Desulfurization of AL-Ahdab Crude Oil using Oxidative Processes
Two different oxidative desulfurization strategies based on oxidation/adsorption or oxidation/extraction were evaluated for the desulfurization of AL-Ahdab (AHD) sour crude oil (3.9wt% sulfur content). In the oxidation process, a homogenous oxidizing agent comprising of hydrogen peroxide and formic...
| Main Authors: | , |
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| Format: | Article |
| Language: | English |
| Published: |
University of Baghdad
2015-07-01
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| Series: | Journal of Engineering |
| Online Access: | https://www.jcoeng.edu.iq/index.php/main/article/view/396/343 |
| _version_ | 1797709536865288192 |
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| author | Neran Khalel Ibrahim Saja Mohsen Jabbar |
| author_facet | Neran Khalel Ibrahim Saja Mohsen Jabbar |
| author_sort | Neran Khalel Ibrahim |
| collection | DOAJ |
| description | Two different oxidative desulfurization strategies based on oxidation/adsorption or oxidation/extraction were evaluated for the desulfurization of AL-Ahdab (AHD) sour crude oil (3.9wt% sulfur content). In the oxidation process, a homogenous oxidizing agent comprising of hydrogen peroxide and formic acid was used. Activated carbons were used as sorbent/catalyst in the oxidation/adsorption process while acetonitrile was used as an extraction solvent in the oxidation/extraction process. For the oxidation/adsorption scheme, the experimental results indicated that the oxidation desulfurization efficiency was enhanced on using activated carbon as catalyst/sorbent. The effects of the operating conditions (contact time, temperature, mixing speed and sorbent dose) on the desulfurization efficiency were examined. The desulfurization efficiency measured at the best operating conditions(optimum conditions): 60 , 500rpm, 60min contact time and sorbent dose of 0.7g AC/100 ml AHD crude, was 32.8% corresponding to a sulfur content of 2.6 wt%. Applying the same optimum operating conditions and at 3:1 solvent/oil ratio, the oxidation/extraction method gave comparable desulfurization efficiency of 31.5%. |
| first_indexed | 2024-03-12T06:38:43Z |
| format | Article |
| id | doaj.art-f723bc2bf3b84b13bb47ecddeedb3ddd |
| institution | Directory Open Access Journal |
| issn | 1726-4073 2520-3339 |
| language | English |
| last_indexed | 2024-03-12T06:38:43Z |
| publishDate | 2015-07-01 |
| publisher | University of Baghdad |
| record_format | Article |
| series | Journal of Engineering |
| spelling | doaj.art-f723bc2bf3b84b13bb47ecddeedb3ddd2023-09-03T01:10:47ZengUniversity of BaghdadJournal of Engineering1726-40732520-33392015-07-01217102112Desulfurization of AL-Ahdab Crude Oil using Oxidative ProcessesNeran Khalel IbrahimSaja Mohsen JabbarTwo different oxidative desulfurization strategies based on oxidation/adsorption or oxidation/extraction were evaluated for the desulfurization of AL-Ahdab (AHD) sour crude oil (3.9wt% sulfur content). In the oxidation process, a homogenous oxidizing agent comprising of hydrogen peroxide and formic acid was used. Activated carbons were used as sorbent/catalyst in the oxidation/adsorption process while acetonitrile was used as an extraction solvent in the oxidation/extraction process. For the oxidation/adsorption scheme, the experimental results indicated that the oxidation desulfurization efficiency was enhanced on using activated carbon as catalyst/sorbent. The effects of the operating conditions (contact time, temperature, mixing speed and sorbent dose) on the desulfurization efficiency were examined. The desulfurization efficiency measured at the best operating conditions(optimum conditions): 60 , 500rpm, 60min contact time and sorbent dose of 0.7g AC/100 ml AHD crude, was 32.8% corresponding to a sulfur content of 2.6 wt%. Applying the same optimum operating conditions and at 3:1 solvent/oil ratio, the oxidation/extraction method gave comparable desulfurization efficiency of 31.5%.https://www.jcoeng.edu.iq/index.php/main/article/view/396/343 |
| spellingShingle | Neran Khalel Ibrahim Saja Mohsen Jabbar Desulfurization of AL-Ahdab Crude Oil using Oxidative Processes Journal of Engineering |
| title | Desulfurization of AL-Ahdab Crude Oil using Oxidative Processes |
| title_full | Desulfurization of AL-Ahdab Crude Oil using Oxidative Processes |
| title_fullStr | Desulfurization of AL-Ahdab Crude Oil using Oxidative Processes |
| title_full_unstemmed | Desulfurization of AL-Ahdab Crude Oil using Oxidative Processes |
| title_short | Desulfurization of AL-Ahdab Crude Oil using Oxidative Processes |
| title_sort | desulfurization of al ahdab crude oil using oxidative processes |
| url | https://www.jcoeng.edu.iq/index.php/main/article/view/396/343 |
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