A Bio-Refinery Concept for N and P Recovery—A Chance for Biogas Plant Development

Biogas is an alternative source of energy for fossil fuels. In the process of transforming organic materials into biogas significant amounts of valuable digestate are produced. In order to make the whole process sustainable digestate should be utilized this is a constraining factor in the developmen...

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Main Authors: Magdalena Szymańska, Ewa Szara, Tomasz Sosulski, Adam Wąs, Gijs W. P. van Pruissen, René L. Cornelissen, Mieczysław Borowik
Format: Article
Language:English
Published: MDPI AG 2019-01-01
Series:Energies
Subjects:
Online Access:http://www.mdpi.com/1996-1073/12/1/155
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author Magdalena Szymańska
Ewa Szara
Tomasz Sosulski
Adam Wąs
Gijs W. P. van Pruissen
René L. Cornelissen
Mieczysław Borowik
author_facet Magdalena Szymańska
Ewa Szara
Tomasz Sosulski
Adam Wąs
Gijs W. P. van Pruissen
René L. Cornelissen
Mieczysław Borowik
author_sort Magdalena Szymańska
collection DOAJ
description Biogas is an alternative source of energy for fossil fuels. In the process of transforming organic materials into biogas significant amounts of valuable digestate are produced. In order to make the whole process sustainable digestate should be utilized this is a constraining factor in the development of the biogas industry. Consequently, there is an on-going search for new technologies to process digestate, allowing to broaden the range of possible ways of digestate utilization. One of such possibilities is technology of nitrogen (N) and phosphorus (P) recovery from the anaerobic digestate. In this study results of physicochemical analysis of materials flowing through the farm-scale bio-refinery producing struvite (STR) and ammonium sulphate (AS) are presented. Struvite was precipitated from the liquid fraction of digestate (LFDS). Ammonia was bound by sulphuric acid resulting in obtaining ammonium sulphate. The STR obtained was of medium purity and contained other macronutrients and micronutrients that further enhanced its agronomic value. The P recovery effectiveness, counted as the difference between the Ptot content in the material before and after STR precipitation was 43.8%. The AS was characterized by relatively low Ntot and Stot content. The Ntot recovery efficiency reached 43.2%. The study showed that struvite precipitation and ammonia stripping technologies can be used for processing digestate however, the processes efficiency should be improved.
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spelling doaj.art-f7ad2fbfe7b94e67be00ce2b971af8322022-12-22T01:56:21ZengMDPI AGEnergies1996-10732019-01-0112115510.3390/en12010155en12010155A Bio-Refinery Concept for N and P Recovery—A Chance for Biogas Plant DevelopmentMagdalena Szymańska0Ewa Szara1Tomasz Sosulski2Adam Wąs3Gijs W. P. van Pruissen4René L. Cornelissen5Mieczysław BorowikDepartment of Soil Environment Sciences, Warsaw University of Life Sciences–SGGW, Nowoursynowska 159, 02–776 Warsaw, PolandDepartment of Soil Environment Sciences, Warsaw University of Life Sciences–SGGW, Nowoursynowska 159, 02–776 Warsaw, PolandDepartment of Soil Environment Sciences, Warsaw University of Life Sciences–SGGW, Nowoursynowska 159, 02–776 Warsaw, PolandDepartment of Economics and Organisation of Enterprises, Warsaw University of Life Sciences – SGGW, Nowoursynowska 166, 02–787 Warsaw, PolandCornelissen Consulting Services BV, Binnensingel 3, 7411 PL Deventer, The NetherlandsCornelissen Consulting Services BV, Binnensingel 3, 7411 PL Deventer, The NetherlandsBiogas is an alternative source of energy for fossil fuels. In the process of transforming organic materials into biogas significant amounts of valuable digestate are produced. In order to make the whole process sustainable digestate should be utilized this is a constraining factor in the development of the biogas industry. Consequently, there is an on-going search for new technologies to process digestate, allowing to broaden the range of possible ways of digestate utilization. One of such possibilities is technology of nitrogen (N) and phosphorus (P) recovery from the anaerobic digestate. In this study results of physicochemical analysis of materials flowing through the farm-scale bio-refinery producing struvite (STR) and ammonium sulphate (AS) are presented. Struvite was precipitated from the liquid fraction of digestate (LFDS). Ammonia was bound by sulphuric acid resulting in obtaining ammonium sulphate. The STR obtained was of medium purity and contained other macronutrients and micronutrients that further enhanced its agronomic value. The P recovery effectiveness, counted as the difference between the Ptot content in the material before and after STR precipitation was 43.8%. The AS was characterized by relatively low Ntot and Stot content. The Ntot recovery efficiency reached 43.2%. The study showed that struvite precipitation and ammonia stripping technologies can be used for processing digestate however, the processes efficiency should be improved.http://www.mdpi.com/1996-1073/12/1/155biogas plantstruvite precipitationammonia strippingcircular bioeconomydigestate treatment
spellingShingle Magdalena Szymańska
Ewa Szara
Tomasz Sosulski
Adam Wąs
Gijs W. P. van Pruissen
René L. Cornelissen
Mieczysław Borowik
A Bio-Refinery Concept for N and P Recovery—A Chance for Biogas Plant Development
Energies
biogas plant
struvite precipitation
ammonia stripping
circular bioeconomy
digestate treatment
title A Bio-Refinery Concept for N and P Recovery—A Chance for Biogas Plant Development
title_full A Bio-Refinery Concept for N and P Recovery—A Chance for Biogas Plant Development
title_fullStr A Bio-Refinery Concept for N and P Recovery—A Chance for Biogas Plant Development
title_full_unstemmed A Bio-Refinery Concept for N and P Recovery—A Chance for Biogas Plant Development
title_short A Bio-Refinery Concept for N and P Recovery—A Chance for Biogas Plant Development
title_sort bio refinery concept for n and p recovery a chance for biogas plant development
topic biogas plant
struvite precipitation
ammonia stripping
circular bioeconomy
digestate treatment
url http://www.mdpi.com/1996-1073/12/1/155
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