Synthesis of a novel porous Ag2O nanomaterial on ion exchange resin and its application for COD determination of high salinity water

Abstract This study reports for the first time on the synthesis of novel resin@P-Ag2O material and its application for reducing the chloride effect on COD determination of high salinity water. This engineered core–shell nanomaterial with cationic ion exchange resin core and porous Ag2O shell was pre...

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Main Authors: Trung Thanh Nguyen, Quynh Anh Nguyen Thi, Ngoc Hang Le, Nhat Huy Nguyen
Format: Article
Language:English
Published: Nature Portfolio 2021-06-01
Series:Scientific Reports
Online Access:https://doi.org/10.1038/s41598-021-91004-w
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author Trung Thanh Nguyen
Quynh Anh Nguyen Thi
Ngoc Hang Le
Nhat Huy Nguyen
author_facet Trung Thanh Nguyen
Quynh Anh Nguyen Thi
Ngoc Hang Le
Nhat Huy Nguyen
author_sort Trung Thanh Nguyen
collection DOAJ
description Abstract This study reports for the first time on the synthesis of novel resin@P-Ag2O material and its application for reducing the chloride effect on COD determination of high salinity water. This engineered core–shell nanomaterial with cationic ion exchange resin core and porous Ag2O shell was prepared by facile ion exchange and silver oxidation method at ambient temperature without using toxic chemicals. The material was characterized by FTIR, XRD, SEM, and SEM–EDX mapping. In the chloride removal test, this material gave a high adsorption capacity of ca. 244 mgCl/gAg at the mild condition with high durability after several adsorption–desorption cycles. Moreover, resin@P-Ag2O was applied for removing chloride in water to improve the accuracy of the SMEWW 5220C:2012 method for COD determination of high salinity water. The result showed that the COD of a water sample with salt content after being treated by the material had a low error (≤ 10%) as compared to the sample without salt. Meanwhile, the COD of salty water measured by the dilution method had an error of around 15%. These results indicate that resin@P-Ag2O material has a very potential application for chloride removal and COD determination of high salinity water.
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spelling doaj.art-f7b44beb2fa540428427e152758c5a282022-12-21T21:46:36ZengNature PortfolioScientific Reports2045-23222021-06-011111910.1038/s41598-021-91004-wSynthesis of a novel porous Ag2O nanomaterial on ion exchange resin and its application for COD determination of high salinity waterTrung Thanh Nguyen0Quynh Anh Nguyen Thi1Ngoc Hang Le2Nhat Huy Nguyen3Laboratory of Nanomaterial, An Giang UniversityLaboratory of Nanomaterial, An Giang UniversityLaboratory of Nanomaterial, An Giang UniversityVietnam National University Ho Chi Minh CityAbstract This study reports for the first time on the synthesis of novel resin@P-Ag2O material and its application for reducing the chloride effect on COD determination of high salinity water. This engineered core–shell nanomaterial with cationic ion exchange resin core and porous Ag2O shell was prepared by facile ion exchange and silver oxidation method at ambient temperature without using toxic chemicals. The material was characterized by FTIR, XRD, SEM, and SEM–EDX mapping. In the chloride removal test, this material gave a high adsorption capacity of ca. 244 mgCl/gAg at the mild condition with high durability after several adsorption–desorption cycles. Moreover, resin@P-Ag2O was applied for removing chloride in water to improve the accuracy of the SMEWW 5220C:2012 method for COD determination of high salinity water. The result showed that the COD of a water sample with salt content after being treated by the material had a low error (≤ 10%) as compared to the sample without salt. Meanwhile, the COD of salty water measured by the dilution method had an error of around 15%. These results indicate that resin@P-Ag2O material has a very potential application for chloride removal and COD determination of high salinity water.https://doi.org/10.1038/s41598-021-91004-w
spellingShingle Trung Thanh Nguyen
Quynh Anh Nguyen Thi
Ngoc Hang Le
Nhat Huy Nguyen
Synthesis of a novel porous Ag2O nanomaterial on ion exchange resin and its application for COD determination of high salinity water
Scientific Reports
title Synthesis of a novel porous Ag2O nanomaterial on ion exchange resin and its application for COD determination of high salinity water
title_full Synthesis of a novel porous Ag2O nanomaterial on ion exchange resin and its application for COD determination of high salinity water
title_fullStr Synthesis of a novel porous Ag2O nanomaterial on ion exchange resin and its application for COD determination of high salinity water
title_full_unstemmed Synthesis of a novel porous Ag2O nanomaterial on ion exchange resin and its application for COD determination of high salinity water
title_short Synthesis of a novel porous Ag2O nanomaterial on ion exchange resin and its application for COD determination of high salinity water
title_sort synthesis of a novel porous ag2o nanomaterial on ion exchange resin and its application for cod determination of high salinity water
url https://doi.org/10.1038/s41598-021-91004-w
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