Mixed Micelle Formation and Co-adsorption of Anionic/Non-ionic Surfactant Mixtures on Rutile
Mixed micelle formation between the anionic surfactant p-dodecyl benzene sulphonate and the non-ionic surfactants Brij-58, Brij-78 and Brij-99, having the same number of oxyethylene units but a varying number of hydrophobic groups, has been studied using surface tension and NMR spectroscopic measure...
| Main Authors: | , |
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| Format: | Article |
| Language: | English |
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SAGE Publishing
1996-10-01
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| Series: | Adsorption Science & Technology |
| Online Access: | https://doi.org/10.1177/026361749601300507 |
| _version_ | 1826910959777611776 |
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| author | Ajay K. Vanjara Sharad G. Dixit |
| author_facet | Ajay K. Vanjara Sharad G. Dixit |
| author_sort | Ajay K. Vanjara |
| collection | DOAJ |
| description | Mixed micelle formation between the anionic surfactant p-dodecyl benzene sulphonate and the non-ionic surfactants Brij-58, Brij-78 and Brij-99, having the same number of oxyethylene units but a varying number of hydrophobic groups, has been studied using surface tension and NMR spectroscopic measurements. Both hydrophobic–hydrophobic and hydrophilic–hydrophilic interactions play an important role in mixed micelle formation leading to greater non-ideality. The effect of mixed micelle interactions on the adsorption of these surfactants from their mixtures on rutile have been investigated using adsorption and zeta potential measurements. Adsorption above the CMC level is dictated by the relatively higher tendency of mixed micellization over mixed aggregation at the solid/liquid interface. |
| first_indexed | 2024-03-07T17:22:39Z |
| format | Article |
| id | doaj.art-f7dfbab41c5141429271de36632ebab5 |
| institution | Directory Open Access Journal |
| issn | 0263-6174 2048-4038 |
| language | English |
| last_indexed | 2025-02-17T10:08:33Z |
| publishDate | 1996-10-01 |
| publisher | SAGE Publishing |
| record_format | Article |
| series | Adsorption Science & Technology |
| spelling | doaj.art-f7dfbab41c5141429271de36632ebab52025-01-02T02:58:03ZengSAGE PublishingAdsorption Science & Technology0263-61742048-40381996-10-011310.1177/026361749601300507Mixed Micelle Formation and Co-adsorption of Anionic/Non-ionic Surfactant Mixtures on RutileAjay K. Vanjara0Sharad G. Dixit1Department of Chemical Technology, (U.D.C.T.), University of Bombay, Matunga, Bombay 400 019, India.Department of Chemical Technology, (U.D.C.T.), University of Bombay, Matunga, Bombay 400 019, India.Mixed micelle formation between the anionic surfactant p-dodecyl benzene sulphonate and the non-ionic surfactants Brij-58, Brij-78 and Brij-99, having the same number of oxyethylene units but a varying number of hydrophobic groups, has been studied using surface tension and NMR spectroscopic measurements. Both hydrophobic–hydrophobic and hydrophilic–hydrophilic interactions play an important role in mixed micelle formation leading to greater non-ideality. The effect of mixed micelle interactions on the adsorption of these surfactants from their mixtures on rutile have been investigated using adsorption and zeta potential measurements. Adsorption above the CMC level is dictated by the relatively higher tendency of mixed micellization over mixed aggregation at the solid/liquid interface.https://doi.org/10.1177/026361749601300507 |
| spellingShingle | Ajay K. Vanjara Sharad G. Dixit Mixed Micelle Formation and Co-adsorption of Anionic/Non-ionic Surfactant Mixtures on Rutile Adsorption Science & Technology |
| title | Mixed Micelle Formation and Co-adsorption of Anionic/Non-ionic Surfactant Mixtures on Rutile |
| title_full | Mixed Micelle Formation and Co-adsorption of Anionic/Non-ionic Surfactant Mixtures on Rutile |
| title_fullStr | Mixed Micelle Formation and Co-adsorption of Anionic/Non-ionic Surfactant Mixtures on Rutile |
| title_full_unstemmed | Mixed Micelle Formation and Co-adsorption of Anionic/Non-ionic Surfactant Mixtures on Rutile |
| title_short | Mixed Micelle Formation and Co-adsorption of Anionic/Non-ionic Surfactant Mixtures on Rutile |
| title_sort | mixed micelle formation and co adsorption of anionic non ionic surfactant mixtures on rutile |
| url | https://doi.org/10.1177/026361749601300507 |
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