Stabilized anode-electrolyte interfaces via Cs4Pb(Cl/Br/I)6 perovskite crystal based glass-ceramics for fast and long cycle-life lithium ion batteries
Alternative choices of anode materials in lithium-ion batteries (LiBs) have drawn great attention to the urgent demands of rapid charging, however, the severe interface problems remain a bottleneck for the anode development. Based on the high reducibility of halogen elements, herein a smart anode/li...
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| Format: | Article |
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Elsevier
2022-08-01
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| Series: | Materials & Design |
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| Online Access: | http://www.sciencedirect.com/science/article/pii/S0264127522004828 |
| _version_ | 1818048117505785856 |
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| author | Wenqing Xie Jianghang Cao Panpan Li Meiqiang Fan Shiqing Xu Jincheng Du Junjie Zhang |
| author_facet | Wenqing Xie Jianghang Cao Panpan Li Meiqiang Fan Shiqing Xu Jincheng Du Junjie Zhang |
| author_sort | Wenqing Xie |
| collection | DOAJ |
| description | Alternative choices of anode materials in lithium-ion batteries (LiBs) have drawn great attention to the urgent demands of rapid charging, however, the severe interface problems remain a bottleneck for the anode development. Based on the high reducibility of halogen elements, herein a smart anode/liquid electrolyte interface is designed for the high energy density batteries that present large specific capacity retentions of about 510.5 mAh∙g−1 (Cl-matrix) and 429.6 mAh∙g−1 (Br-matrix) at the current density of 5 A∙g−1 after cycling 1000 times. As a novel anode material, the low-dimension halide perovskite microcrystals Cs4Pb(Cl/Br/I)6 embedded in the glass matrix present high ionic conductivities (10−5 ∼ 10−4 S∙cm−1) that enables fast charge transfer, besides the smooth interface benefits ionic transport reversibly. Most impressively, simple composite processing has significant economic benefits that might drive the crystal-in-glass composite material as a promising new generation anode for rechargeable LiBs. |
| first_indexed | 2024-12-10T10:16:35Z |
| format | Article |
| id | doaj.art-f850823818984628926fa7b09806acca |
| institution | Directory Open Access Journal |
| issn | 0264-1275 |
| language | English |
| last_indexed | 2024-12-10T10:16:35Z |
| publishDate | 2022-08-01 |
| publisher | Elsevier |
| record_format | Article |
| series | Materials & Design |
| spelling | doaj.art-f850823818984628926fa7b09806acca2022-12-22T01:52:59ZengElsevierMaterials & Design0264-12752022-08-01220110860Stabilized anode-electrolyte interfaces via Cs4Pb(Cl/Br/I)6 perovskite crystal based glass-ceramics for fast and long cycle-life lithium ion batteriesWenqing Xie0Jianghang Cao1Panpan Li2Meiqiang Fan3Shiqing Xu4Jincheng Du5Junjie Zhang6College of Optical and Electronic Technology, China Jiliang University, Hangzhou 310018, China; College of Engineering, University of North Texas, Denton, TX 76203, USACollege of Materials and Chemistry, China Jiliang University, Hangzhou 310018, ChinaCollege of Optical and Electronic Technology, China Jiliang University, Hangzhou 310018, ChinaCollege of Materials and Chemistry, China Jiliang University, Hangzhou 310018, ChinaCollege of Optical and Electronic Technology, China Jiliang University, Hangzhou 310018, China; Corresponding authors.College of Engineering, University of North Texas, Denton, TX 76203, USACollege of Optical and Electronic Technology, China Jiliang University, Hangzhou 310018, China; Corresponding authors.Alternative choices of anode materials in lithium-ion batteries (LiBs) have drawn great attention to the urgent demands of rapid charging, however, the severe interface problems remain a bottleneck for the anode development. Based on the high reducibility of halogen elements, herein a smart anode/liquid electrolyte interface is designed for the high energy density batteries that present large specific capacity retentions of about 510.5 mAh∙g−1 (Cl-matrix) and 429.6 mAh∙g−1 (Br-matrix) at the current density of 5 A∙g−1 after cycling 1000 times. As a novel anode material, the low-dimension halide perovskite microcrystals Cs4Pb(Cl/Br/I)6 embedded in the glass matrix present high ionic conductivities (10−5 ∼ 10−4 S∙cm−1) that enables fast charge transfer, besides the smooth interface benefits ionic transport reversibly. Most impressively, simple composite processing has significant economic benefits that might drive the crystal-in-glass composite material as a promising new generation anode for rechargeable LiBs.http://www.sciencedirect.com/science/article/pii/S0264127522004828HalogenZero-dimension perovskiteGlass–ceramicInterfaceLithium-ion batteries |
| spellingShingle | Wenqing Xie Jianghang Cao Panpan Li Meiqiang Fan Shiqing Xu Jincheng Du Junjie Zhang Stabilized anode-electrolyte interfaces via Cs4Pb(Cl/Br/I)6 perovskite crystal based glass-ceramics for fast and long cycle-life lithium ion batteries Materials & Design Halogen Zero-dimension perovskite Glass–ceramic Interface Lithium-ion batteries |
| title | Stabilized anode-electrolyte interfaces via Cs4Pb(Cl/Br/I)6 perovskite crystal based glass-ceramics for fast and long cycle-life lithium ion batteries |
| title_full | Stabilized anode-electrolyte interfaces via Cs4Pb(Cl/Br/I)6 perovskite crystal based glass-ceramics for fast and long cycle-life lithium ion batteries |
| title_fullStr | Stabilized anode-electrolyte interfaces via Cs4Pb(Cl/Br/I)6 perovskite crystal based glass-ceramics for fast and long cycle-life lithium ion batteries |
| title_full_unstemmed | Stabilized anode-electrolyte interfaces via Cs4Pb(Cl/Br/I)6 perovskite crystal based glass-ceramics for fast and long cycle-life lithium ion batteries |
| title_short | Stabilized anode-electrolyte interfaces via Cs4Pb(Cl/Br/I)6 perovskite crystal based glass-ceramics for fast and long cycle-life lithium ion batteries |
| title_sort | stabilized anode electrolyte interfaces via cs4pb cl br i 6 perovskite crystal based glass ceramics for fast and long cycle life lithium ion batteries |
| topic | Halogen Zero-dimension perovskite Glass–ceramic Interface Lithium-ion batteries |
| url | http://www.sciencedirect.com/science/article/pii/S0264127522004828 |
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