Pd-Based Bimetallic Electrocatalysts for Hydrogen Oxidation Reaction in 0.1 M KOH Solution
A series of carbon black-supported 7.5 wt.% Pd-2.5 wt.% M/C (M: Ag, Ca, Co, Cu, Fe, Ni, Ru, Sn, Zn) electrocatalysts, synthesized via the wet impregnation method, and reduced at 300 °C, were compared in terms of their hydrogen oxidation reaction (HOR) activity in a 0.1 M KOH solution using the thin-...
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MDPI AG
2024-03-01
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| Series: | Nanomaterials |
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| Online Access: | https://www.mdpi.com/2079-4991/14/6/500 |
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| author | Georgios Bampos Symeon Bebelis |
| author_facet | Georgios Bampos Symeon Bebelis |
| author_sort | Georgios Bampos |
| collection | DOAJ |
| description | A series of carbon black-supported 7.5 wt.% Pd-2.5 wt.% M/C (M: Ag, Ca, Co, Cu, Fe, Ni, Ru, Sn, Zn) electrocatalysts, synthesized via the wet impregnation method, and reduced at 300 °C, were compared in terms of their hydrogen oxidation reaction (HOR) activity in a 0.1 M KOH solution using the thin-film rotating-disk electrode technique. Moreover, 10 wt.% Pd/C and 10 wt.% Pt/C electrocatalysts were prepared in the same manner and used as references. The 7.5 wt.% Pd-2.5 wt.% Ni/C electrocatalyst exhibited the highest HOR activity among the Pd-based electrocatalysts, although it was lower than that of the 10 wt.% Pt/C. Its activity was also found to be higher than that of Pd-Ni electrocatalysts of the same total metal loading (10 wt.%) and reduction temperature (300 °C) but of different Pd to Ni atomic ratio. It was also higher than that of 7.5 wt.% Pd-2.5 wt.% Ni/C electrocatalysts that were reduced at temperatures other than 300 °C. The superior activity of this electrocatalyst was attributed to an optimum value of the hydrogen binding energy of Pd, which was induced by the presence of Ni (electronic effect), as well as to the oxophilic character of Ni, which favors adsorption on the Ni surface of hydroxyl species that readily react with adsorbed hydrogen atoms on neighboring Pd sites in the rate-determining step. |
| first_indexed | 2024-04-24T17:57:48Z |
| format | Article |
| id | doaj.art-f82cd506f3084e98907f058db10b02df |
| institution | Directory Open Access Journal |
| issn | 2079-4991 |
| language | English |
| last_indexed | 2024-04-24T17:57:48Z |
| publishDate | 2024-03-01 |
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| series | Nanomaterials |
| spelling | doaj.art-f82cd506f3084e98907f058db10b02df2024-03-27T13:57:32ZengMDPI AGNanomaterials2079-49912024-03-0114650010.3390/nano14060500Pd-Based Bimetallic Electrocatalysts for Hydrogen Oxidation Reaction in 0.1 M KOH SolutionGeorgios Bampos0Symeon Bebelis1Department of Chemical Engineering, University of Patras, GR-26504 Patras, GreeceDepartment of Chemical Engineering, University of Patras, GR-26504 Patras, GreeceA series of carbon black-supported 7.5 wt.% Pd-2.5 wt.% M/C (M: Ag, Ca, Co, Cu, Fe, Ni, Ru, Sn, Zn) electrocatalysts, synthesized via the wet impregnation method, and reduced at 300 °C, were compared in terms of their hydrogen oxidation reaction (HOR) activity in a 0.1 M KOH solution using the thin-film rotating-disk electrode technique. Moreover, 10 wt.% Pd/C and 10 wt.% Pt/C electrocatalysts were prepared in the same manner and used as references. The 7.5 wt.% Pd-2.5 wt.% Ni/C electrocatalyst exhibited the highest HOR activity among the Pd-based electrocatalysts, although it was lower than that of the 10 wt.% Pt/C. Its activity was also found to be higher than that of Pd-Ni electrocatalysts of the same total metal loading (10 wt.%) and reduction temperature (300 °C) but of different Pd to Ni atomic ratio. It was also higher than that of 7.5 wt.% Pd-2.5 wt.% Ni/C electrocatalysts that were reduced at temperatures other than 300 °C. The superior activity of this electrocatalyst was attributed to an optimum value of the hydrogen binding energy of Pd, which was induced by the presence of Ni (electronic effect), as well as to the oxophilic character of Ni, which favors adsorption on the Ni surface of hydroxyl species that readily react with adsorbed hydrogen atoms on neighboring Pd sites in the rate-determining step.https://www.mdpi.com/2079-4991/14/6/500hydrogen oxidation reactionPd-based electrocatalystsalkaline mediumhydrogen binding energyhydroxyl species binding energystrain effect |
| spellingShingle | Georgios Bampos Symeon Bebelis Pd-Based Bimetallic Electrocatalysts for Hydrogen Oxidation Reaction in 0.1 M KOH Solution Nanomaterials hydrogen oxidation reaction Pd-based electrocatalysts alkaline medium hydrogen binding energy hydroxyl species binding energy strain effect |
| title | Pd-Based Bimetallic Electrocatalysts for Hydrogen Oxidation Reaction in 0.1 M KOH Solution |
| title_full | Pd-Based Bimetallic Electrocatalysts for Hydrogen Oxidation Reaction in 0.1 M KOH Solution |
| title_fullStr | Pd-Based Bimetallic Electrocatalysts for Hydrogen Oxidation Reaction in 0.1 M KOH Solution |
| title_full_unstemmed | Pd-Based Bimetallic Electrocatalysts for Hydrogen Oxidation Reaction in 0.1 M KOH Solution |
| title_short | Pd-Based Bimetallic Electrocatalysts for Hydrogen Oxidation Reaction in 0.1 M KOH Solution |
| title_sort | pd based bimetallic electrocatalysts for hydrogen oxidation reaction in 0 1 m koh solution |
| topic | hydrogen oxidation reaction Pd-based electrocatalysts alkaline medium hydrogen binding energy hydroxyl species binding energy strain effect |
| url | https://www.mdpi.com/2079-4991/14/6/500 |
| work_keys_str_mv | AT georgiosbampos pdbasedbimetallicelectrocatalystsforhydrogenoxidationreactionin01mkohsolution AT symeonbebelis pdbasedbimetallicelectrocatalystsforhydrogenoxidationreactionin01mkohsolution |