Enhancement of Epoxy Thermosets with Hyperbranched and Multiarm Star Polymers: A Review

Hyperbranched polymers and multiarm star polymers are a type of dendritic polymers which have attracted substantial interest during the last 30 years because of their unique properties. They can be used to modify epoxy thermosets to increase their toughness and flexibility but without adversely affe...

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Main Authors: David Santiago, Àngels Serra
Format: Article
Language:English
Published: MDPI AG 2022-05-01
Series:Polymers
Subjects:
Online Access:https://www.mdpi.com/2073-4360/14/11/2228
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author David Santiago
Àngels Serra
author_facet David Santiago
Àngels Serra
author_sort David Santiago
collection DOAJ
description Hyperbranched polymers and multiarm star polymers are a type of dendritic polymers which have attracted substantial interest during the last 30 years because of their unique properties. They can be used to modify epoxy thermosets to increase their toughness and flexibility but without adversely affecting other properties such as reactivity or thermal properties. In addition, the final properties of materials can be tailored by modifying the structure, molecular weight, or type of functional end-groups of the hyperbranched and multiarm star polymers. In this review, we focus on the modification of epoxy-based thermosets with hyperbranched and multiarm star polymers in terms of the effect on the curing process of epoxy formulations, thermal, mechanical, and rheological properties, and their advantages in fire retardancy on the final thermosets.
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spelling doaj.art-f75f8b74779d4b57abe32b7580a5c2b22023-11-23T14:41:41ZengMDPI AGPolymers2073-43602022-05-011411222810.3390/polym14112228Enhancement of Epoxy Thermosets with Hyperbranched and Multiarm Star Polymers: A ReviewDavid Santiago0Àngels Serra1Eurecat–Chemical Technologies Unit, C/Marcel·lí Domingo 2, 43007 Tarragona, SpainDepartment of Analytical and Organic Chemistry, Universitat Rovira i Virgili, C/Marcel·lí Domingo 1, 43007 Tarragona, SpainHyperbranched polymers and multiarm star polymers are a type of dendritic polymers which have attracted substantial interest during the last 30 years because of their unique properties. They can be used to modify epoxy thermosets to increase their toughness and flexibility but without adversely affecting other properties such as reactivity or thermal properties. In addition, the final properties of materials can be tailored by modifying the structure, molecular weight, or type of functional end-groups of the hyperbranched and multiarm star polymers. In this review, we focus on the modification of epoxy-based thermosets with hyperbranched and multiarm star polymers in terms of the effect on the curing process of epoxy formulations, thermal, mechanical, and rheological properties, and their advantages in fire retardancy on the final thermosets.https://www.mdpi.com/2073-4360/14/11/2228hyperbranched polymersmultiarm star polymersepoxy resinsthermosets
spellingShingle David Santiago
Àngels Serra
Enhancement of Epoxy Thermosets with Hyperbranched and Multiarm Star Polymers: A Review
Polymers
hyperbranched polymers
multiarm star polymers
epoxy resins
thermosets
title Enhancement of Epoxy Thermosets with Hyperbranched and Multiarm Star Polymers: A Review
title_full Enhancement of Epoxy Thermosets with Hyperbranched and Multiarm Star Polymers: A Review
title_fullStr Enhancement of Epoxy Thermosets with Hyperbranched and Multiarm Star Polymers: A Review
title_full_unstemmed Enhancement of Epoxy Thermosets with Hyperbranched and Multiarm Star Polymers: A Review
title_short Enhancement of Epoxy Thermosets with Hyperbranched and Multiarm Star Polymers: A Review
title_sort enhancement of epoxy thermosets with hyperbranched and multiarm star polymers a review
topic hyperbranched polymers
multiarm star polymers
epoxy resins
thermosets
url https://www.mdpi.com/2073-4360/14/11/2228
work_keys_str_mv AT davidsantiago enhancementofepoxythermosetswithhyperbranchedandmultiarmstarpolymersareview
AT angelsserra enhancementofepoxythermosetswithhyperbranchedandmultiarmstarpolymersareview