A 3-D Metal-Organic Framework Constructed with Manganese(ΙΙ), 4,4'-Oxybis(benzoic acid) and 2,2'-Biphenyl: Synthesis, Crystal Structure and Photoelectric Property Characterization
Assembly of 4,4'-oxybis(benzoic acid) (H2L) with manganese chloride in the presence of 2,2'-biphenyl (2,2'-bpy) affords a new coordination polymer [Mn3L3(2,2'-bpy)2]n (1), in which the [MnL2]n layers are extended by L bridges resulting in a three-dimensional (3-D)...
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| Format: | Article |
| Language: | English |
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MDPI AG
2012-09-01
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| Series: | Molecules |
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| Online Access: | http://www.mdpi.com/1420-3049/17/9/11103 |
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| author | Fu-Hou Lei Kai-Sheng Diao Yu-Qiu Ding Long Li |
| author_facet | Fu-Hou Lei Kai-Sheng Diao Yu-Qiu Ding Long Li |
| author_sort | Fu-Hou Lei |
| collection | DOAJ |
| description | Assembly of 4,4'-oxybis(benzoic acid) (H2L) with manganese chloride in the presence of 2,2'-biphenyl (2,2'-bpy) affords a new coordination polymer [Mn3L3(2,2'-bpy)2]n (1), in which the [MnL2]n layers are extended by L bridges resulting in a three-dimensional (3-D) coordination framework. The network structure of 1 has unusual (2,6)-connectivity and represents a new type of (812·123)(8)(3) topology. These identical and complementary networks are entangled to generate a self-penetrating supramolecular lattice. Moreover, the fluorescence spectrum of 1 exhibits fluorescent emission in the solution of methanol at room temperature. Electrochemical investigation illustrates the electrochemical properties of the title compound. The structure (C62H40Mn3N4O15)n is monoclinic with a = 14.2304(18), b = 17.019(2), c = 25.805(3) Å, α = γ = 90, β = 92.932(2)° and space group C2/c. |
| first_indexed | 2024-12-20T12:04:11Z |
| format | Article |
| id | doaj.art-f76ec6385ce947ca941f0e2bd360f3bf |
| institution | Directory Open Access Journal |
| issn | 1420-3049 |
| language | English |
| last_indexed | 2024-12-20T12:04:11Z |
| publishDate | 2012-09-01 |
| publisher | MDPI AG |
| record_format | Article |
| series | Molecules |
| spelling | doaj.art-f76ec6385ce947ca941f0e2bd360f3bf2022-12-21T19:41:27ZengMDPI AGMolecules1420-30492012-09-01179111031111210.3390/molecules170911103A 3-D Metal-Organic Framework Constructed with Manganese(ΙΙ), 4,4'-Oxybis(benzoic acid) and 2,2'-Biphenyl: Synthesis, Crystal Structure and Photoelectric Property CharacterizationFu-Hou LeiKai-Sheng DiaoYu-Qiu DingLong LiAssembly of 4,4'-oxybis(benzoic acid) (H2L) with manganese chloride in the presence of 2,2'-biphenyl (2,2'-bpy) affords a new coordination polymer [Mn3L3(2,2'-bpy)2]n (1), in which the [MnL2]n layers are extended by L bridges resulting in a three-dimensional (3-D) coordination framework. The network structure of 1 has unusual (2,6)-connectivity and represents a new type of (812·123)(8)(3) topology. These identical and complementary networks are entangled to generate a self-penetrating supramolecular lattice. Moreover, the fluorescence spectrum of 1 exhibits fluorescent emission in the solution of methanol at room temperature. Electrochemical investigation illustrates the electrochemical properties of the title compound. The structure (C62H40Mn3N4O15)n is monoclinic with a = 14.2304(18), b = 17.019(2), c = 25.805(3) Å, α = γ = 90, β = 92.932(2)° and space group C2/c.http://www.mdpi.com/1420-3049/17/9/11103(3-D) coordination framework4,4'-oxybis(benzoic acid)self-penetrating topologyfluorescenceelectrochemical properties |
| spellingShingle | Fu-Hou Lei Kai-Sheng Diao Yu-Qiu Ding Long Li A 3-D Metal-Organic Framework Constructed with Manganese(ΙΙ), 4,4'-Oxybis(benzoic acid) and 2,2'-Biphenyl: Synthesis, Crystal Structure and Photoelectric Property Characterization Molecules (3-D) coordination framework 4,4'-oxybis(benzoic acid) self-penetrating topology fluorescence electrochemical properties |
| title | A 3-D Metal-Organic Framework Constructed with Manganese(ΙΙ), 4,4'-Oxybis(benzoic acid) and 2,2'-Biphenyl: Synthesis, Crystal Structure and Photoelectric Property Characterization |
| title_full | A 3-D Metal-Organic Framework Constructed with Manganese(ΙΙ), 4,4'-Oxybis(benzoic acid) and 2,2'-Biphenyl: Synthesis, Crystal Structure and Photoelectric Property Characterization |
| title_fullStr | A 3-D Metal-Organic Framework Constructed with Manganese(ΙΙ), 4,4'-Oxybis(benzoic acid) and 2,2'-Biphenyl: Synthesis, Crystal Structure and Photoelectric Property Characterization |
| title_full_unstemmed | A 3-D Metal-Organic Framework Constructed with Manganese(ΙΙ), 4,4'-Oxybis(benzoic acid) and 2,2'-Biphenyl: Synthesis, Crystal Structure and Photoelectric Property Characterization |
| title_short | A 3-D Metal-Organic Framework Constructed with Manganese(ΙΙ), 4,4'-Oxybis(benzoic acid) and 2,2'-Biphenyl: Synthesis, Crystal Structure and Photoelectric Property Characterization |
| title_sort | 3 d metal organic framework constructed with manganese ιι 4 4 039 oxybis benzoic acid and 2 2 039 biphenyl synthesis crystal structure and photoelectric property characterization |
| topic | (3-D) coordination framework 4,4'-oxybis(benzoic acid) self-penetrating topology fluorescence electrochemical properties |
| url | http://www.mdpi.com/1420-3049/17/9/11103 |
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