Conversion of Sunan Candlenut Oil to Aromatic Hydrocarbons with Hydrocracking Process Over Nano-HZSM-5 Catalyst

In this paper, the catalysts (Nano-HZSM-5 and Fe-La/nano HZSM-5) were prepared with incipient wetness impregnation and applied for hydrocracking of Sunan candlenut oil. The hydrocracking process was conducted in a batch reactor with a pressure of 20-30 bar H2 gas for 2 h under various temperatures....

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Main Authors: Muhammad Al Muttaqii, Maja Pranata Marbun, Sudibyo Sudibyo, Asif Aunillah, Dibyo Pranowo, Hasanudin Hasanudin, Nino Rinaldi, Teuku Beuna Bardant
Format: Article
Language:English
Published: Masyarakat Katalis Indonesia - Indonesian Catalyst Society (MKICS) 2024-04-01
Series:Bulletin of Chemical Reaction Engineering & Catalysis
Subjects:
Online Access:https://journal.bcrec.id/index.php/bcrec/article/view/20116
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author Muhammad Al Muttaqii
Maja Pranata Marbun
Sudibyo Sudibyo
Asif Aunillah
Dibyo Pranowo
Hasanudin Hasanudin
Nino Rinaldi
Teuku Beuna Bardant
author_facet Muhammad Al Muttaqii
Maja Pranata Marbun
Sudibyo Sudibyo
Asif Aunillah
Dibyo Pranowo
Hasanudin Hasanudin
Nino Rinaldi
Teuku Beuna Bardant
author_sort Muhammad Al Muttaqii
collection DOAJ
description In this paper, the catalysts (Nano-HZSM-5 and Fe-La/nano HZSM-5) were prepared with incipient wetness impregnation and applied for hydrocracking of Sunan candlenut oil. The hydrocracking process was conducted in a batch reactor with a pressure of 20-30 bar H2 gas for 2 h under various temperatures. The results demonstrated that hydrocracking of Sunan candlenut oil using nano HZSM-5 and Fe-La/NHZ catalysts could be converted into aromatic hydrocarbons, and the reaction temperature affected hydrocarbon production. The aromatic compounds, such as propyl-benzene, 1-ethyl-3-methylbenzene, heptyl-benzene, 2-ethyl-naphthalene, etc., reached 35.51% over the Fe-La/NHZ_2 catalyst. In all cases, the zeolite-based catalysts are the most suitable to produce aromatic hydrocarbons. Metal impregnated (Fe and La) on nano HZSM-5 catalyst could improve the aromatics compounds due to increased metal and acid sites. Copyright © 2024 by Authors, Published by BCREC Publishing Group. This is an open access article under the CC BY-SA License (https://creativecommons.org/licenses/by-sa/4.0).
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spelling doaj.art-f642c2b9624d4c7dac0ac9655b55bdfa2024-02-29T04:28:03ZengMasyarakat Katalis Indonesia - Indonesian Catalyst Society (MKICS)Bulletin of Chemical Reaction Engineering & Catalysis1978-29932024-04-0119114114810.9767/bcrec.201168430Conversion of Sunan Candlenut Oil to Aromatic Hydrocarbons with Hydrocracking Process Over Nano-HZSM-5 CatalystMuhammad Al Muttaqii0https://orcid.org/0000-0001-5000-3478Maja Pranata Marbun1Sudibyo Sudibyo2Asif Aunillah3Dibyo Pranowo4Hasanudin Hasanudin5Nino Rinaldi6Teuku Beuna Bardant7Research Center for Chemistry, National Research and Innovation Agency (BRIN-Indonesia), South Tangerang 15314, IndonesiaDepartment of Chemical Engineering, University of Sonan Bonang, East Java 62311, IndonesiaResearch Center for Mining Technology, National Research and Innovation Agency (BRIN-Indonesia), South Lampung 35361, IndonesiaResearch Center for Agroindustry, National Research and Innovation Agency (BRIN-Indonesia), Cibinong Jl. Raya Jakarta-Bogor KM 46, Cibinong 16911, IndonesiaResearch Center for Horticultural and Estate Crops, National Research and Innovation Agency (BRIN-Indonesia), Cibinong 16911, IndonesiaDepartment of Chemistry, University of Sriwijaya, South Sumatera 30662, IndonesiaResearch Center for Chemistry, National Research and Innovation Agency (BRIN-Indonesia), South Tangerang 15314, IndonesiaResearch Center for Chemistry, National Research and Innovation Agency (BRIN-Indonesia), South Tangerang 15314, IndonesiaIn this paper, the catalysts (Nano-HZSM-5 and Fe-La/nano HZSM-5) were prepared with incipient wetness impregnation and applied for hydrocracking of Sunan candlenut oil. The hydrocracking process was conducted in a batch reactor with a pressure of 20-30 bar H2 gas for 2 h under various temperatures. The results demonstrated that hydrocracking of Sunan candlenut oil using nano HZSM-5 and Fe-La/NHZ catalysts could be converted into aromatic hydrocarbons, and the reaction temperature affected hydrocarbon production. The aromatic compounds, such as propyl-benzene, 1-ethyl-3-methylbenzene, heptyl-benzene, 2-ethyl-naphthalene, etc., reached 35.51% over the Fe-La/NHZ_2 catalyst. In all cases, the zeolite-based catalysts are the most suitable to produce aromatic hydrocarbons. Metal impregnated (Fe and La) on nano HZSM-5 catalyst could improve the aromatics compounds due to increased metal and acid sites. Copyright © 2024 by Authors, Published by BCREC Publishing Group. This is an open access article under the CC BY-SA License (https://creativecommons.org/licenses/by-sa/4.0).https://journal.bcrec.id/index.php/bcrec/article/view/20116hydrocrackingnano hzsm-5fe-la/nhz catalystssunan candlenut oilaromatics compounds
spellingShingle Muhammad Al Muttaqii
Maja Pranata Marbun
Sudibyo Sudibyo
Asif Aunillah
Dibyo Pranowo
Hasanudin Hasanudin
Nino Rinaldi
Teuku Beuna Bardant
Conversion of Sunan Candlenut Oil to Aromatic Hydrocarbons with Hydrocracking Process Over Nano-HZSM-5 Catalyst
Bulletin of Chemical Reaction Engineering & Catalysis
hydrocracking
nano hzsm-5
fe-la/nhz catalysts
sunan candlenut oil
aromatics compounds
title Conversion of Sunan Candlenut Oil to Aromatic Hydrocarbons with Hydrocracking Process Over Nano-HZSM-5 Catalyst
title_full Conversion of Sunan Candlenut Oil to Aromatic Hydrocarbons with Hydrocracking Process Over Nano-HZSM-5 Catalyst
title_fullStr Conversion of Sunan Candlenut Oil to Aromatic Hydrocarbons with Hydrocracking Process Over Nano-HZSM-5 Catalyst
title_full_unstemmed Conversion of Sunan Candlenut Oil to Aromatic Hydrocarbons with Hydrocracking Process Over Nano-HZSM-5 Catalyst
title_short Conversion of Sunan Candlenut Oil to Aromatic Hydrocarbons with Hydrocracking Process Over Nano-HZSM-5 Catalyst
title_sort conversion of sunan candlenut oil to aromatic hydrocarbons with hydrocracking process over nano hzsm 5 catalyst
topic hydrocracking
nano hzsm-5
fe-la/nhz catalysts
sunan candlenut oil
aromatics compounds
url https://journal.bcrec.id/index.php/bcrec/article/view/20116
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