Conversion of Sunan Candlenut Oil to Aromatic Hydrocarbons with Hydrocracking Process Over Nano-HZSM-5 Catalyst
In this paper, the catalysts (Nano-HZSM-5 and Fe-La/nano HZSM-5) were prepared with incipient wetness impregnation and applied for hydrocracking of Sunan candlenut oil. The hydrocracking process was conducted in a batch reactor with a pressure of 20-30 bar H2 gas for 2 h under various temperatures....
Main Authors: | , , , , , , , |
---|---|
Format: | Article |
Language: | English |
Published: |
Masyarakat Katalis Indonesia - Indonesian Catalyst Society (MKICS)
2024-04-01
|
Series: | Bulletin of Chemical Reaction Engineering & Catalysis |
Subjects: | |
Online Access: | https://journal.bcrec.id/index.php/bcrec/article/view/20116 |
_version_ | 1827339019406540800 |
---|---|
author | Muhammad Al Muttaqii Maja Pranata Marbun Sudibyo Sudibyo Asif Aunillah Dibyo Pranowo Hasanudin Hasanudin Nino Rinaldi Teuku Beuna Bardant |
author_facet | Muhammad Al Muttaqii Maja Pranata Marbun Sudibyo Sudibyo Asif Aunillah Dibyo Pranowo Hasanudin Hasanudin Nino Rinaldi Teuku Beuna Bardant |
author_sort | Muhammad Al Muttaqii |
collection | DOAJ |
description | In this paper, the catalysts (Nano-HZSM-5 and Fe-La/nano HZSM-5) were prepared with incipient wetness impregnation and applied for hydrocracking of Sunan candlenut oil. The hydrocracking process was conducted in a batch reactor with a pressure of 20-30 bar H2 gas for 2 h under various temperatures. The results demonstrated that hydrocracking of Sunan candlenut oil using nano HZSM-5 and Fe-La/NHZ catalysts could be converted into aromatic hydrocarbons, and the reaction temperature affected hydrocarbon production. The aromatic compounds, such as propyl-benzene, 1-ethyl-3-methylbenzene, heptyl-benzene, 2-ethyl-naphthalene, etc., reached 35.51% over the Fe-La/NHZ_2 catalyst. In all cases, the zeolite-based catalysts are the most suitable to produce aromatic hydrocarbons. Metal impregnated (Fe and La) on nano HZSM-5 catalyst could improve the aromatics compounds due to increased metal and acid sites. Copyright © 2024 by Authors, Published by BCREC Publishing Group. This is an open access article under the CC BY-SA License (https://creativecommons.org/licenses/by-sa/4.0). |
first_indexed | 2024-03-07T19:45:00Z |
format | Article |
id | doaj.art-f642c2b9624d4c7dac0ac9655b55bdfa |
institution | Directory Open Access Journal |
issn | 1978-2993 |
language | English |
last_indexed | 2024-03-07T19:45:00Z |
publishDate | 2024-04-01 |
publisher | Masyarakat Katalis Indonesia - Indonesian Catalyst Society (MKICS) |
record_format | Article |
series | Bulletin of Chemical Reaction Engineering & Catalysis |
spelling | doaj.art-f642c2b9624d4c7dac0ac9655b55bdfa2024-02-29T04:28:03ZengMasyarakat Katalis Indonesia - Indonesian Catalyst Society (MKICS)Bulletin of Chemical Reaction Engineering & Catalysis1978-29932024-04-0119114114810.9767/bcrec.201168430Conversion of Sunan Candlenut Oil to Aromatic Hydrocarbons with Hydrocracking Process Over Nano-HZSM-5 CatalystMuhammad Al Muttaqii0https://orcid.org/0000-0001-5000-3478Maja Pranata Marbun1Sudibyo Sudibyo2Asif Aunillah3Dibyo Pranowo4Hasanudin Hasanudin5Nino Rinaldi6Teuku Beuna Bardant7Research Center for Chemistry, National Research and Innovation Agency (BRIN-Indonesia), South Tangerang 15314, IndonesiaDepartment of Chemical Engineering, University of Sonan Bonang, East Java 62311, IndonesiaResearch Center for Mining Technology, National Research and Innovation Agency (BRIN-Indonesia), South Lampung 35361, IndonesiaResearch Center for Agroindustry, National Research and Innovation Agency (BRIN-Indonesia), Cibinong Jl. Raya Jakarta-Bogor KM 46, Cibinong 16911, IndonesiaResearch Center for Horticultural and Estate Crops, National Research and Innovation Agency (BRIN-Indonesia), Cibinong 16911, IndonesiaDepartment of Chemistry, University of Sriwijaya, South Sumatera 30662, IndonesiaResearch Center for Chemistry, National Research and Innovation Agency (BRIN-Indonesia), South Tangerang 15314, IndonesiaResearch Center for Chemistry, National Research and Innovation Agency (BRIN-Indonesia), South Tangerang 15314, IndonesiaIn this paper, the catalysts (Nano-HZSM-5 and Fe-La/nano HZSM-5) were prepared with incipient wetness impregnation and applied for hydrocracking of Sunan candlenut oil. The hydrocracking process was conducted in a batch reactor with a pressure of 20-30 bar H2 gas for 2 h under various temperatures. The results demonstrated that hydrocracking of Sunan candlenut oil using nano HZSM-5 and Fe-La/NHZ catalysts could be converted into aromatic hydrocarbons, and the reaction temperature affected hydrocarbon production. The aromatic compounds, such as propyl-benzene, 1-ethyl-3-methylbenzene, heptyl-benzene, 2-ethyl-naphthalene, etc., reached 35.51% over the Fe-La/NHZ_2 catalyst. In all cases, the zeolite-based catalysts are the most suitable to produce aromatic hydrocarbons. Metal impregnated (Fe and La) on nano HZSM-5 catalyst could improve the aromatics compounds due to increased metal and acid sites. Copyright © 2024 by Authors, Published by BCREC Publishing Group. This is an open access article under the CC BY-SA License (https://creativecommons.org/licenses/by-sa/4.0).https://journal.bcrec.id/index.php/bcrec/article/view/20116hydrocrackingnano hzsm-5fe-la/nhz catalystssunan candlenut oilaromatics compounds |
spellingShingle | Muhammad Al Muttaqii Maja Pranata Marbun Sudibyo Sudibyo Asif Aunillah Dibyo Pranowo Hasanudin Hasanudin Nino Rinaldi Teuku Beuna Bardant Conversion of Sunan Candlenut Oil to Aromatic Hydrocarbons with Hydrocracking Process Over Nano-HZSM-5 Catalyst Bulletin of Chemical Reaction Engineering & Catalysis hydrocracking nano hzsm-5 fe-la/nhz catalysts sunan candlenut oil aromatics compounds |
title | Conversion of Sunan Candlenut Oil to Aromatic Hydrocarbons with Hydrocracking Process Over Nano-HZSM-5 Catalyst |
title_full | Conversion of Sunan Candlenut Oil to Aromatic Hydrocarbons with Hydrocracking Process Over Nano-HZSM-5 Catalyst |
title_fullStr | Conversion of Sunan Candlenut Oil to Aromatic Hydrocarbons with Hydrocracking Process Over Nano-HZSM-5 Catalyst |
title_full_unstemmed | Conversion of Sunan Candlenut Oil to Aromatic Hydrocarbons with Hydrocracking Process Over Nano-HZSM-5 Catalyst |
title_short | Conversion of Sunan Candlenut Oil to Aromatic Hydrocarbons with Hydrocracking Process Over Nano-HZSM-5 Catalyst |
title_sort | conversion of sunan candlenut oil to aromatic hydrocarbons with hydrocracking process over nano hzsm 5 catalyst |
topic | hydrocracking nano hzsm-5 fe-la/nhz catalysts sunan candlenut oil aromatics compounds |
url | https://journal.bcrec.id/index.php/bcrec/article/view/20116 |
work_keys_str_mv | AT muhammadalmuttaqii conversionofsunancandlenutoiltoaromatichydrocarbonswithhydrocrackingprocessovernanohzsm5catalyst AT majapranatamarbun conversionofsunancandlenutoiltoaromatichydrocarbonswithhydrocrackingprocessovernanohzsm5catalyst AT sudibyosudibyo conversionofsunancandlenutoiltoaromatichydrocarbonswithhydrocrackingprocessovernanohzsm5catalyst AT asifaunillah conversionofsunancandlenutoiltoaromatichydrocarbonswithhydrocrackingprocessovernanohzsm5catalyst AT dibyopranowo conversionofsunancandlenutoiltoaromatichydrocarbonswithhydrocrackingprocessovernanohzsm5catalyst AT hasanudinhasanudin conversionofsunancandlenutoiltoaromatichydrocarbonswithhydrocrackingprocessovernanohzsm5catalyst AT ninorinaldi conversionofsunancandlenutoiltoaromatichydrocarbonswithhydrocrackingprocessovernanohzsm5catalyst AT teukubeunabardant conversionofsunancandlenutoiltoaromatichydrocarbonswithhydrocrackingprocessovernanohzsm5catalyst |