Trends and drivers of CO2 parameters, from 2006 to 2021, at a time-series station in the Eastern Tropical Atlantic (6°S, 10°W)

The seawater fugacity of CO2 (fCO2) has been monitored hourly at an instrumented mooring at 6°S, 10°W since 2006. The mooring is located in the South Equatorial Current and is affected by the equatorial Atlantic cold tongue. This site is characterized by large seasonal sea surface temperature variat...

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Main Authors: Nathalie Lefèvre, Doris Veleda, Laurence Beaumont
Format: Article
Language:English
Published: Frontiers Media S.A. 2024-02-01
Series:Frontiers in Marine Science
Subjects:
Online Access:https://www.frontiersin.org/articles/10.3389/fmars.2024.1299071/full
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author Nathalie Lefèvre
Doris Veleda
Laurence Beaumont
author_facet Nathalie Lefèvre
Doris Veleda
Laurence Beaumont
author_sort Nathalie Lefèvre
collection DOAJ
description The seawater fugacity of CO2 (fCO2) has been monitored hourly at an instrumented mooring at 6°S, 10°W since 2006. The mooring is located in the South Equatorial Current and is affected by the equatorial Atlantic cold tongue. This site is characterized by large seasonal sea surface temperature variations (>4°C). The fCO2 is measured by a spectrophotometric sensor deployed at about 1.5 meters deep. Measurements of seawater fCO2, sea surface temperature (SST) and sea surface salinity (SSS) are used to calculate total dissolved inorganic carbon (TCO2) and pH. Total alkalinity (TA) is calculated using an empirical relationship with SSS determined for this region. Satellite chlorophyll-a concentrations at 6°S, 10°W are low (<0.2 mg m-3) but some peaks over 0.8 mg m-3 are sometimes detected in August. Nevertheless, the site is a permanent source of CO2 to the atmosphere, averaging 4.7 ± 2.4 mmol m-2d-1 over 2006-2021. Despite the weakening of the wind, the CO2 flux increases significantly by 0.20 ± 0.05 mmol m-2d-1 yr-1. This suggests that the source of CO2 is increasing in this region. This is explained by seawater fCO2 increasing faster than the atmospheric increase during 2006-2021. Most of the seawater fCO2 increase is driven by the increase of TCO2, followed by SST. The fCO2 increase leads to a pH decrease of -0.0030 ± 0.0004 yr-1. The SST anomalies (SSTA) at 6°S, 10°W are correlated to the Tropical Southern Atlantic (TSA) index and to the Atlantic 3 region (ATL3) index with a correlation coefficient higher than 0.75. The strong positive phase of both ATL3 and TSA, observed towards the end of the time-series, is likely contributing to the strong increase of seawater fCO2.
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spelling doaj.art-f784bb2da27b4e2d917e6e9c64db15de2024-02-19T04:45:23ZengFrontiers Media S.A.Frontiers in Marine Science2296-77452024-02-011110.3389/fmars.2024.12990711299071Trends and drivers of CO2 parameters, from 2006 to 2021, at a time-series station in the Eastern Tropical Atlantic (6°S, 10°W)Nathalie Lefèvre0Doris Veleda1Laurence Beaumont2Laboratoire d'Océanographie et du Climat: Expérimentations et Approches Numériques/Institut Pierre Simon Laplace (LOCEAN/IPSL), Institut de Recherche pour le Développement (IRD), Sorbonne Université, Centre National de la Recherche Scientifique-Muséum National d'Histoire Naturelle (CNRS-MNHN), Paris, FranceLaboratório de Oceanografia Física Estuarina e Costeira (LOFEC), Federal University of Pernambuco, Department of Oceanography, Recife, BrazilDivision Technique, Institut National des Sciences de l'Univers (INSU), Gif sur Yvette, FranceThe seawater fugacity of CO2 (fCO2) has been monitored hourly at an instrumented mooring at 6°S, 10°W since 2006. The mooring is located in the South Equatorial Current and is affected by the equatorial Atlantic cold tongue. This site is characterized by large seasonal sea surface temperature variations (>4°C). The fCO2 is measured by a spectrophotometric sensor deployed at about 1.5 meters deep. Measurements of seawater fCO2, sea surface temperature (SST) and sea surface salinity (SSS) are used to calculate total dissolved inorganic carbon (TCO2) and pH. Total alkalinity (TA) is calculated using an empirical relationship with SSS determined for this region. Satellite chlorophyll-a concentrations at 6°S, 10°W are low (<0.2 mg m-3) but some peaks over 0.8 mg m-3 are sometimes detected in August. Nevertheless, the site is a permanent source of CO2 to the atmosphere, averaging 4.7 ± 2.4 mmol m-2d-1 over 2006-2021. Despite the weakening of the wind, the CO2 flux increases significantly by 0.20 ± 0.05 mmol m-2d-1 yr-1. This suggests that the source of CO2 is increasing in this region. This is explained by seawater fCO2 increasing faster than the atmospheric increase during 2006-2021. Most of the seawater fCO2 increase is driven by the increase of TCO2, followed by SST. The fCO2 increase leads to a pH decrease of -0.0030 ± 0.0004 yr-1. The SST anomalies (SSTA) at 6°S, 10°W are correlated to the Tropical Southern Atlantic (TSA) index and to the Atlantic 3 region (ATL3) index with a correlation coefficient higher than 0.75. The strong positive phase of both ATL3 and TSA, observed towards the end of the time-series, is likely contributing to the strong increase of seawater fCO2.https://www.frontiersin.org/articles/10.3389/fmars.2024.1299071/fullacidificationfugacity of CO2carbon cycletropical Southern Atlantic indexPIRATA mooring
spellingShingle Nathalie Lefèvre
Doris Veleda
Laurence Beaumont
Trends and drivers of CO2 parameters, from 2006 to 2021, at a time-series station in the Eastern Tropical Atlantic (6°S, 10°W)
Frontiers in Marine Science
acidification
fugacity of CO2
carbon cycle
tropical Southern Atlantic index
PIRATA mooring
title Trends and drivers of CO2 parameters, from 2006 to 2021, at a time-series station in the Eastern Tropical Atlantic (6°S, 10°W)
title_full Trends and drivers of CO2 parameters, from 2006 to 2021, at a time-series station in the Eastern Tropical Atlantic (6°S, 10°W)
title_fullStr Trends and drivers of CO2 parameters, from 2006 to 2021, at a time-series station in the Eastern Tropical Atlantic (6°S, 10°W)
title_full_unstemmed Trends and drivers of CO2 parameters, from 2006 to 2021, at a time-series station in the Eastern Tropical Atlantic (6°S, 10°W)
title_short Trends and drivers of CO2 parameters, from 2006 to 2021, at a time-series station in the Eastern Tropical Atlantic (6°S, 10°W)
title_sort trends and drivers of co2 parameters from 2006 to 2021 at a time series station in the eastern tropical atlantic 6°s 10°w
topic acidification
fugacity of CO2
carbon cycle
tropical Southern Atlantic index
PIRATA mooring
url https://www.frontiersin.org/articles/10.3389/fmars.2024.1299071/full
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AT dorisveleda trendsanddriversofco2parametersfrom2006to2021atatimeseriesstationintheeasterntropicalatlantic6s10w
AT laurencebeaumont trendsanddriversofco2parametersfrom2006to2021atatimeseriesstationintheeasterntropicalatlantic6s10w