Continuous negative-to-positive tuning of thermal expansion achieved by controlled gas sorption in porous coordination frameworks
Achieving control over the thermomechanical properties of functional materials is desirable, yet remains highly challenging. Here, the authors demonstrate continuous negative-to-positive tuning of thermal expansion in two Prussian blue analogues, by varying the concentration of adsorbed CO2.
| Main Authors: | , , , , , , |
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| Format: | Article |
| Language: | English |
| Published: |
Nature Portfolio
2018-11-01
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| Series: | Nature Communications |
| Online Access: | https://doi.org/10.1038/s41467-018-06850-6 |
| _version_ | 1818841534915674112 |
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| author | Josie E. Auckett Arnold A. Barkhordarian Stephen H. Ogilvie Samuel G. Duyker Hubert Chevreau Vanessa K. Peterson Cameron J. Kepert |
| author_facet | Josie E. Auckett Arnold A. Barkhordarian Stephen H. Ogilvie Samuel G. Duyker Hubert Chevreau Vanessa K. Peterson Cameron J. Kepert |
| author_sort | Josie E. Auckett |
| collection | DOAJ |
| description | Achieving control over the thermomechanical properties of functional materials is desirable, yet remains highly challenging. Here, the authors demonstrate continuous negative-to-positive tuning of thermal expansion in two Prussian blue analogues, by varying the concentration of adsorbed CO2. |
| first_indexed | 2024-12-19T04:27:37Z |
| format | Article |
| id | doaj.art-f76b06f294574459aa5fe53ad4d4dc8b |
| institution | Directory Open Access Journal |
| issn | 2041-1723 |
| language | English |
| last_indexed | 2024-12-19T04:27:37Z |
| publishDate | 2018-11-01 |
| publisher | Nature Portfolio |
| record_format | Article |
| series | Nature Communications |
| spelling | doaj.art-f76b06f294574459aa5fe53ad4d4dc8b2022-12-21T20:36:00ZengNature PortfolioNature Communications2041-17232018-11-01911510.1038/s41467-018-06850-6Continuous negative-to-positive tuning of thermal expansion achieved by controlled gas sorption in porous coordination frameworksJosie E. Auckett0Arnold A. Barkhordarian1Stephen H. Ogilvie2Samuel G. Duyker3Hubert Chevreau4Vanessa K. Peterson5Cameron J. Kepert6Australian Centre for Neutron Scattering, Australian Nuclear Science and Technology OrganisationSchool of Chemistry, The University of SydneySchool of Chemistry, The University of SydneySchool of Chemistry, The University of SydneyAustralian Centre for Neutron Scattering, Australian Nuclear Science and Technology OrganisationAustralian Centre for Neutron Scattering, Australian Nuclear Science and Technology OrganisationSchool of Chemistry, The University of SydneyAchieving control over the thermomechanical properties of functional materials is desirable, yet remains highly challenging. Here, the authors demonstrate continuous negative-to-positive tuning of thermal expansion in two Prussian blue analogues, by varying the concentration of adsorbed CO2.https://doi.org/10.1038/s41467-018-06850-6 |
| spellingShingle | Josie E. Auckett Arnold A. Barkhordarian Stephen H. Ogilvie Samuel G. Duyker Hubert Chevreau Vanessa K. Peterson Cameron J. Kepert Continuous negative-to-positive tuning of thermal expansion achieved by controlled gas sorption in porous coordination frameworks Nature Communications |
| title | Continuous negative-to-positive tuning of thermal expansion achieved by controlled gas sorption in porous coordination frameworks |
| title_full | Continuous negative-to-positive tuning of thermal expansion achieved by controlled gas sorption in porous coordination frameworks |
| title_fullStr | Continuous negative-to-positive tuning of thermal expansion achieved by controlled gas sorption in porous coordination frameworks |
| title_full_unstemmed | Continuous negative-to-positive tuning of thermal expansion achieved by controlled gas sorption in porous coordination frameworks |
| title_short | Continuous negative-to-positive tuning of thermal expansion achieved by controlled gas sorption in porous coordination frameworks |
| title_sort | continuous negative to positive tuning of thermal expansion achieved by controlled gas sorption in porous coordination frameworks |
| url | https://doi.org/10.1038/s41467-018-06850-6 |
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