One Step Catalytic Conversion of Polysaccharides in <i>Ulva prolifera</i> to Lactic Acid and Value-Added Chemicals
The production of lactic acid and value-added chemicals (such as hydroxypropanone, glycolic acid, and formic acid) directly from <i>Ulva prolifera</i> via one-step catalytic process was studied. The effect of different amounts of YCl<sub>3</sub>-derived catalysts on the hydro...
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MDPI AG
2023-01-01
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author | Mingyu Li Yingdong Zhou Changwei Hu |
author_facet | Mingyu Li Yingdong Zhou Changwei Hu |
author_sort | Mingyu Li |
collection | DOAJ |
description | The production of lactic acid and value-added chemicals (such as hydroxypropanone, glycolic acid, and formic acid) directly from <i>Ulva prolifera</i> via one-step catalytic process was studied. The effect of different amounts of YCl<sub>3</sub>-derived catalysts on the hydrothermal conversion of carbohydrates in <i>Ulva prolifera</i> was explored, and the reaction conditions were optimized. In this catalytic system, rhamnose could be extracted from <i>Ulva prolifera</i> and converted in situ into lactic acid and hydroxypropanone at 160 °C, while all the glucose, xylose, and rhamnose were fractionated and completely converted to lactic acid at 220 °C or at a higher temperature, via several consecutive and/or parallel catalytic processes. The highest yield of lactic acid obtained was 31.4 wt% under the optimized conditions. The hydrothermal conversion of <i>Ulva prolifera</i> occurred rapidly (within 10 min) and showed promise to valorize <i>Ulva prolifera</i>. |
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language | English |
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spelling | doaj.art-f6af4dbc378244b68a30ac18059bdb122023-11-16T19:40:36ZengMDPI AGCatalysts2073-43442023-01-0113226210.3390/catal13020262One Step Catalytic Conversion of Polysaccharides in <i>Ulva prolifera</i> to Lactic Acid and Value-Added ChemicalsMingyu Li0Yingdong Zhou1Changwei Hu2Key Laboratory of Green Chemistry and Technology, Ministry of Education, College of Chemistry, Sichuan University, Chengdu 610064, ChinaKey Laboratory of Green Chemistry and Technology, Ministry of Education, College of Chemistry, Sichuan University, Chengdu 610064, ChinaKey Laboratory of Green Chemistry and Technology, Ministry of Education, College of Chemistry, Sichuan University, Chengdu 610064, ChinaThe production of lactic acid and value-added chemicals (such as hydroxypropanone, glycolic acid, and formic acid) directly from <i>Ulva prolifera</i> via one-step catalytic process was studied. The effect of different amounts of YCl<sub>3</sub>-derived catalysts on the hydrothermal conversion of carbohydrates in <i>Ulva prolifera</i> was explored, and the reaction conditions were optimized. In this catalytic system, rhamnose could be extracted from <i>Ulva prolifera</i> and converted in situ into lactic acid and hydroxypropanone at 160 °C, while all the glucose, xylose, and rhamnose were fractionated and completely converted to lactic acid at 220 °C or at a higher temperature, via several consecutive and/or parallel catalytic processes. The highest yield of lactic acid obtained was 31.4 wt% under the optimized conditions. The hydrothermal conversion of <i>Ulva prolifera</i> occurred rapidly (within 10 min) and showed promise to valorize <i>Ulva prolifera</i>.https://www.mdpi.com/2073-4344/13/2/262<i>Ulva prolifera</i>lactic acidhydrothermal conversioncatalystYCl<sub>3</sub> |
spellingShingle | Mingyu Li Yingdong Zhou Changwei Hu One Step Catalytic Conversion of Polysaccharides in <i>Ulva prolifera</i> to Lactic Acid and Value-Added Chemicals Catalysts <i>Ulva prolifera</i> lactic acid hydrothermal conversion catalyst YCl<sub>3</sub> |
title | One Step Catalytic Conversion of Polysaccharides in <i>Ulva prolifera</i> to Lactic Acid and Value-Added Chemicals |
title_full | One Step Catalytic Conversion of Polysaccharides in <i>Ulva prolifera</i> to Lactic Acid and Value-Added Chemicals |
title_fullStr | One Step Catalytic Conversion of Polysaccharides in <i>Ulva prolifera</i> to Lactic Acid and Value-Added Chemicals |
title_full_unstemmed | One Step Catalytic Conversion of Polysaccharides in <i>Ulva prolifera</i> to Lactic Acid and Value-Added Chemicals |
title_short | One Step Catalytic Conversion of Polysaccharides in <i>Ulva prolifera</i> to Lactic Acid and Value-Added Chemicals |
title_sort | one step catalytic conversion of polysaccharides in i ulva prolifera i to lactic acid and value added chemicals |
topic | <i>Ulva prolifera</i> lactic acid hydrothermal conversion catalyst YCl<sub>3</sub> |
url | https://www.mdpi.com/2073-4344/13/2/262 |
work_keys_str_mv | AT mingyuli onestepcatalyticconversionofpolysaccharidesiniulvaproliferaitolacticacidandvalueaddedchemicals AT yingdongzhou onestepcatalyticconversionofpolysaccharidesiniulvaproliferaitolacticacidandvalueaddedchemicals AT changweihu onestepcatalyticconversionofpolysaccharidesiniulvaproliferaitolacticacidandvalueaddedchemicals |