Sequence-regulated copolymerization based on periodic covalent positioning of monomers along one-dimensional nanochannels
Achieving sequence control in polymers is limited by the relative monomer reactivity and thus often statistically random copolymers are obtained. Here the authors show sequence control in radical polymerizations by immobilising the monomer on a porous coordination polymer and subsequent polymerizati...
| Main Authors: | , , , , , |
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| Format: | Article |
| Language: | English |
| Published: |
Nature Portfolio
2018-01-01
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| Series: | Nature Communications |
| Online Access: | https://doi.org/10.1038/s41467-017-02736-1 |
| _version_ | 1819039710804180992 |
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| author | Shuto Mochizuki Naoki Ogiwara Masayoshi Takayanagi Masataka Nagaoka Susumu Kitagawa Takashi Uemura |
| author_facet | Shuto Mochizuki Naoki Ogiwara Masayoshi Takayanagi Masataka Nagaoka Susumu Kitagawa Takashi Uemura |
| author_sort | Shuto Mochizuki |
| collection | DOAJ |
| description | Achieving sequence control in polymers is limited by the relative monomer reactivity and thus often statistically random copolymers are obtained. Here the authors show sequence control in radical polymerizations by immobilising the monomer on a porous coordination polymer and subsequent polymerization with a second free monomer. |
| first_indexed | 2024-12-21T08:57:32Z |
| format | Article |
| id | doaj.art-f85941af7cf64d5d8069e014b447ea07 |
| institution | Directory Open Access Journal |
| issn | 2041-1723 |
| language | English |
| last_indexed | 2024-12-21T08:57:32Z |
| publishDate | 2018-01-01 |
| publisher | Nature Portfolio |
| record_format | Article |
| series | Nature Communications |
| spelling | doaj.art-f85941af7cf64d5d8069e014b447ea072022-12-21T19:09:32ZengNature PortfolioNature Communications2041-17232018-01-01911610.1038/s41467-017-02736-1Sequence-regulated copolymerization based on periodic covalent positioning of monomers along one-dimensional nanochannelsShuto Mochizuki0Naoki Ogiwara1Masayoshi Takayanagi2Masataka Nagaoka3Susumu Kitagawa4Takashi Uemura5Department of Synthetic Chemistry and Biological Chemistry, Graduate School of Engineering, Kyoto UniversityDepartment of Synthetic Chemistry and Biological Chemistry, Graduate School of Engineering, Kyoto UniversityDepartment of Complex Systems Science, Graduate School of Informatics, Nagoya UniversityDepartment of Complex Systems Science, Graduate School of Informatics, Nagoya UniversityDepartment of Synthetic Chemistry and Biological Chemistry, Graduate School of Engineering, Kyoto UniversityDepartment of Synthetic Chemistry and Biological Chemistry, Graduate School of Engineering, Kyoto UniversityAchieving sequence control in polymers is limited by the relative monomer reactivity and thus often statistically random copolymers are obtained. Here the authors show sequence control in radical polymerizations by immobilising the monomer on a porous coordination polymer and subsequent polymerization with a second free monomer.https://doi.org/10.1038/s41467-017-02736-1 |
| spellingShingle | Shuto Mochizuki Naoki Ogiwara Masayoshi Takayanagi Masataka Nagaoka Susumu Kitagawa Takashi Uemura Sequence-regulated copolymerization based on periodic covalent positioning of monomers along one-dimensional nanochannels Nature Communications |
| title | Sequence-regulated copolymerization based on periodic covalent positioning of monomers along one-dimensional nanochannels |
| title_full | Sequence-regulated copolymerization based on periodic covalent positioning of monomers along one-dimensional nanochannels |
| title_fullStr | Sequence-regulated copolymerization based on periodic covalent positioning of monomers along one-dimensional nanochannels |
| title_full_unstemmed | Sequence-regulated copolymerization based on periodic covalent positioning of monomers along one-dimensional nanochannels |
| title_short | Sequence-regulated copolymerization based on periodic covalent positioning of monomers along one-dimensional nanochannels |
| title_sort | sequence regulated copolymerization based on periodic covalent positioning of monomers along one dimensional nanochannels |
| url | https://doi.org/10.1038/s41467-017-02736-1 |
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