[(1S,2S)-2-(1-{[2-(2-Oxidobenzylideneamino)cyclohexyl]imino}ethyl)phenolato-κ4O,N,N′,O′]copper(II)
In the title compound, [Cu(C21H22N2O2)], the cyclohexyl ring adopts a chair conformation with the two imine groups linked at equatorial positions. The CuII ion is coordinated by two N atoms and two O atoms from the bis-Schiff base ligand in a slightly distorted square-planar geometry. The dihedral a...
| Main Authors: | , , |
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2010-07-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536810022889 |
| _version_ | 1818916462039924736 |
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| author | Nura Suleiman Gwaram Hamid Khaledi Hapipah Mohd Ali |
| author_facet | Nura Suleiman Gwaram Hamid Khaledi Hapipah Mohd Ali |
| author_sort | Nura Suleiman Gwaram |
| collection | DOAJ |
| description | In the title compound, [Cu(C21H22N2O2)], the cyclohexyl ring adopts a chair conformation with the two imine groups linked at equatorial positions. The CuII ion is coordinated by two N atoms and two O atoms from the bis-Schiff base ligand in a slightly distorted square-planar geometry. The dihedral angle between the two benzene rings is 45.89 (9)°. The crystal structure is devoid of any classical hydrogen bonds. However, intermolecular C—H...O interactions are present and stabilize the structure. |
| first_indexed | 2024-12-20T00:18:33Z |
| format | Article |
| id | doaj.art-f7177c0831c444aaaf4548adbdb23707 |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-20T00:18:33Z |
| publishDate | 2010-07-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-f7177c0831c444aaaf4548adbdb237072022-12-21T20:00:15ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682010-07-01667m813m81310.1107/S1600536810022889[(1S,2S)-2-(1-{[2-(2-Oxidobenzylideneamino)cyclohexyl]imino}ethyl)phenolato-κ4O,N,N′,O′]copper(II)Nura Suleiman GwaramHamid KhalediHapipah Mohd AliIn the title compound, [Cu(C21H22N2O2)], the cyclohexyl ring adopts a chair conformation with the two imine groups linked at equatorial positions. The CuII ion is coordinated by two N atoms and two O atoms from the bis-Schiff base ligand in a slightly distorted square-planar geometry. The dihedral angle between the two benzene rings is 45.89 (9)°. The crystal structure is devoid of any classical hydrogen bonds. However, intermolecular C—H...O interactions are present and stabilize the structure.http://scripts.iucr.org/cgi-bin/paper?S1600536810022889 |
| spellingShingle | Nura Suleiman Gwaram Hamid Khaledi Hapipah Mohd Ali [(1S,2S)-2-(1-{[2-(2-Oxidobenzylideneamino)cyclohexyl]imino}ethyl)phenolato-κ4O,N,N′,O′]copper(II) Acta Crystallographica Section E |
| title | [(1S,2S)-2-(1-{[2-(2-Oxidobenzylideneamino)cyclohexyl]imino}ethyl)phenolato-κ4O,N,N′,O′]copper(II) |
| title_full | [(1S,2S)-2-(1-{[2-(2-Oxidobenzylideneamino)cyclohexyl]imino}ethyl)phenolato-κ4O,N,N′,O′]copper(II) |
| title_fullStr | [(1S,2S)-2-(1-{[2-(2-Oxidobenzylideneamino)cyclohexyl]imino}ethyl)phenolato-κ4O,N,N′,O′]copper(II) |
| title_full_unstemmed | [(1S,2S)-2-(1-{[2-(2-Oxidobenzylideneamino)cyclohexyl]imino}ethyl)phenolato-κ4O,N,N′,O′]copper(II) |
| title_short | [(1S,2S)-2-(1-{[2-(2-Oxidobenzylideneamino)cyclohexyl]imino}ethyl)phenolato-κ4O,N,N′,O′]copper(II) |
| title_sort | 1s 2s 2 1 2 2 oxidobenzylideneamino cyclohexyl imino ethyl phenolato amp 954 4o n n amp 8242 o amp 8242 copper ii |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536810022889 |
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