Recent Progress in Research on [2.2]Paracyclophane-Based Dyes
In recent years, the [2.2]paracyclophane (PCP) ring has attracted extensive attention due to its features of providing not only chirality and electron-donating ability but also steric hindrance, which reduces intermolecular π–π stacking interactions and thereby improves the fluorescence properties o...
| Main Authors: | , , , , |
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| Format: | Article |
| Language: | English |
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MDPI AG
2023-03-01
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| Series: | Molecules |
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| Online Access: | https://www.mdpi.com/1420-3049/28/7/2891 |
| _version_ | 1797607460317429760 |
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| author | Wenjing Liu Huabin Li Yanmin Huo Qingxia Yao Wenzeng Duan |
| author_facet | Wenjing Liu Huabin Li Yanmin Huo Qingxia Yao Wenzeng Duan |
| author_sort | Wenjing Liu |
| collection | DOAJ |
| description | In recent years, the [2.2]paracyclophane (PCP) ring has attracted extensive attention due to its features of providing not only chirality and electron-donating ability but also steric hindrance, which reduces intermolecular π–π stacking interactions and thereby improves the fluorescence properties of dyes. To date, some circularly polarized luminescence (CPL)-active small organic molecules based on the PCP skeleton have been reviewed; however, the application of the PCP ring in improving the photophysical properties of fluorescent dyes is still limited, and new molecular design strategies are still required. This review summarizes and promotes the application of PCP in fluorescent dye design, fluorescence detection, and CPL modulation. We expect that this review will provide readers with a comprehensive understanding of the PCP skeleton and lead to further improvement in fluorescent dye design. |
| first_indexed | 2024-03-11T05:31:18Z |
| format | Article |
| id | doaj.art-f7a93b5c39f545beb5502139a793ad46 |
| institution | Directory Open Access Journal |
| issn | 1420-3049 |
| language | English |
| last_indexed | 2024-03-11T05:31:18Z |
| publishDate | 2023-03-01 |
| publisher | MDPI AG |
| record_format | Article |
| series | Molecules |
| spelling | doaj.art-f7a93b5c39f545beb5502139a793ad462023-11-17T17:10:28ZengMDPI AGMolecules1420-30492023-03-01287289110.3390/molecules28072891Recent Progress in Research on [2.2]Paracyclophane-Based DyesWenjing Liu0Huabin Li1Yanmin Huo2Qingxia Yao3Wenzeng Duan4School of Chemistry and Chemical Engineering, Shandong Provincial Key Laboratory of Chemical Energy Storage and Novel Cell Technology, Liaocheng University, Liaocheng 252000, ChinaSchool of Chemistry and Chemical Engineering, Shandong Provincial Key Laboratory of Chemical Energy Storage and Novel Cell Technology, Liaocheng University, Liaocheng 252000, ChinaSchool of Chemistry and Chemical Engineering, Shandong Provincial Key Laboratory of Chemical Energy Storage and Novel Cell Technology, Liaocheng University, Liaocheng 252000, ChinaSchool of Chemistry and Chemical Engineering, Shandong Provincial Key Laboratory of Chemical Energy Storage and Novel Cell Technology, Liaocheng University, Liaocheng 252000, ChinaSchool of Chemistry and Chemical Engineering, Shandong Provincial Key Laboratory of Chemical Energy Storage and Novel Cell Technology, Liaocheng University, Liaocheng 252000, ChinaIn recent years, the [2.2]paracyclophane (PCP) ring has attracted extensive attention due to its features of providing not only chirality and electron-donating ability but also steric hindrance, which reduces intermolecular π–π stacking interactions and thereby improves the fluorescence properties of dyes. To date, some circularly polarized luminescence (CPL)-active small organic molecules based on the PCP skeleton have been reviewed; however, the application of the PCP ring in improving the photophysical properties of fluorescent dyes is still limited, and new molecular design strategies are still required. This review summarizes and promotes the application of PCP in fluorescent dye design, fluorescence detection, and CPL modulation. We expect that this review will provide readers with a comprehensive understanding of the PCP skeleton and lead to further improvement in fluorescent dye design.https://www.mdpi.com/1420-3049/28/7/2891[2.2]paracyclophanefluorescent dyefluorescent probeAICPL |
| spellingShingle | Wenjing Liu Huabin Li Yanmin Huo Qingxia Yao Wenzeng Duan Recent Progress in Research on [2.2]Paracyclophane-Based Dyes Molecules [2.2]paracyclophane fluorescent dye fluorescent probe AICPL |
| title | Recent Progress in Research on [2.2]Paracyclophane-Based Dyes |
| title_full | Recent Progress in Research on [2.2]Paracyclophane-Based Dyes |
| title_fullStr | Recent Progress in Research on [2.2]Paracyclophane-Based Dyes |
| title_full_unstemmed | Recent Progress in Research on [2.2]Paracyclophane-Based Dyes |
| title_short | Recent Progress in Research on [2.2]Paracyclophane-Based Dyes |
| title_sort | recent progress in research on 2 2 paracyclophane based dyes |
| topic | [2.2]paracyclophane fluorescent dye fluorescent probe AICPL |
| url | https://www.mdpi.com/1420-3049/28/7/2891 |
| work_keys_str_mv | AT wenjingliu recentprogressinresearchon22paracyclophanebaseddyes AT huabinli recentprogressinresearchon22paracyclophanebaseddyes AT yanminhuo recentprogressinresearchon22paracyclophanebaseddyes AT qingxiayao recentprogressinresearchon22paracyclophanebaseddyes AT wenzengduan recentprogressinresearchon22paracyclophanebaseddyes |