'an ChinaAbstract Nonfullerene acceptors (NFAs) lead the continuous development of organic solar cells (OSCs) with competitive efficiency over 19%. Design and synthesis of novel photovoltaic materials are effective methods to improve the OSCs performance, which can regulate the optoelectric properties, such as energy level, absorption spectra, charge transport, and so on. So far, hundreds of NFAs have been reported. Meanwhile, it has been demonstrated that intrinsic morphology of active layer is partially determined by the chemical structures of NFAs. Hence, only in‐depth understanding of the relationship between different structures of NFAs and morphology can guide the molecular design of NFAs for highly efficient OSCs. Herein, we review some state‐of‐the‐art NFAs according to their functional moieties, that is, arene core, end group and side chain, and discuss the relationship between molecular structure, morphology and device parameter. Additionally, the challenges and prospects for further development of OSCs based on NFAs are briefly considered. This review brings a unique insight into structure–function correlation in this field, which may help to rapidly develop efficient OSCs.https://doi.org/10.1002/bte2.20220040molecular structuremorphologynonfullerene acceptororganic solar cellsperformance
spellingShingle Jingming Xin
Wangchang Li
Yutong Zhang
Qiuju Liang
Chunpeng Song
Yuzhen Zhao
Zemin He
Jiangang Liu
Wei Ma
A review of nonfullerene solar cells: Insight into the correlation among molecular structure, morphology, and device performance
Battery Energy
molecular structure
morphology
nonfullerene acceptor
organic solar cells
performance
title A review of nonfullerene solar cells: Insight into the correlation among molecular structure, morphology, and device performance
title_full A review of nonfullerene solar cells: Insight into the correlation among molecular structure, morphology, and device performance
title_fullStr A review of nonfullerene solar cells: Insight into the correlation among molecular structure, morphology, and device performance
title_full_unstemmed A review of nonfullerene solar cells: Insight into the correlation among molecular structure, morphology, and device performance
title_short A review of nonfullerene solar cells: Insight into the correlation among molecular structure, morphology, and device performance
title_sort review of nonfullerene solar cells insight into the correlation among molecular structure morphology and device performance
topic molecular structure
morphology
nonfullerene acceptor
organic solar cells
performance
url https://doi.org/10.1002/bte2.20220040
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