Advances in Selective Electrochemical Oxidation of 5‐Hydroxymethylfurfural to Produce High‐Value Chemicals
Abstract The conversion of biomass is a favorable alternative to the fossil energy route to solve the energy crisis and environmental pollution. As one of the most versatile platform compounds, 5‐hydroxymethylfural (HMF) can be transformed to various value‐added chemicals via electrolysis combining...
| Main Authors: | , , , , , , , |
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| Format: | Article |
| Language: | English |
| Published: |
Wiley
2023-02-01
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| Series: | Advanced Science |
| Subjects: | |
| Online Access: | https://doi.org/10.1002/advs.202205540 |
| _version_ | 1827820363823710208 |
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| author | Lei Guo Xiaoxue Zhang Li Gan Lun Pan Chengxiang Shi Zhen‐Feng Huang Xiangwen Zhang Ji‐Jun Zou |
| author_facet | Lei Guo Xiaoxue Zhang Li Gan Lun Pan Chengxiang Shi Zhen‐Feng Huang Xiangwen Zhang Ji‐Jun Zou |
| author_sort | Lei Guo |
| collection | DOAJ |
| description | Abstract The conversion of biomass is a favorable alternative to the fossil energy route to solve the energy crisis and environmental pollution. As one of the most versatile platform compounds, 5‐hydroxymethylfural (HMF) can be transformed to various value‐added chemicals via electrolysis combining with renewable energy. Here, the recent advances in electrochemical oxidation of HMF, from reaction mechanism to reactor design are reviewed. First, the reaction mechanism and pathway are summarized systematically. Second, the parameters easy to be ignored are emphasized and discussed. Then, the electrocatalysts are reviewed comprehensively for different products and the reactors are introduced. Finally, future efforts on exploring reaction mechanism, electrocatalysts, and reactor are prospected. This review provides a deeper understanding of mechanism for electrochemical oxidation of HMF, the design of electrocatalyst and reactor, which is expected to promote the economical and efficient electrochemical conversion of biomass for industrial applications. |
| first_indexed | 2024-03-12T01:27:54Z |
| format | Article |
| id | doaj.art-f72ed2c98c65439da8153ea61b57a81d |
| institution | Directory Open Access Journal |
| issn | 2198-3844 |
| language | English |
| last_indexed | 2024-03-12T01:27:54Z |
| publishDate | 2023-02-01 |
| publisher | Wiley |
| record_format | Article |
| series | Advanced Science |
| spelling | doaj.art-f72ed2c98c65439da8153ea61b57a81d2023-09-12T14:40:47ZengWileyAdvanced Science2198-38442023-02-01104n/an/a10.1002/advs.202205540Advances in Selective Electrochemical Oxidation of 5‐Hydroxymethylfurfural to Produce High‐Value ChemicalsLei Guo0Xiaoxue Zhang1Li Gan2Lun Pan3Chengxiang Shi4Zhen‐Feng Huang5Xiangwen Zhang6Ji‐Jun Zou7Key Laboratory for Green Chemical Technology of the Ministry of Education School of Chemical Engineering and Technology Tianjin University Tianjin 300072 ChinaKey Laboratory for Green Chemical Technology of the Ministry of Education School of Chemical Engineering and Technology Tianjin University Tianjin 300072 ChinaKey Laboratory for Green Chemical Technology of the Ministry of Education School of Chemical Engineering and Technology Tianjin University Tianjin 300072 ChinaKey Laboratory for Green Chemical Technology of the Ministry of Education School of Chemical Engineering and Technology Tianjin University Tianjin 300072 ChinaKey Laboratory for Green Chemical Technology of the Ministry of Education School of Chemical Engineering and Technology Tianjin University Tianjin 300072 ChinaKey Laboratory for Green Chemical Technology of the Ministry of Education School of Chemical Engineering and Technology Tianjin University Tianjin 300072 ChinaKey Laboratory for Green Chemical Technology of the Ministry of Education School of Chemical Engineering and Technology Tianjin University Tianjin 300072 ChinaKey Laboratory for Green Chemical Technology of the Ministry of Education School of Chemical Engineering and Technology Tianjin University Tianjin 300072 ChinaAbstract The conversion of biomass is a favorable alternative to the fossil energy route to solve the energy crisis and environmental pollution. As one of the most versatile platform compounds, 5‐hydroxymethylfural (HMF) can be transformed to various value‐added chemicals via electrolysis combining with renewable energy. Here, the recent advances in electrochemical oxidation of HMF, from reaction mechanism to reactor design are reviewed. First, the reaction mechanism and pathway are summarized systematically. Second, the parameters easy to be ignored are emphasized and discussed. Then, the electrocatalysts are reviewed comprehensively for different products and the reactors are introduced. Finally, future efforts on exploring reaction mechanism, electrocatalysts, and reactor are prospected. This review provides a deeper understanding of mechanism for electrochemical oxidation of HMF, the design of electrocatalyst and reactor, which is expected to promote the economical and efficient electrochemical conversion of biomass for industrial applications.https://doi.org/10.1002/advs.202205540biomass upgradingelectrocatalystHMF oxidation electrolysisreaction mechanismreactor |
| spellingShingle | Lei Guo Xiaoxue Zhang Li Gan Lun Pan Chengxiang Shi Zhen‐Feng Huang Xiangwen Zhang Ji‐Jun Zou Advances in Selective Electrochemical Oxidation of 5‐Hydroxymethylfurfural to Produce High‐Value Chemicals Advanced Science biomass upgrading electrocatalyst HMF oxidation electrolysis reaction mechanism reactor |
| title | Advances in Selective Electrochemical Oxidation of 5‐Hydroxymethylfurfural to Produce High‐Value Chemicals |
| title_full | Advances in Selective Electrochemical Oxidation of 5‐Hydroxymethylfurfural to Produce High‐Value Chemicals |
| title_fullStr | Advances in Selective Electrochemical Oxidation of 5‐Hydroxymethylfurfural to Produce High‐Value Chemicals |
| title_full_unstemmed | Advances in Selective Electrochemical Oxidation of 5‐Hydroxymethylfurfural to Produce High‐Value Chemicals |
| title_short | Advances in Selective Electrochemical Oxidation of 5‐Hydroxymethylfurfural to Produce High‐Value Chemicals |
| title_sort | advances in selective electrochemical oxidation of 5 hydroxymethylfurfural to produce high value chemicals |
| topic | biomass upgrading electrocatalyst HMF oxidation electrolysis reaction mechanism reactor |
| url | https://doi.org/10.1002/advs.202205540 |
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