Preparation of layered gradient Cu–Cr–Ti alloy with excellent mechanical properties, thermal stability, and electrical conductivity

Cu–Cr–Ti alloy with gradient properties was prepared at 960°C for 2 h in air, 80% cold rolling, and then aging at 500°C for 1 h. The results showed that the surface layer of Cu–Cr–Ti alloy had achieved a good match of electrical conductivity (96.2% International Annealed Copper Standard (IACS)), the...

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Main Authors: Fu Shaoli, Chen Xiaohong, Liu Ping, Zhou Honglei, Ma Fengcang, Li Wei
Format: Article
Language:English
Published: De Gruyter 2022-12-01
Series:Nanotechnology Reviews
Subjects:
Online Access:https://doi.org/10.1515/ntrev-2022-0500
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author Fu Shaoli
Chen Xiaohong
Liu Ping
Zhou Honglei
Ma Fengcang
Li Wei
author_facet Fu Shaoli
Chen Xiaohong
Liu Ping
Zhou Honglei
Ma Fengcang
Li Wei
author_sort Fu Shaoli
collection DOAJ
description Cu–Cr–Ti alloy with gradient properties was prepared at 960°C for 2 h in air, 80% cold rolling, and then aging at 500°C for 1 h. The results showed that the surface layer of Cu–Cr–Ti alloy had achieved a good match of electrical conductivity (96.2% International Annealed Copper Standard (IACS)), thermal stability (softening temperature of 650°C), and wear resistance (friction coefficient of 0.17). Meanwhile, the core region maintains high tensile strength (519 MPa) and good electrical conductivity of 71.8% IACS. Transmission electron microscope characterization revealed that the precipitates of surface layer are composed of Cr oxides, complex oxides formed by Cu, Cr, and O, and Ti-rich phases. The existence of oxide particles with discontinuous distribution and stable properties is the reason for the good electrical conductivity, excellent thermal stability, and outstanding wear resistance of the surface layer. The main precipitates of the core are Cr. The high tensile strength of the core is ascribed to the aging strengthening effect of these fine Cr particles. This work provides ideas and approaches for the preparation of copper alloy with excellent properties for high-speed railway contact wire, and solves the drawbacks of composites synthesized from heterogeneous materials.
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spelling doaj.art-f780eeb87ed547d68e13c92cb03f087a2023-01-19T13:47:24ZengDe GruyterNanotechnology Reviews2191-90972022-12-011113207321710.1515/ntrev-2022-0500Preparation of layered gradient Cu–Cr–Ti alloy with excellent mechanical properties, thermal stability, and electrical conductivityFu Shaoli0Chen Xiaohong1Liu Ping2Zhou Honglei3Ma Fengcang4Li Wei5School of Materials and Chemistry, University of Shanghai for Science and Technology, Shanghai 200093, ChinaSchool of Materials and Chemistry, University of Shanghai for Science and Technology, Shanghai 200093, ChinaSchool of Materials and Chemistry, University of Shanghai for Science and Technology, Shanghai 200093, ChinaSchool of Materials and Chemistry, University of Shanghai for Science and Technology, Shanghai 200093, ChinaSchool of Materials and Chemistry, University of Shanghai for Science and Technology, Shanghai 200093, ChinaSchool of Materials and Chemistry, University of Shanghai for Science and Technology, Shanghai 200093, ChinaCu–Cr–Ti alloy with gradient properties was prepared at 960°C for 2 h in air, 80% cold rolling, and then aging at 500°C for 1 h. The results showed that the surface layer of Cu–Cr–Ti alloy had achieved a good match of electrical conductivity (96.2% International Annealed Copper Standard (IACS)), thermal stability (softening temperature of 650°C), and wear resistance (friction coefficient of 0.17). Meanwhile, the core region maintains high tensile strength (519 MPa) and good electrical conductivity of 71.8% IACS. Transmission electron microscope characterization revealed that the precipitates of surface layer are composed of Cr oxides, complex oxides formed by Cu, Cr, and O, and Ti-rich phases. The existence of oxide particles with discontinuous distribution and stable properties is the reason for the good electrical conductivity, excellent thermal stability, and outstanding wear resistance of the surface layer. The main precipitates of the core are Cr. The high tensile strength of the core is ascribed to the aging strengthening effect of these fine Cr particles. This work provides ideas and approaches for the preparation of copper alloy with excellent properties for high-speed railway contact wire, and solves the drawbacks of composites synthesized from heterogeneous materials.https://doi.org/10.1515/ntrev-2022-0500cu–cr–ti alloygradient propertiesinternal oxidationoxidesfine cr precipitates
spellingShingle Fu Shaoli
Chen Xiaohong
Liu Ping
Zhou Honglei
Ma Fengcang
Li Wei
Preparation of layered gradient Cu–Cr–Ti alloy with excellent mechanical properties, thermal stability, and electrical conductivity
Nanotechnology Reviews
cu–cr–ti alloy
gradient properties
internal oxidation
oxides
fine cr precipitates
title Preparation of layered gradient Cu–Cr–Ti alloy with excellent mechanical properties, thermal stability, and electrical conductivity
title_full Preparation of layered gradient Cu–Cr–Ti alloy with excellent mechanical properties, thermal stability, and electrical conductivity
title_fullStr Preparation of layered gradient Cu–Cr–Ti alloy with excellent mechanical properties, thermal stability, and electrical conductivity
title_full_unstemmed Preparation of layered gradient Cu–Cr–Ti alloy with excellent mechanical properties, thermal stability, and electrical conductivity
title_short Preparation of layered gradient Cu–Cr–Ti alloy with excellent mechanical properties, thermal stability, and electrical conductivity
title_sort preparation of layered gradient cu cr ti alloy with excellent mechanical properties thermal stability and electrical conductivity
topic cu–cr–ti alloy
gradient properties
internal oxidation
oxides
fine cr precipitates
url https://doi.org/10.1515/ntrev-2022-0500
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