Zeolite Synthesis from Coal Fly Ash Prepared by Hydrothermal Treatment Method and Effect of Particle Size on Its Reaction Mechanism [Translated]†

We investigated an effect of fly ash particle size on the synthesis of zeolites from coal fly ash, proposed and formulated the formation mechanism of zeolite. It is found that the treatment time for the zeolites to synthesize decreases with a decrease in feed fl...

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Main Authors: Kunihiro Fukui, Hideto Yoshida, Hironori Sakaguchi, MItsuhiro Arita
Format: Article
Language:English
Published: Hosokawa Powder Technology Foundation 2014-05-01
Series:KONA Powder and Particle Journal
Subjects:
Online Access:https://www.jstage.jst.go.jp/article/kona/19/0/19_2001025/_pdf/-char/en
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author Kunihiro Fukui
Hideto Yoshida
Hironori Sakaguchi
MItsuhiro Arita
author_facet Kunihiro Fukui
Hideto Yoshida
Hironori Sakaguchi
MItsuhiro Arita
author_sort Kunihiro Fukui
collection DOAJ
description We investigated an effect of fly ash particle size on the synthesis of zeolites from coal fly ash, proposed and formulated the formation mechanism of zeolite. It is found that the treatment time for the zeolites to synthesize decreases with a decrease in feed fly ash particle size. When the feed size is small, both phillipsite and hydroxysodalite are synthesized by hydrothermal treatment with NaOH solution. Only phillipsite is synthesized when large fly ash particles are used. The zeolite from the fly ash having 2.1 μm mass median diameter indicates the maximum NH4+-adsorption capacity. The change in liquid ion concentrations calculated by the newly proposed model agrees with the experimental results. It is assumed that dissoluble silica is contained by about twice the mass of dissoluble alumina in the large fly ash particles, while in the case of small ones, they are almost equal.† This report was originally printed in Kagaku Kogaku Ronbunshu, 25(6), 987-992 (1999) in Japanese, before being translated into English by KONA Editorial Committee with the permission of the editorial committee of the Soc. Chemical Engineers, Japan.
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spelling doaj.art-f70c7d33a6054ce08d98e665ae7baf5c2022-12-21T23:16:46ZengHosokawa Powder Technology FoundationKONA Powder and Particle Journal0288-45342187-55372014-05-0119023223910.14356/kona.2001025konaZeolite Synthesis from Coal Fly Ash Prepared by Hydrothermal Treatment Method and Effect of Particle Size on Its Reaction Mechanism [Translated]†Kunihiro Fukui0Hideto Yoshida1Hironori Sakaguchi2MItsuhiro Arita3Department of Chemical Engineering, Hiroshima UniversityDepartment of Chemical Engineering, Hiroshima UniversityDepartment of Chemical Engineering, Hiroshima UniversityDepartment of Chemical Engineering, Hiroshima UniversityWe investigated an effect of fly ash particle size on the synthesis of zeolites from coal fly ash, proposed and formulated the formation mechanism of zeolite. It is found that the treatment time for the zeolites to synthesize decreases with a decrease in feed fly ash particle size. When the feed size is small, both phillipsite and hydroxysodalite are synthesized by hydrothermal treatment with NaOH solution. Only phillipsite is synthesized when large fly ash particles are used. The zeolite from the fly ash having 2.1 μm mass median diameter indicates the maximum NH4+-adsorption capacity. The change in liquid ion concentrations calculated by the newly proposed model agrees with the experimental results. It is assumed that dissoluble silica is contained by about twice the mass of dissoluble alumina in the large fly ash particles, while in the case of small ones, they are almost equal.† This report was originally printed in Kagaku Kogaku Ronbunshu, 25(6), 987-992 (1999) in Japanese, before being translated into English by KONA Editorial Committee with the permission of the editorial committee of the Soc. Chemical Engineers, Japan.https://www.jstage.jst.go.jp/article/kona/19/0/19_2001025/_pdf/-char/enfly ashhydrothermal synthesisparticle sizezeolite
spellingShingle Kunihiro Fukui
Hideto Yoshida
Hironori Sakaguchi
MItsuhiro Arita
Zeolite Synthesis from Coal Fly Ash Prepared by Hydrothermal Treatment Method and Effect of Particle Size on Its Reaction Mechanism [Translated]†
KONA Powder and Particle Journal
fly ash
hydrothermal synthesis
particle size
zeolite
title Zeolite Synthesis from Coal Fly Ash Prepared by Hydrothermal Treatment Method and Effect of Particle Size on Its Reaction Mechanism [Translated]†
title_full Zeolite Synthesis from Coal Fly Ash Prepared by Hydrothermal Treatment Method and Effect of Particle Size on Its Reaction Mechanism [Translated]†
title_fullStr Zeolite Synthesis from Coal Fly Ash Prepared by Hydrothermal Treatment Method and Effect of Particle Size on Its Reaction Mechanism [Translated]†
title_full_unstemmed Zeolite Synthesis from Coal Fly Ash Prepared by Hydrothermal Treatment Method and Effect of Particle Size on Its Reaction Mechanism [Translated]†
title_short Zeolite Synthesis from Coal Fly Ash Prepared by Hydrothermal Treatment Method and Effect of Particle Size on Its Reaction Mechanism [Translated]†
title_sort zeolite synthesis from coal fly ash prepared by hydrothermal treatment method and effect of particle size on its reaction mechanism translated †
topic fly ash
hydrothermal synthesis
particle size
zeolite
url https://www.jstage.jst.go.jp/article/kona/19/0/19_2001025/_pdf/-char/en
work_keys_str_mv AT kunihirofukui zeolitesynthesisfromcoalflyashpreparedbyhydrothermaltreatmentmethodandeffectofparticlesizeonitsreactionmechanismtranslated
AT hidetoyoshida zeolitesynthesisfromcoalflyashpreparedbyhydrothermaltreatmentmethodandeffectofparticlesizeonitsreactionmechanismtranslated
AT hironorisakaguchi zeolitesynthesisfromcoalflyashpreparedbyhydrothermaltreatmentmethodandeffectofparticlesizeonitsreactionmechanismtranslated
AT mitsuhiroarita zeolitesynthesisfromcoalflyashpreparedbyhydrothermaltreatmentmethodandeffectofparticlesizeonitsreactionmechanismtranslated