Functional Supramolecular Architectures of Dipyrrin Complexes
Dynamic formation of self-assemblies from molecular components is a useful and efficient way to produce molecular and supramolecular architectures with sophisticated functions. The labile coordination bond and dynamic covalent bond as a reversible bond have often been used to create a well-organized...
| Main Authors: | , |
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| Format: | Article |
| Language: | English |
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Frontiers Media S.A.
2018-08-01
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| Series: | Frontiers in Chemistry |
| Subjects: | |
| Online Access: | https://www.frontiersin.org/article/10.3389/fchem.2018.00349/full |
| _version_ | 1811309712297164800 |
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| author | Ryota Matsuoka Tatsuya Nabeshima |
| author_facet | Ryota Matsuoka Tatsuya Nabeshima |
| author_sort | Ryota Matsuoka |
| collection | DOAJ |
| description | Dynamic formation of self-assemblies from molecular components is a useful and efficient way to produce molecular and supramolecular architectures with sophisticated functions. The labile coordination bond and dynamic covalent bond as a reversible bond have often been used to create a well-organized supramolecular self-assembly. In order to realize sophisticated novel functions of the supramolecular self-assemblies, dipyrrin complexes have recently been employed as a functional unit and incorporated into the supramolecular architectures because of their outstanding properties and functions such as a high photostability and strong light absorption/emission. This review article summarizes recent development in functional supramolecular architectures of the dipyrrin complexes produced by coordination to a metal ion and dynamic covalent bond formation. We first describe the synthesis and unique functions of a series of discrete supramolecular architectures: helicates, macrocycles, and cages. The polymeric supramolecular self-assemblies with 1D, 2D, and 3D structures are then introduced as a functional infinite supramolecular architecture. |
| first_indexed | 2024-04-13T09:47:10Z |
| format | Article |
| id | doaj.art-f7f8fc47160a47cdb13ad1911b62393b |
| institution | Directory Open Access Journal |
| issn | 2296-2646 |
| language | English |
| last_indexed | 2024-04-13T09:47:10Z |
| publishDate | 2018-08-01 |
| publisher | Frontiers Media S.A. |
| record_format | Article |
| series | Frontiers in Chemistry |
| spelling | doaj.art-f7f8fc47160a47cdb13ad1911b62393b2022-12-22T02:51:44ZengFrontiers Media S.A.Frontiers in Chemistry2296-26462018-08-01610.3389/fchem.2018.00349402628Functional Supramolecular Architectures of Dipyrrin ComplexesRyota MatsuokaTatsuya NabeshimaDynamic formation of self-assemblies from molecular components is a useful and efficient way to produce molecular and supramolecular architectures with sophisticated functions. The labile coordination bond and dynamic covalent bond as a reversible bond have often been used to create a well-organized supramolecular self-assembly. In order to realize sophisticated novel functions of the supramolecular self-assemblies, dipyrrin complexes have recently been employed as a functional unit and incorporated into the supramolecular architectures because of their outstanding properties and functions such as a high photostability and strong light absorption/emission. This review article summarizes recent development in functional supramolecular architectures of the dipyrrin complexes produced by coordination to a metal ion and dynamic covalent bond formation. We first describe the synthesis and unique functions of a series of discrete supramolecular architectures: helicates, macrocycles, and cages. The polymeric supramolecular self-assemblies with 1D, 2D, and 3D structures are then introduced as a functional infinite supramolecular architecture.https://www.frontiersin.org/article/10.3389/fchem.2018.00349/fullsupramolecular chemistryself-assemblycoordination bonddynamic covalent bonddipyrrinBODIPY |
| spellingShingle | Ryota Matsuoka Tatsuya Nabeshima Functional Supramolecular Architectures of Dipyrrin Complexes Frontiers in Chemistry supramolecular chemistry self-assembly coordination bond dynamic covalent bond dipyrrin BODIPY |
| title | Functional Supramolecular Architectures of Dipyrrin Complexes |
| title_full | Functional Supramolecular Architectures of Dipyrrin Complexes |
| title_fullStr | Functional Supramolecular Architectures of Dipyrrin Complexes |
| title_full_unstemmed | Functional Supramolecular Architectures of Dipyrrin Complexes |
| title_short | Functional Supramolecular Architectures of Dipyrrin Complexes |
| title_sort | functional supramolecular architectures of dipyrrin complexes |
| topic | supramolecular chemistry self-assembly coordination bond dynamic covalent bond dipyrrin BODIPY |
| url | https://www.frontiersin.org/article/10.3389/fchem.2018.00349/full |
| work_keys_str_mv | AT ryotamatsuoka functionalsupramoleculararchitecturesofdipyrrincomplexes AT tatsuyanabeshima functionalsupramoleculararchitecturesofdipyrrincomplexes |