Effect of Sign-Alternating Cyclic Polarisation and Hydrogen Uptake on the Localised Corrosion of X70 Pipeline Steel in Near-Neutral Solutions

The effect of sign-alternating cycling polarisation (SACP) on the localised corrosion of X70pipeline steel in solutions of various compositions was studied. Localised corrosion of steel at anodic potentials was accelerated with an increase in the duration of the cathodic half-cycle, in the presence...

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Main Authors: Alevtina Rybkina, Natalia Gladkikh, Andrey Marshakov, Maxim Petrunin, Andrei Nazarov
Format: Article
Language:English
Published: MDPI AG 2020-02-01
Series:Metals
Subjects:
Online Access:https://www.mdpi.com/2075-4701/10/2/245
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author Alevtina Rybkina
Natalia Gladkikh
Andrey Marshakov
Maxim Petrunin
Andrei Nazarov
author_facet Alevtina Rybkina
Natalia Gladkikh
Andrey Marshakov
Maxim Petrunin
Andrei Nazarov
author_sort Alevtina Rybkina
collection DOAJ
description The effect of sign-alternating cycling polarisation (SACP) on the localised corrosion of X70pipeline steel in solutions of various compositions was studied. Localised corrosion of steel at anodic potentials was accelerated with an increase in the duration of the cathodic half-cycle, in the presence of a promoter of hydrogen absorption in aqueous electrolyte, and with an increase in the concentrations of chloride and bicarbonate ions. It was pointed out that the corrosion rate is determined by the amount of hydrogen absorbed by the steel. A quantitative indicator to determine the intensity of localised corrosion under SACP was suggested.
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spelling doaj.art-f611308d28d24b1ab9449ede4c09ab092022-12-21T19:37:06ZengMDPI AGMetals2075-47012020-02-0110224510.3390/met10020245met10020245Effect of Sign-Alternating Cyclic Polarisation and Hydrogen Uptake on the Localised Corrosion of X70 Pipeline Steel in Near-Neutral SolutionsAlevtina Rybkina0Natalia Gladkikh1Andrey Marshakov2Maxim Petrunin3Andrei Nazarov4Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences, 119071 Moscow, RussiaFrumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences, 119071 Moscow, RussiaFrumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences, 119071 Moscow, RussiaFrumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences, 119071 Moscow, RussiaFrench Corrosion Institute, 29200 Brest, FranceThe effect of sign-alternating cycling polarisation (SACP) on the localised corrosion of X70pipeline steel in solutions of various compositions was studied. Localised corrosion of steel at anodic potentials was accelerated with an increase in the duration of the cathodic half-cycle, in the presence of a promoter of hydrogen absorption in aqueous electrolyte, and with an increase in the concentrations of chloride and bicarbonate ions. It was pointed out that the corrosion rate is determined by the amount of hydrogen absorbed by the steel. A quantitative indicator to determine the intensity of localised corrosion under SACP was suggested.https://www.mdpi.com/2075-4701/10/2/245pipeline steelsign-alternating polarisationpitting corrosionsoil electrolytehydrogen uptake
spellingShingle Alevtina Rybkina
Natalia Gladkikh
Andrey Marshakov
Maxim Petrunin
Andrei Nazarov
Effect of Sign-Alternating Cyclic Polarisation and Hydrogen Uptake on the Localised Corrosion of X70 Pipeline Steel in Near-Neutral Solutions
Metals
pipeline steel
sign-alternating polarisation
pitting corrosion
soil electrolyte
hydrogen uptake
title Effect of Sign-Alternating Cyclic Polarisation and Hydrogen Uptake on the Localised Corrosion of X70 Pipeline Steel in Near-Neutral Solutions
title_full Effect of Sign-Alternating Cyclic Polarisation and Hydrogen Uptake on the Localised Corrosion of X70 Pipeline Steel in Near-Neutral Solutions
title_fullStr Effect of Sign-Alternating Cyclic Polarisation and Hydrogen Uptake on the Localised Corrosion of X70 Pipeline Steel in Near-Neutral Solutions
title_full_unstemmed Effect of Sign-Alternating Cyclic Polarisation and Hydrogen Uptake on the Localised Corrosion of X70 Pipeline Steel in Near-Neutral Solutions
title_short Effect of Sign-Alternating Cyclic Polarisation and Hydrogen Uptake on the Localised Corrosion of X70 Pipeline Steel in Near-Neutral Solutions
title_sort effect of sign alternating cyclic polarisation and hydrogen uptake on the localised corrosion of x70 pipeline steel in near neutral solutions
topic pipeline steel
sign-alternating polarisation
pitting corrosion
soil electrolyte
hydrogen uptake
url https://www.mdpi.com/2075-4701/10/2/245
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