Influence of CaO Addition, FeO/SiO2 , and MgO/SiO2 on the Melting Characteristic Temperatures of FeO-SiO2-MgO-CaO System

In order to decrease the oxidation temperature of fayalite in molten nickel slags, the influence of CaO addition, FeO/SiO2, and MgO/SiO2 on melting characteristic temperatures of FeO-SiO2-MgO-CaO system were investigated. The melting characteristic temperatures, including softening temperature (Ts),...

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Main Authors: Yongbo Ma, Xueyan Du
Format: Article
Language:English
Published: Associação Brasileira de Metalurgia e Materiais (ABM); Associação Brasileira de Cerâmica (ABC); Associação Brasileira de Polímeros (ABPol) 2019-04-01
Series:Materials Research
Subjects:
Online Access:http://www.scielo.br/pdf/mr/v22n3/1516-1439-mr-22-03-e20180645.pdf
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author Yongbo Ma
Xueyan Du
author_facet Yongbo Ma
Xueyan Du
author_sort Yongbo Ma
collection DOAJ
description In order to decrease the oxidation temperature of fayalite in molten nickel slags, the influence of CaO addition, FeO/SiO2, and MgO/SiO2 on melting characteristic temperatures of FeO-SiO2-MgO-CaO system were investigated. The melting characteristic temperatures, including softening temperature (Ts), hemispherical temperature (Th), and flow temperature (Tf),were measured with hot stage microscope. Experimental results showed that the melting characteristic temperatures first decreased sharply and then increased slowly with increasing w(CaO) for samples at given FeO/SiO2 and MgO/SiO2 ratios. The melting characteristic temperatures of samples without CaO addition were much higher than that of samples with different CaO addition, which was mainly caused by the phase components at different compositions. The variation of melting characteristic temperatures were described in detail. Phase components and liquid fractions were calculated by FactSage 7.1, which was good agreement with the XRD patterns.
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spelling doaj.art-f6fc290e1a704df79a13d4d210565ee72022-12-21T21:20:09ZengAssociação Brasileira de Metalurgia e Materiais (ABM); Associação Brasileira de Cerâmica (ABC); Associação Brasileira de Polímeros (ABPol)Materials Research1516-14392019-04-0122310.1590/1980-5373-mr-2018-0645Influence of CaO Addition, FeO/SiO2 , and MgO/SiO2 on the Melting Characteristic Temperatures of FeO-SiO2-MgO-CaO SystemYongbo Mahttps://orcid.org/0000-0002-0939-8727Xueyan DuIn order to decrease the oxidation temperature of fayalite in molten nickel slags, the influence of CaO addition, FeO/SiO2, and MgO/SiO2 on melting characteristic temperatures of FeO-SiO2-MgO-CaO system were investigated. The melting characteristic temperatures, including softening temperature (Ts), hemispherical temperature (Th), and flow temperature (Tf),were measured with hot stage microscope. Experimental results showed that the melting characteristic temperatures first decreased sharply and then increased slowly with increasing w(CaO) for samples at given FeO/SiO2 and MgO/SiO2 ratios. The melting characteristic temperatures of samples without CaO addition were much higher than that of samples with different CaO addition, which was mainly caused by the phase components at different compositions. The variation of melting characteristic temperatures were described in detail. Phase components and liquid fractions were calculated by FactSage 7.1, which was good agreement with the XRD patterns.http://www.scielo.br/pdf/mr/v22n3/1516-1439-mr-22-03-e20180645.pdfmelting characteristic temperaturenickel slagFeO/SiO2MgO/SiO2w(CaO)
spellingShingle Yongbo Ma
Xueyan Du
Influence of CaO Addition, FeO/SiO2 , and MgO/SiO2 on the Melting Characteristic Temperatures of FeO-SiO2-MgO-CaO System
Materials Research
melting characteristic temperature
nickel slag
FeO/SiO2
MgO/SiO2
w(CaO)
title Influence of CaO Addition, FeO/SiO2 , and MgO/SiO2 on the Melting Characteristic Temperatures of FeO-SiO2-MgO-CaO System
title_full Influence of CaO Addition, FeO/SiO2 , and MgO/SiO2 on the Melting Characteristic Temperatures of FeO-SiO2-MgO-CaO System
title_fullStr Influence of CaO Addition, FeO/SiO2 , and MgO/SiO2 on the Melting Characteristic Temperatures of FeO-SiO2-MgO-CaO System
title_full_unstemmed Influence of CaO Addition, FeO/SiO2 , and MgO/SiO2 on the Melting Characteristic Temperatures of FeO-SiO2-MgO-CaO System
title_short Influence of CaO Addition, FeO/SiO2 , and MgO/SiO2 on the Melting Characteristic Temperatures of FeO-SiO2-MgO-CaO System
title_sort influence of cao addition feo sio2 and mgo sio2 on the melting characteristic temperatures of feo sio2 mgo cao system
topic melting characteristic temperature
nickel slag
FeO/SiO2
MgO/SiO2
w(CaO)
url http://www.scielo.br/pdf/mr/v22n3/1516-1439-mr-22-03-e20180645.pdf
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