Exploring Gel-Point Identification in Epoxy Resin Using Rheology and Unsupervised Learning

Any thermoset resin’s processing properties and end-use performance are heavily influenced by the gel time. The complicated viscosity of resin as a function of temperature is investigated in this work, with a particular emphasis on identifying the gel point and comprehending polymerization. Rheology...

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Main Authors: Eddie Gazo Hanna, Khaled Younes, Semaan Amine, Rabih Roufayel
Format: Article
Language:English
Published: MDPI AG 2023-10-01
Series:Gels
Subjects:
Online Access:https://www.mdpi.com/2310-2861/9/10/828
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author Eddie Gazo Hanna
Khaled Younes
Semaan Amine
Rabih Roufayel
author_facet Eddie Gazo Hanna
Khaled Younes
Semaan Amine
Rabih Roufayel
author_sort Eddie Gazo Hanna
collection DOAJ
description Any thermoset resin’s processing properties and end-use performance are heavily influenced by the gel time. The complicated viscosity of resin as a function of temperature is investigated in this work, with a particular emphasis on identifying the gel point and comprehending polymerization. Rheology studies carried out using a plate-plate controlled stress rheometer under isothermal conditions were used to compare three experimental techniques for figuring out an epoxy resin’s gel point. We also look at the basic modifications that take place during polymerization. We verify the reliability of the three strategies by including Principal Component Analysis (PCA), an unsupervised machine learning methodology. PCA assists in uncovering hidden connections between these methods and various affecting factors. PCA serves a dual role in our study, confirming method validity and identifying patterns. It sheds light on the intricate relationships between experimental techniques and material properties. This concise study expands our understanding of resin behavior and provides insights that are essential for optimizing resin-based processes in a variety of industrial applications.
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spelling doaj.art-f6e58bd90188482da101608e7ceeff932023-11-19T16:35:58ZengMDPI AGGels2310-28612023-10-0191082810.3390/gels9100828Exploring Gel-Point Identification in Epoxy Resin Using Rheology and Unsupervised LearningEddie Gazo Hanna0Khaled Younes1Semaan Amine2Rabih Roufayel3College of Engineering and Technology, American University of the Middle East, Egaila 54200, KuwaitCollege of Engineering and Technology, American University of the Middle East, Egaila 54200, KuwaitCollege of Engineering and Technology, American University of the Middle East, Egaila 54200, KuwaitCollege of Engineering and Technology, American University of the Middle East, Egaila 54200, KuwaitAny thermoset resin’s processing properties and end-use performance are heavily influenced by the gel time. The complicated viscosity of resin as a function of temperature is investigated in this work, with a particular emphasis on identifying the gel point and comprehending polymerization. Rheology studies carried out using a plate-plate controlled stress rheometer under isothermal conditions were used to compare three experimental techniques for figuring out an epoxy resin’s gel point. We also look at the basic modifications that take place during polymerization. We verify the reliability of the three strategies by including Principal Component Analysis (PCA), an unsupervised machine learning methodology. PCA assists in uncovering hidden connections between these methods and various affecting factors. PCA serves a dual role in our study, confirming method validity and identifying patterns. It sheds light on the intricate relationships between experimental techniques and material properties. This concise study expands our understanding of resin behavior and provides insights that are essential for optimizing resin-based processes in a variety of industrial applications.https://www.mdpi.com/2310-2861/9/10/828epoxyrheologygel pointthermosetprincipal component analysis (PCA)
spellingShingle Eddie Gazo Hanna
Khaled Younes
Semaan Amine
Rabih Roufayel
Exploring Gel-Point Identification in Epoxy Resin Using Rheology and Unsupervised Learning
Gels
epoxy
rheology
gel point
thermoset
principal component analysis (PCA)
title Exploring Gel-Point Identification in Epoxy Resin Using Rheology and Unsupervised Learning
title_full Exploring Gel-Point Identification in Epoxy Resin Using Rheology and Unsupervised Learning
title_fullStr Exploring Gel-Point Identification in Epoxy Resin Using Rheology and Unsupervised Learning
title_full_unstemmed Exploring Gel-Point Identification in Epoxy Resin Using Rheology and Unsupervised Learning
title_short Exploring Gel-Point Identification in Epoxy Resin Using Rheology and Unsupervised Learning
title_sort exploring gel point identification in epoxy resin using rheology and unsupervised learning
topic epoxy
rheology
gel point
thermoset
principal component analysis (PCA)
url https://www.mdpi.com/2310-2861/9/10/828
work_keys_str_mv AT eddiegazohanna exploringgelpointidentificationinepoxyresinusingrheologyandunsupervisedlearning
AT khaledyounes exploringgelpointidentificationinepoxyresinusingrheologyandunsupervisedlearning
AT semaanamine exploringgelpointidentificationinepoxyresinusingrheologyandunsupervisedlearning
AT rabihroufayel exploringgelpointidentificationinepoxyresinusingrheologyandunsupervisedlearning