Effect of the Deposit Temperature of ZnO Doped with Ni by HFCVD

The effect of the deposit temperature of zinc oxide (ZnO) doped with nickel (Ni) by hot filament chemical vapor deposition (HFCVD) technique is reported in this work. The technique allows depositing ZnO:Ni in short intervals (1 min). A deposit of undoped ZnO is used as a reference sample. The refere...

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Main Authors: Delfino R. Gutiérrez, Godofredo García-Salgado, Antonio Coyopol, Enrique Rosendo-Andrés, Román Romano, Crisóforo Morales, Alfredo Benítez, Francisco Severiano, Ana María Herrera, Francisco Ramírez-González
Format: Article
Language:English
Published: MDPI AG 2023-02-01
Series:Materials
Subjects:
Online Access:https://www.mdpi.com/1996-1944/16/4/1526
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author Delfino R. Gutiérrez
Godofredo García-Salgado
Antonio Coyopol
Enrique Rosendo-Andrés
Román Romano
Crisóforo Morales
Alfredo Benítez
Francisco Severiano
Ana María Herrera
Francisco Ramírez-González
author_facet Delfino R. Gutiérrez
Godofredo García-Salgado
Antonio Coyopol
Enrique Rosendo-Andrés
Román Romano
Crisóforo Morales
Alfredo Benítez
Francisco Severiano
Ana María Herrera
Francisco Ramírez-González
author_sort Delfino R. Gutiérrez
collection DOAJ
description The effect of the deposit temperature of zinc oxide (ZnO) doped with nickel (Ni) by hot filament chemical vapor deposition (HFCVD) technique is reported in this work. The technique allows depositing ZnO:Ni in short intervals (1 min). A deposit of undoped ZnO is used as a reference sample. The reference sample was deposited at 500 °C. The ZnO:Ni samples were deposited at 500 °C, 400 °C, 350 °C, and 300 °C. The samples were studied using structural, morphological, and optical characterization techniques. The Ni incorporation to the ZnO lattice was verified by the shift of the X-ray diffraction peaks, the Raman peaks, the band gap, and the photoluminescence measurements. It was found that the deposit temperature affects the structural, morphological, and optical properties of the ZnO:Ni samples too. The structure of the ZnO:Ni samples corresponds to the hexagonal structure. Different microstructures shapes such as spheres, sea urchins, and agglomerate were found in samples; their change is attributed to the deposit temperature variation. The intensity of the photoluminescence of the ZnO:Ni improves concerning the ZnO due to the Ni incorporation, but it decreases as the deposit temperature decreases.
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spelling doaj.art-f6568c7a451443fba96d29c0d999059a2023-11-16T21:50:58ZengMDPI AGMaterials1996-19442023-02-01164152610.3390/ma16041526Effect of the Deposit Temperature of ZnO Doped with Ni by HFCVDDelfino R. Gutiérrez0Godofredo García-Salgado1Antonio Coyopol2Enrique Rosendo-Andrés3Román Romano4Crisóforo Morales5Alfredo Benítez6Francisco Severiano7Ana María Herrera8Francisco Ramírez-González9IC-CIDS, Benemérita Universidad Autónoma de Puebla, Ed. IC5, Col. San Manuel, Puebla 72570, MexicoIC-CIDS, Benemérita Universidad Autónoma de Puebla, Ed. IC5, Col. San Manuel, Puebla 72570, MexicoIC-CIDS, Benemérita Universidad Autónoma de Puebla, Ed. IC5, Col. San Manuel, Puebla 72570, MexicoIC-CIDS, Benemérita Universidad Autónoma de Puebla, Ed. IC5, Col. San Manuel, Puebla 72570, MexicoIC-CIDS, Benemérita Universidad Autónoma de Puebla, Ed. IC5, Col. San Manuel, Puebla 72570, MexicoIC-CIDS, Benemérita Universidad Autónoma de Puebla, Ed. IC5, Col. San Manuel, Puebla 72570, MexicoCONACYT-CIO, Lomas del Bosque 115, Col. Lomas del Campestre, León 37150, MexicoCONACYT-IPN, Av. Insurgentes Sur 1582, Col. Crédito Constructor, Del. Benito Juárez, Ciudad de Mexico 03940, MexicoDepartamento de Investigación en Física, Universidad de Sonora (UNISON), Hermosillo 83190, MexicoIIIER, Universidad de Ciencias y Artes de Chiapas, Libramiento Norte 1150 Lajas Maciel, Tuxtla Gutiérrez 29039, MexicoThe effect of the deposit temperature of zinc oxide (ZnO) doped with nickel (Ni) by hot filament chemical vapor deposition (HFCVD) technique is reported in this work. The technique allows depositing ZnO:Ni in short intervals (1 min). A deposit of undoped ZnO is used as a reference sample. The reference sample was deposited at 500 °C. The ZnO:Ni samples were deposited at 500 °C, 400 °C, 350 °C, and 300 °C. The samples were studied using structural, morphological, and optical characterization techniques. The Ni incorporation to the ZnO lattice was verified by the shift of the X-ray diffraction peaks, the Raman peaks, the band gap, and the photoluminescence measurements. It was found that the deposit temperature affects the structural, morphological, and optical properties of the ZnO:Ni samples too. The structure of the ZnO:Ni samples corresponds to the hexagonal structure. Different microstructures shapes such as spheres, sea urchins, and agglomerate were found in samples; their change is attributed to the deposit temperature variation. The intensity of the photoluminescence of the ZnO:Ni improves concerning the ZnO due to the Ni incorporation, but it decreases as the deposit temperature decreases.https://www.mdpi.com/1996-1944/16/4/1526HFCVD techniquezinc oxidenickeldopanttemperature
spellingShingle Delfino R. Gutiérrez
Godofredo García-Salgado
Antonio Coyopol
Enrique Rosendo-Andrés
Román Romano
Crisóforo Morales
Alfredo Benítez
Francisco Severiano
Ana María Herrera
Francisco Ramírez-González
Effect of the Deposit Temperature of ZnO Doped with Ni by HFCVD
Materials
HFCVD technique
zinc oxide
nickel
dopant
temperature
title Effect of the Deposit Temperature of ZnO Doped with Ni by HFCVD
title_full Effect of the Deposit Temperature of ZnO Doped with Ni by HFCVD
title_fullStr Effect of the Deposit Temperature of ZnO Doped with Ni by HFCVD
title_full_unstemmed Effect of the Deposit Temperature of ZnO Doped with Ni by HFCVD
title_short Effect of the Deposit Temperature of ZnO Doped with Ni by HFCVD
title_sort effect of the deposit temperature of zno doped with ni by hfcvd
topic HFCVD technique
zinc oxide
nickel
dopant
temperature
url https://www.mdpi.com/1996-1944/16/4/1526
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