Viscoelastic Analysis of Pectin Hydrogels Regenerated from Citrus Pomelo Waste by Gelling Effects of Calcium Ion Crosslinking at Different pHs
Pectin was extracted from citrus pomelo waste, and the effects of calcium ions (Ca<sup>2+</sup>) on the gelation and hydrogels properties were investigated over a pH range of 3.2–8 by using viscoelastic analysis. The gelatinization of Ca<sup>2+</sup>-pectin was examined at co...
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| Format: | Article |
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MDPI AG
2022-12-01
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| Online Access: | https://www.mdpi.com/2310-2861/8/12/814 |
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| author | Tu Minh Tran Vo Takaomi Kobayashi Pranut Potiyaraj |
| author_facet | Tu Minh Tran Vo Takaomi Kobayashi Pranut Potiyaraj |
| author_sort | Tu Minh Tran Vo |
| collection | DOAJ |
| description | Pectin was extracted from citrus pomelo waste, and the effects of calcium ions (Ca<sup>2+</sup>) on the gelation and hydrogels properties were investigated over a pH range of 3.2–8 by using viscoelastic analysis. The gelatinization of Ca<sup>2+</sup>-pectin was examined at concentrations of 0.9, 1.8, 2.4, and 3.6 M of Ca<sup>2+</sup> in aqueous pectin solutions of 1%, 2%, 3%, and 4%. The gel transition of Ca<sup>2+</sup>-pectin solution to hydrogels was determined by measuring the storage modulus (G’) and loss modulus (G”) under mechanical strain from 0.01 to 100%. In a hydrogel of 3% pectin at Ca<sup>2+</sup> = 2.4 M, as pH increased to 7, the G’ at 0.01 strain % was 3 × 10<sup>4</sup> Pa, and 3 × 10<sup>3</sup> Pa at pH 5, indicating that the crosslinking weakened at acidic pH. Due to the crosslinking between the calcium ions and the ionized carboxylic acid groups of pectin, the resulting hydrogel became stiff. When the mechanical strain % was in the range of 0.01–1%, G’ was unchanged and G” was an order of magnitude smaller than G’, indicating that the mechanical stress was relieved by the gel. In the range of 1–100%, the gel deformation progressed and both the moduli values were dropped. Collapse from the gel state to the solution state occurred at 1–10 strain %, but the softer hydrogels with G’ of 10<sup>3</sup> Pa had a larger strain % than the stiffer hydrogels with G’ of 10<sup>4</sup> Pa. |
| first_indexed | 2024-03-09T16:31:56Z |
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| language | English |
| last_indexed | 2024-03-09T16:31:56Z |
| publishDate | 2022-12-01 |
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| spelling | doaj.art-f70583a60f424d7ea9a5c9523846a2b22023-11-24T15:01:31ZengMDPI AGGels2310-28612022-12-0181281410.3390/gels8120814Viscoelastic Analysis of Pectin Hydrogels Regenerated from Citrus Pomelo Waste by Gelling Effects of Calcium Ion Crosslinking at Different pHsTu Minh Tran Vo0Takaomi Kobayashi1Pranut Potiyaraj2Department of Energy and Environmental Science, Nagaoka University of Technology, 1603-1 Kamitomioka, Nagaoka 940-2188, Niigata, JapanDepartment of Energy and Environmental Science, Nagaoka University of Technology, 1603-1 Kamitomioka, Nagaoka 940-2188, Niigata, JapanDepartment of Materials Science, Faculty of Science, Chulalongkorn University, Bangkok 10330, ThailandPectin was extracted from citrus pomelo waste, and the effects of calcium ions (Ca<sup>2+</sup>) on the gelation and hydrogels properties were investigated over a pH range of 3.2–8 by using viscoelastic analysis. The gelatinization of Ca<sup>2+</sup>-pectin was examined at concentrations of 0.9, 1.8, 2.4, and 3.6 M of Ca<sup>2+</sup> in aqueous pectin solutions of 1%, 2%, 3%, and 4%. The gel transition of Ca<sup>2+</sup>-pectin solution to hydrogels was determined by measuring the storage modulus (G’) and loss modulus (G”) under mechanical strain from 0.01 to 100%. In a hydrogel of 3% pectin at Ca<sup>2+</sup> = 2.4 M, as pH increased to 7, the G’ at 0.01 strain % was 3 × 10<sup>4</sup> Pa, and 3 × 10<sup>3</sup> Pa at pH 5, indicating that the crosslinking weakened at acidic pH. Due to the crosslinking between the calcium ions and the ionized carboxylic acid groups of pectin, the resulting hydrogel became stiff. When the mechanical strain % was in the range of 0.01–1%, G’ was unchanged and G” was an order of magnitude smaller than G’, indicating that the mechanical stress was relieved by the gel. In the range of 1–100%, the gel deformation progressed and both the moduli values were dropped. Collapse from the gel state to the solution state occurred at 1–10 strain %, but the softer hydrogels with G’ of 10<sup>3</sup> Pa had a larger strain % than the stiffer hydrogels with G’ of 10<sup>4</sup> Pa.https://www.mdpi.com/2310-2861/8/12/814pectin hydrogelviscoelasticitypomelo albedoCa<sup>2+</sup> crosslinkingpH-effectgelation |
| spellingShingle | Tu Minh Tran Vo Takaomi Kobayashi Pranut Potiyaraj Viscoelastic Analysis of Pectin Hydrogels Regenerated from Citrus Pomelo Waste by Gelling Effects of Calcium Ion Crosslinking at Different pHs Gels pectin hydrogel viscoelasticity pomelo albedo Ca<sup>2+</sup> crosslinking pH-effect gelation |
| title | Viscoelastic Analysis of Pectin Hydrogels Regenerated from Citrus Pomelo Waste by Gelling Effects of Calcium Ion Crosslinking at Different pHs |
| title_full | Viscoelastic Analysis of Pectin Hydrogels Regenerated from Citrus Pomelo Waste by Gelling Effects of Calcium Ion Crosslinking at Different pHs |
| title_fullStr | Viscoelastic Analysis of Pectin Hydrogels Regenerated from Citrus Pomelo Waste by Gelling Effects of Calcium Ion Crosslinking at Different pHs |
| title_full_unstemmed | Viscoelastic Analysis of Pectin Hydrogels Regenerated from Citrus Pomelo Waste by Gelling Effects of Calcium Ion Crosslinking at Different pHs |
| title_short | Viscoelastic Analysis of Pectin Hydrogels Regenerated from Citrus Pomelo Waste by Gelling Effects of Calcium Ion Crosslinking at Different pHs |
| title_sort | viscoelastic analysis of pectin hydrogels regenerated from citrus pomelo waste by gelling effects of calcium ion crosslinking at different phs |
| topic | pectin hydrogel viscoelasticity pomelo albedo Ca<sup>2+</sup> crosslinking pH-effect gelation |
| url | https://www.mdpi.com/2310-2861/8/12/814 |
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