Hinged and Wide: A New P^P Ligand for Emissive [Cu(P^P)(N^N)][PF<sub>6</sub>] Complexes

Hinged and Wide: A New P^P Ligand for Emissive [Cu(P^P)(N^N)][PF<sub>6</sub>] Complexes

Heteroleptic [Cu(BIPHEP)(N^N)][PF<sub>6</sub>] complexes (BIPHEP = 1,1&#8242;-biphenyl-2,2&#8242;-diylbis(diphenylphosphane)), in which N^N is 2,2&#8242;-bipyridine (bpy), 6-methyl-2,2&#8242;-bipyridine (6-Mebpy), 6-ethyl-2,2&#8242;-bipyridine (6-Etbpy), or 5,5&#8...

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Bibliographic Details
Main Authors: Sarah Keller, Matthias Bantle, Alessandro Prescimone, Edwin C. Constable, Catherine E. Housecroft
Format: Article
Language:English
Published: MDPI AG 2019-10-01
Series:Molecules
Subjects:
copper(i)
bis(phosphane)
2,2′-bipyridine
x-ray structure
photophysics
tadf
Online Access:https://www.mdpi.com/1420-3049/24/21/3934

Internet

https://www.mdpi.com/1420-3049/24/21/3934

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