Microporous metal-organic frameworks based on deep eutectic solvents for adsorption of toxic gases and volatile organic compounds: A review
Metal-organic frameworks (MOFs) belonging to porous 2- or 3-dimensional materials have shown promising potential with wide use in different multidisciplinary fields because they possess remarkable structural properties which confer on them tunable functionalities coupled with excellent morphologies...
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| Format: | Article |
| Language: | English |
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Elsevier
2022-11-01
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| Series: | Chemical Engineering Journal Advances |
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| Online Access: | http://www.sciencedirect.com/science/article/pii/S2666821122001211 |
| _version_ | 1828097391463497728 |
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| author | Onome Ejeromedoghene Olayinka Oderinde Charles Obinwanne Okoye Abiodun Oladipo Yakubu Adekunle Alli |
| author_facet | Onome Ejeromedoghene Olayinka Oderinde Charles Obinwanne Okoye Abiodun Oladipo Yakubu Adekunle Alli |
| author_sort | Onome Ejeromedoghene |
| collection | DOAJ |
| description | Metal-organic frameworks (MOFs) belonging to porous 2- or 3-dimensional materials have shown promising potential with wide use in different multidisciplinary fields because they possess remarkable structural properties which confer on them tunable functionalities coupled with excellent morphologies and topologies. Different syntheses approaches have been designed and developed for the preparation of various MOF derivatives. However, unique solvents such as deep eutectic solvents (DESs) have been extensively studied recently because they can serve as essential precursors for preparing many novels and sophisticated composite materials where environmental benign processes are required. These green solvents are gaining serious attention as a templating agent for the facile, direct mixing, and/or ionothermal synthesis of MOFs because they synthesize easily, production is less expensive, and possess effective control of particle morphologies, pore sizes, and shapes, which have been reported to have significant influence in their adsorptive functions. Thus, this review highlights the progress in the development of DES-based MOFs bearing tunable functionalities and their applications for the adsorption of toxic gaseous pollutants. |
| first_indexed | 2024-04-11T07:45:38Z |
| format | Article |
| id | doaj.art-f7fc2c5e78fa48d2af02cd2d5e35961d |
| institution | Directory Open Access Journal |
| issn | 2666-8211 |
| language | English |
| last_indexed | 2024-04-11T07:45:38Z |
| publishDate | 2022-11-01 |
| publisher | Elsevier |
| record_format | Article |
| series | Chemical Engineering Journal Advances |
| spelling | doaj.art-f7fc2c5e78fa48d2af02cd2d5e35961d2022-12-22T04:36:18ZengElsevierChemical Engineering Journal Advances2666-82112022-11-0112100361Microporous metal-organic frameworks based on deep eutectic solvents for adsorption of toxic gases and volatile organic compounds: A reviewOnome Ejeromedoghene0Olayinka Oderinde1Charles Obinwanne Okoye2Abiodun Oladipo3Yakubu Adekunle Alli4School of Chemistry and Chemical Engineering, Southeast University, 211189 Nanjing, Jiangsu Province, China; Corresponding author.Department of Chemistry, Faculty of Natural and Applied Sciences, Lead City University, PMB 200255, Ibadan, Nigeria; Corresponding author.Biofuels Institute, School of Environment and Safety Engineering, Jiangsu University, Zhengjiang 212013, ChinaCo-Innovation Center for Sustainable Forestry in Southern China, College of Forestry, Nanjing Forestry University, 210037 Nanjing, Jiangsu, ChinaDepartment of Chemical Sciences, Faculty of Science and Computing, Ahman Pategi University, KM 3, Patigi-Kpada Road, Kwara State, NigeriaMetal-organic frameworks (MOFs) belonging to porous 2- or 3-dimensional materials have shown promising potential with wide use in different multidisciplinary fields because they possess remarkable structural properties which confer on them tunable functionalities coupled with excellent morphologies and topologies. Different syntheses approaches have been designed and developed for the preparation of various MOF derivatives. However, unique solvents such as deep eutectic solvents (DESs) have been extensively studied recently because they can serve as essential precursors for preparing many novels and sophisticated composite materials where environmental benign processes are required. These green solvents are gaining serious attention as a templating agent for the facile, direct mixing, and/or ionothermal synthesis of MOFs because they synthesize easily, production is less expensive, and possess effective control of particle morphologies, pore sizes, and shapes, which have been reported to have significant influence in their adsorptive functions. Thus, this review highlights the progress in the development of DES-based MOFs bearing tunable functionalities and their applications for the adsorption of toxic gaseous pollutants.http://www.sciencedirect.com/science/article/pii/S2666821122001211Metal-organic frameworksDeep eutectic solventsGreen solventsToxic gasesEnvironmental pollution |
| spellingShingle | Onome Ejeromedoghene Olayinka Oderinde Charles Obinwanne Okoye Abiodun Oladipo Yakubu Adekunle Alli Microporous metal-organic frameworks based on deep eutectic solvents for adsorption of toxic gases and volatile organic compounds: A review Chemical Engineering Journal Advances Metal-organic frameworks Deep eutectic solvents Green solvents Toxic gases Environmental pollution |
| title | Microporous metal-organic frameworks based on deep eutectic solvents for adsorption of toxic gases and volatile organic compounds: A review |
| title_full | Microporous metal-organic frameworks based on deep eutectic solvents for adsorption of toxic gases and volatile organic compounds: A review |
| title_fullStr | Microporous metal-organic frameworks based on deep eutectic solvents for adsorption of toxic gases and volatile organic compounds: A review |
| title_full_unstemmed | Microporous metal-organic frameworks based on deep eutectic solvents for adsorption of toxic gases and volatile organic compounds: A review |
| title_short | Microporous metal-organic frameworks based on deep eutectic solvents for adsorption of toxic gases and volatile organic compounds: A review |
| title_sort | microporous metal organic frameworks based on deep eutectic solvents for adsorption of toxic gases and volatile organic compounds a review |
| topic | Metal-organic frameworks Deep eutectic solvents Green solvents Toxic gases Environmental pollution |
| url | http://www.sciencedirect.com/science/article/pii/S2666821122001211 |
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