Tl4GdTe3 and Tl4DyTe3 – novel structural Tl5Te3 analogues

The novel ternary compounds Tl4GdTe3 and Tl4DyTe3 ­- structural analogs of Tl5Te3 (Sp.gr.I4/mcm), were synthesized and identified by DTA and XRD methods. From powder XRD data, their crystal lattices parameters were calculated: a=8.8766(7), c=13.0846 (13) Å, Z=4 (Tl4GdTe3); a=8.8588 (9), c=13.0524(16...

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Main Author: S. Imamaliyeva
Format: Article
Language:English
Published: Vasyl Stefanyk Precarpathian National University 2020-09-01
Series:Фізика і хімія твердого тіла
Subjects:
Online Access:https://journals.pnu.edu.ua/index.php/pcss/article/view/4293
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author S. Imamaliyeva
author_facet S. Imamaliyeva
author_sort S. Imamaliyeva
collection DOAJ
description The novel ternary compounds Tl4GdTe3 and Tl4DyTe3 ­- structural analogs of Tl5Te3 (Sp.gr.I4/mcm), were synthesized and identified by DTA and XRD methods. From powder XRD data, their crystal lattices parameters were calculated: a=8.8766(7), c=13.0846 (13) Å, Z=4 (Tl4GdTe3); a=8.8588 (9), c=13.0524(16) Å, Z=4 (Tl4DyTe3). It was found that the synthesized compounds melt with decomposition by peritectic reactions at 770 and 762 K, respectively.
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spelling doaj.art-f7de3a4fa4024257922a5e2788a35c3f2022-12-22T00:28:01ZengVasyl Stefanyk Precarpathian National UniversityФізика і хімія твердого тіла1729-44282309-85892020-09-0121349249510.15330/pcss.21.3.492-4954293Tl4GdTe3 and Tl4DyTe3 – novel structural Tl5Te3 analoguesS. Imamaliyeva0Institute of Catalysis and Inorganic ChemictryThe novel ternary compounds Tl4GdTe3 and Tl4DyTe3 ­- structural analogs of Tl5Te3 (Sp.gr.I4/mcm), were synthesized and identified by DTA and XRD methods. From powder XRD data, their crystal lattices parameters were calculated: a=8.8766(7), c=13.0846 (13) Å, Z=4 (Tl4GdTe3); a=8.8588 (9), c=13.0524(16) Å, Z=4 (Tl4DyTe3). It was found that the synthesized compounds melt with decomposition by peritectic reactions at 770 and 762 K, respectively.https://journals.pnu.edu.ua/index.php/pcss/article/view/4293thallium-ree telluridesdifferential-thermal analysispowder x-ray diffractioncrystal lattice
spellingShingle S. Imamaliyeva
Tl4GdTe3 and Tl4DyTe3 – novel structural Tl5Te3 analogues
Фізика і хімія твердого тіла
thallium-ree tellurides
differential-thermal analysis
powder x-ray diffraction
crystal lattice
title Tl4GdTe3 and Tl4DyTe3 – novel structural Tl5Te3 analogues
title_full Tl4GdTe3 and Tl4DyTe3 – novel structural Tl5Te3 analogues
title_fullStr Tl4GdTe3 and Tl4DyTe3 – novel structural Tl5Te3 analogues
title_full_unstemmed Tl4GdTe3 and Tl4DyTe3 – novel structural Tl5Te3 analogues
title_short Tl4GdTe3 and Tl4DyTe3 – novel structural Tl5Te3 analogues
title_sort tl4gdte3 and tl4dyte3 novel structural tl5te3 analogues
topic thallium-ree tellurides
differential-thermal analysis
powder x-ray diffraction
crystal lattice
url https://journals.pnu.edu.ua/index.php/pcss/article/view/4293
work_keys_str_mv AT simamaliyeva tl4gdte3andtl4dyte3novelstructuraltl5te3analogues