Chitin-Derived Nanocatalysts for Reductive Amination Reactions

Chitin, the second most abundant biopolymer in the planet after cellulose, represents a renewable carbon and nitrogen source. A thrilling opportunity for the valorization of chitin is focused on the preparation of biomass-derived <i>N</i>-doped carbonaceous materials. In this contributio...

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Bibliographic Details
Main Authors: Daniele Polidoro, Daily Rodriguez-Padron, Alvise Perosa, Rafael Luque, Maurizio Selva
Format: Article
Language:English
Published: MDPI AG 2023-01-01
Series:Materials
Subjects:
Online Access:https://www.mdpi.com/1996-1944/16/2/575
Description
Summary:Chitin, the second most abundant biopolymer in the planet after cellulose, represents a renewable carbon and nitrogen source. A thrilling opportunity for the valorization of chitin is focused on the preparation of biomass-derived <i>N</i>-doped carbonaceous materials. In this contribution, chitin-derived <i>N</i>-doped carbons were successfully prepared and functionalized with palladium metal nanoparticles. The physicochemical properties of these nanocomposites were investigated following a multi-technique strategy and their catalytic activity in reductive amination reactions was explored. In particular, a biomass-derived platform molecule, namely furfural, was upgraded to valuable bi-cyclic compounds under continuous flow conditions.
ISSN:1996-1944