Advanced Coatings of Polyureas for Building Blast Protection: Physical, Chemical, Thermal and Mechanical Characterization

Due to the increase in the global terrorist threat, there has been a growing demand for materials that can more efficiently protect civil, industrial, and military structures against explosions. In this sense, two new commercial polyureas (A and B), that present high potential to be used as a protec...

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Main Authors: Fernando Leite, Carlos Mota, João Bessa, Fernando Cunha, Raul Fangueiro, Gabriel Gomes, José Mingote
Format: Article
Language:English
Published: MDPI AG 2022-10-01
Series:Applied Sciences
Subjects:
Online Access:https://www.mdpi.com/2076-3417/12/21/10879
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author Fernando Leite
Carlos Mota
João Bessa
Fernando Cunha
Raul Fangueiro
Gabriel Gomes
José Mingote
author_facet Fernando Leite
Carlos Mota
João Bessa
Fernando Cunha
Raul Fangueiro
Gabriel Gomes
José Mingote
author_sort Fernando Leite
collection DOAJ
description Due to the increase in the global terrorist threat, there has been a growing demand for materials that can more efficiently protect civil, industrial, and military structures against explosions. In this sense, two new commercial polyureas (A and B), that present high potential to be used as a protective coating on building facades against explosions, were compared in this work, through several tests. Chemical characterization with the Scanning Electron Microscope (SEM) of the surface of the polyureas revealed that the commercial polyurea A has a heterogeneous surface while the other polyurea has a more uniform and homogeneous surface, resulting in a more compact structure. The shock-wave attenuation ability of polyurea is believed to be controlled primarily by the hard domains. The TGA tests revealed that polyurea B has more hard segments than polyurea A in its composition. The mechanical tests performed showed that polyurea B has significantly better tensile properties-almost 3000% of maximum deformation capacity compared with approximately 115% of polyurea A. Thus, it was concluded that polyurea B has more potential to be used as a coating in building blast protection due to its exceptional elongation characteristics, a critical parameter to absorb the high frequency and intensity of blasts.
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spelling doaj.art-f78657df4c9049bcbfe686bd9a61a6bd2023-11-24T03:34:21ZengMDPI AGApplied Sciences2076-34172022-10-0112211087910.3390/app122110879Advanced Coatings of Polyureas for Building Blast Protection: Physical, Chemical, Thermal and Mechanical CharacterizationFernando Leite0Carlos Mota1João Bessa2Fernando Cunha3Raul Fangueiro4Gabriel Gomes5José Mingote6Centre for Textile Science and Technology, School of Engineering, University of Minho—Campus of Azurém, 4800-058 Guimarães, PortugalCentre for Textile Science and Technology, School of Engineering, University of Minho—Campus of Azurém, 4800-058 Guimarães, PortugalCentre for Textile Science and Technology, School of Engineering, University of Minho—Campus of Azurém, 4800-058 Guimarães, PortugalCentre for Textile Science and Technology, School of Engineering, University of Minho—Campus of Azurém, 4800-058 Guimarães, PortugalCentre for Textile Science and Technology, School of Engineering, University of Minho—Campus of Azurém, 4800-058 Guimarães, PortugalMilitary Academy Research Center (CINAMIL), Instituto Universitário Militar, Rua Gomes Freire, 1169-203 Lisbon, PortugalNATO Counter Improvised Explosive Devices Centre of Excellence (C-IED COE), Hoyo de Manzanares, 28240 Madrid, SpainDue to the increase in the global terrorist threat, there has been a growing demand for materials that can more efficiently protect civil, industrial, and military structures against explosions. In this sense, two new commercial polyureas (A and B), that present high potential to be used as a protective coating on building facades against explosions, were compared in this work, through several tests. Chemical characterization with the Scanning Electron Microscope (SEM) of the surface of the polyureas revealed that the commercial polyurea A has a heterogeneous surface while the other polyurea has a more uniform and homogeneous surface, resulting in a more compact structure. The shock-wave attenuation ability of polyurea is believed to be controlled primarily by the hard domains. The TGA tests revealed that polyurea B has more hard segments than polyurea A in its composition. The mechanical tests performed showed that polyurea B has significantly better tensile properties-almost 3000% of maximum deformation capacity compared with approximately 115% of polyurea A. Thus, it was concluded that polyurea B has more potential to be used as a coating in building blast protection due to its exceptional elongation characteristics, a critical parameter to absorb the high frequency and intensity of blasts.https://www.mdpi.com/2076-3417/12/21/10879polyureablast protectionelongationcoating
spellingShingle Fernando Leite
Carlos Mota
João Bessa
Fernando Cunha
Raul Fangueiro
Gabriel Gomes
José Mingote
Advanced Coatings of Polyureas for Building Blast Protection: Physical, Chemical, Thermal and Mechanical Characterization
Applied Sciences
polyurea
blast protection
elongation
coating
title Advanced Coatings of Polyureas for Building Blast Protection: Physical, Chemical, Thermal and Mechanical Characterization
title_full Advanced Coatings of Polyureas for Building Blast Protection: Physical, Chemical, Thermal and Mechanical Characterization
title_fullStr Advanced Coatings of Polyureas for Building Blast Protection: Physical, Chemical, Thermal and Mechanical Characterization
title_full_unstemmed Advanced Coatings of Polyureas for Building Blast Protection: Physical, Chemical, Thermal and Mechanical Characterization
title_short Advanced Coatings of Polyureas for Building Blast Protection: Physical, Chemical, Thermal and Mechanical Characterization
title_sort advanced coatings of polyureas for building blast protection physical chemical thermal and mechanical characterization
topic polyurea
blast protection
elongation
coating
url https://www.mdpi.com/2076-3417/12/21/10879
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